Abstract
Electric field assisted sintering (EFAS) is one of the interesting technical strategies for enhancing the performance of DSSCs. To this aim, the present study aimed to present an efficient approach for increasing the photovoltaic performance of DSSCs by implementing EFAS procedure at different sintering temperatures (350, 400, 450 and 500 °C). Interestingly, the EFAS procedure played a positive role on optical and electrical properties simultaneously. Based on the results, applying an external electric field within the sintering procedure results in improving the light harvesting capability of mesoporous TiO2 film at all sintering temperatures, increasing the photocurrent and fill factor efficiently, leading to an improvement in the performance, and reducing the resistive effects and charging recombination sites significantly. EFAS is broadly applicable to improve the performance of mesoporous-based devices such as dye-sensitized and perovskite solar cells or reduce the cost and time of manufacturing by decreasing the sintering temperature. Finally EFAS method may lead to higher performance in flexible DSSCs.
Similar content being viewed by others
References
O’Regan B, Gratzel M, Low-Cost A (1991) High-efficiency solar-cell based on dye-sensitized colloidal TiO2 films. Nature 353:737–740. https://doi.org/10.1038/353737a0
Gong J, Sumathy K, Qiao Q, Zhou Z (2017) Review on dye-sensitized solar cells (DSSCs): advanced techniques and research trends. Renew Sustain Energy Rev 68:234–246. https://doi.org/10.1016/j.rser.2016.09.097
Ahmad S, Guillén E, Kavan L, Grätzel M, Nazeeruddin MK (2013) Metal free sensitizer and catalyst for dye sensitized solar cells. Energy Environ Sci 6:3439–3466. https://doi.org/10.1039/c3ee41888j
Kim H, Lee W, Song H, Yoon J (2017) Plasmonic-enhanced graphene flake counter electrodes for dye-sensitized solar cells. J Appl Phys 121:243103-1–243103-7. https://doi.org/10.1063/1.4989810
Yun MJ, Sim YH, Cha SI, Seo SH, Lee DY (2017) High energy conversion efficiency with 3-D micro-patterned photoanode for enhancement diffusivity and modification of photon distribution in dye-sensitized solar cells. Sci Rep 7:15027-1–15027-10. https://doi.org/10.1038/s41598-017-15110-4
Adineh M, Tahay P, Ameri M, Safari N, Mohajerani E (2016) Fabrication and analysis of dye-sensitized solar cells (DSSCs) using porphyrin dyes with catechol anchoring groups. RSC Adv 6:14512–14521. https://doi.org/10.1039/C5RA23584G
Yella A, Lee H-W, Tsao HN, Yi C, Chandiran AK, Nazeeruddin MK, Diau EW-G, Yeh C-Y, Zakeeruddin SM, Grätzel M (2011) Porphyrin-sensitized solar cells with Cobalt(II/III)—based redox electrolyte exceed 12 percent efficiency. Science 334(80):629–633. https://doi.org/10.1126/science.1209688
Boppella R, Mohammadpour A, Illa S, Farsinezhad S, Basak P, Shankar K, Manorama SV (2016) Hierarchical rutile TiO2 aggregates: a high photonic strength material for optical and optoelectronic devices. Acta Mater 119:92–103. https://doi.org/10.1016/j.actamat.2016.08.004
Hu Q, Li Y, Huang F, Zhang Z, Ding K, Wei M (2005) ZnO nanowires array grown on Ga-doped ZnO single crystal for dye-sensitized solar cells. Nat Publ Gr 5:1–7. https://doi.org/10.1038/srep11499
Mori R, Ueta T, Sakai K (2010) Organic solvent based TiO2 dispersion paste for dye-sensitized solar cells prepared by industrial production level procedure. J Mater Sci (Full Set) 46:1341–1350. https://doi.org/10.1007/s10853-010-4925-2
Wu J, Lan Z, Lin J, Huang M, Huang Y, Fan L, Luo G (2015) Electrolytes in dye-sensitized solar cells. Chem Rev 115:2136–2173. https://doi.org/10.1021/cr400675m
Sahito IA, Ahmed F, Khatri Z, Sun KC, Jeong SH (2017) Enhanced ionic mobility and increased efficiency of dye-sensitized solar cell by adding lithium chloride in poly(vinylidene fluoride) nanofiber as electrolyte medium. J Mater Sci 52:13920–13929. https://doi.org/10.1007/s10853-017-1473-z
Hu Y, Yella A, Guldin S, Schreier M, Stellacci F, Grätzel M, Stefi M (2014) High-surface-area porous platinum electrodes for enhanced charge transfer. Adv Energy Mater 4:1–8. https://doi.org/10.1002/aenm.201400510
Yun D, Jeong YJ, Ra H, Kim J, Park JH, Park S, An TK, Seol M, Park CE, Jang J, Chung DS (2016) Effective way to enhance the electrode performance of multiwall carbon nanotube and poly (3, 4-ethylenedioxythiophene): poly (styrene sulfonate) composite using hcl—methanol treatment. J Phys Chem C 120:10919–10926. https://doi.org/10.1021/acs.jpcc.6b01747
El Ruby Mohamed A, Rohani S (2011) Modified TiO2 nanotube arrays (TNTAs): progressive strategies towards visible light responsive photoanode, a review. Energy Environ Sci 4:1065–1086. https://doi.org/10.1039/c0ee00488j
Basu K, Benetti D, Zhao H, Jin L, Vetrone F (2016) Enhanced photovoltaic properties in dye sensitized solar cells by surface treatment of SnO2 photoanodes. Sci Rep 6:1–10. https://doi.org/10.1038/srep23312
Nakade S, Saito Y, Kubo W, Kitamura T, Wada Y, Yanagida S (2003) Influence of TiO2 nanoparticle size on electron diffusion and recombination in dye-sensitized TiO2 solar cells. J Phys Chem B 107:8607–8611. https://doi.org/10.1021/jp034773w
Chou TP, Zhang Q, Russo B, Fryxell GE, Cao G, Science M, Uni V, Hall R (2007) Titania particle size effect on the overall performance of dye-sensitized solar cells. J Phys Chem C 111:6296–6302. https://doi.org/10.1021/jp068939f
Andrei C, O’Reilly T, Zerulla D (2010) A spatially resolved study on the Sn diffusion during the sintering process in the active layer of dye sensitised solar cells. Phys Chem Chem Phys 12:7241–7245. https://doi.org/10.1039/c000072h
Sun X, Sun Q, Li Y, Sui L, Dong L (2013) Effects of calcination treatment on the morphology, crystallinity, and photoelectric properties of all-solid-state dye-sensitized solar cells assembled by TiO2 nanorod arrays. Phys Chem Chem Phys 15:18716–18720. https://doi.org/10.1039/c3cp51941d
Schattauer S, Reinhold B, Albrecht S, Fahrenson C, Schubert M, Janietz S, Neher D (2012) Influence of sintering on the structural and electronic properties of TiO2 nanoporous layers prepared via a non-sol-gel approach. Colloid Polym Sci 290:1843–1854. https://doi.org/10.1007/s00396-012-2708-9
Chou C-S, Yanga R-Y, Weng M-H, Yeh C-H (2008) The influence of sintering temperature on the performance of dye-sensitized solar cell. Adv Manuf Focus New Emerg Technol 594:281–298. https://doi.org/10.4028/www.scientific.net/MSF.594.281
Tripathi B, Bhatt P, Chandra Kanth P, Yadav P, Desai B, Kumar Pandey M, Kumar M (2015) Temperature induced structural, electrical and optical changes in solution processed perovskite material: application in photovoltaics. Sol Energy Mater Sol Cells 132:615–622. https://doi.org/10.1016/j.solmat.2014.10.017
Brown TM, De Rossi F, Di Giacomo F, Mincuzzi G, Zardetto V, Realea A, Di Carloa A (2014) Progress in flexible dye solar cell materials, processes and devices. J Mater Chem A 2:10788–10817. https://doi.org/10.1039/c4ta00902a
Senthilarasu S, Peiris TAN, García-can J, Wijayantha KGU (2012) Preparation of nanocrystalline TiO2 electrodes for flexible dye-sensitized solar cells: influence of mechanical compression. J Phys Chem C 116:19053–19061. https://doi.org/10.1021/jp301638p
Weerasinghe HC, Huang F, Cheng Y (2013) Fabrication of flexible dye sensitized solar cells on plastic substrates. Nano Energy 2:174–189. https://doi.org/10.1016/j.nanoen.2012.10.004
Zen S, Inoue Y, Ono R (2015) Low temperature (150 °C) fabrication of high-performance TiO2 films for dye-sensitized solar cells using ultraviolet light and plasma treatments of TiO2 paste containing.pdf. J Appl Phys 117:103302-1–103302-5. https://doi.org/10.1063/1.4914873
Cologna M, Rashkova B, Raj R (2010) Flash sintering of nanograin zirconia in o 5 s at 850 1 C. J Am Ceram Soc 93:3556–3559. https://doi.org/10.1111/j.1551-2916.2010.04089.x
Jha SK, Lebrun JM, Seymour KC, Kriven WM, Raj R (2016) Journal of the European ceramic society electric field induced texture in titania during experiments related to flash sintering. J Eur Ceram Soc 36:257–261. https://doi.org/10.1016/j.jeurceramsoc.2015.09.002
Shojaeifar M, Mohajerani E, Fathollahi M (2018) Electric field assisted sintering to improve the performance of nanostructured dye sensitized solar cell (DSSC). J Appl Phys 123:13101–13102. https://doi.org/10.1063/1.5010009
Gholizadeh A, Reyhani A, Parvin P, Mortazavi SZ (2017) Efficiency enhancement of ZnO nanostructure assisted Si solar cell based on fill factor enlargement and UV-blue spectral down-shifting. J Phys D Appl Phys 50:185501-1–185501-11. https://doi.org/10.1088/1361-6463/aa6454
Koide N, Islam A, Chiba Y, Han L (2006) Improvement of efficiency of dye-sensitized solar cells based on analysis of equivalent circuit. J Photochem Photobiol A Chem 182:296–305. https://doi.org/10.1016/j.jphotochem.2006.04.030
Sarker S, Seo HW, Kim DM (2014) Calculating current density-voltage curves of dye-sensitized solar cells: a straight-forward approach. J Power Sour 248:739–744. https://doi.org/10.1016/j.jpowsour.2013.09.101
Ni M, Leung MKH, Leung DYC, Sumathy K (2006) Theoretical modeling of TiO2/TCO interfacial effect on dye-sensitized solar cell performance. Sol Energy Mater Sol Cells 90:2000–2009. https://doi.org/10.1016/j.solmat.2006.02.005
Niu H, Zhang S, Wang R, Guo Z, Shang X, Gan W, Qin S, Wan L, Xu J (2014) Dye-sensitized solar cells employing a multifunctionalized hierarchical SnO2 nano flower structure passivated by TiO2 nanogranulum. Am Chem Soc 118:3504–3513. https://doi.org/10.1021/jp409203w
Alvar MS, Javadi M, Abdi Y, Arzi E (2016) Enhancing the electron lifetime and diffusion coefficient in dye-sensitized solar cells by patterning the layer of TiO2 nanoparticles. J Appl Phys 19:114302-1–114302-7. https://doi.org/10.1063/1.4943772
Xu B, Wang G, Fu H (2016) Enhanced photoelectric conversion efficiency of dye- sensitized solar cells by the incorporation of flower-like Bi2S3: Eu3+ sub-microspheres. Sci Rep 6:1–9. https://doi.org/10.1038/srep23395
Marinova N, Valero S, Delgado JL (2017) Organic and perovskite solar cells: working principles, materials and interfaces. J Colloid Interface Sci 488:373–389. https://doi.org/10.1016/j.jcis.2016.11.021
Murayama M, Mori T (2006) Evaluation of treatment effects for high-performance dye-sensitized solar cells using equivalent circuit analysis. Thin Solid Films 509:123–126. https://doi.org/10.1016/j.tsf.2005.09.145
Choudhury MSH, Kato S, Kishi N, Soga T (2017) Nickel tetraphenylporphyrin doping into ZnO nanoparticles for flexible dye-sensitized solar cell application Nickel tetraphenylporphyrin doping into ZnO nanoparticles for flexible dye-sensitized solar cell application. Jpn J Appl Phys 56:04CS05-1–04CS05-7. https://doi.org/10.7567/jjap.56.04cs05
Zhao D, Peng T, Lu L, Cai P, Jiang P, Bian Z (2008) Effect of annealing temperature on the photoelectrochemical properties of dye-sensitized solar cells made with mesoporous TiO2 nanoparticles. J Phys Chem C 112:8486–8494. https://doi.org/10.1021/jp800127x
Wang B, Shen S, Mao SS (2017) Black TiO2 for solar hydrogen conversion. J Mater 3:96–111. https://doi.org/10.1016/j.jmat.2017.02.001
Dusastre V (2011) Materials for sustainable energy. Nature Publishing Group, London
Ghadiri E, Taghavinia N, Zakeeruddin SM, Gra M (2010) Enhanced electron collection efficiency in dye-sensitized solar cells based on nanostructured TiO2 hollow fibers. Nano Lett 10:1632–1638. https://doi.org/10.1021/nl904125q
Acknowledgements
This research was partly supported by the Iran Ministry of Science and Technology. The authors would like to thank Dr. Mohammad Reza Fathollahi for his thankful recommendations.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Shojaeifar, M., Mohajerani, E. The effect of temperature on electric field assisted sintering in dye-sensitized solar cells. J Mater Sci 54, 1629–1639 (2019). https://doi.org/10.1007/s10853-018-2934-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-018-2934-8