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Metalloporphyrin supported on hyper cross-linked polymer: green protocol for reduction of nitroarenes

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Abstract

In the current study, a Pd–porphyrin catalyst was anchored covalently onto functionalized polymeric spine based on a calix[4]resorcinarene. The achieved catalytic system was characterized, and its catalytic activity was investigated in the reduction of nitroarenes. The main advantages of the present work are: using water as green solvent, catalyst reusability, easy refinement of the products, excellent yields, and relatively short reaction times.

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Acknowledgements

This work was supported by the Research Council at the University of Shahid Chamran.

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  1. Department of Chemistry, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran

    Sheida Hamid & Arash Mouradzadegun

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  1. Sheida Hamid
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  2. Arash Mouradzadegun
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Correspondence to Arash Mouradzadegun.

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Hamid, S., Mouradzadegun, A. Metalloporphyrin supported on hyper cross-linked polymer: green protocol for reduction of nitroarenes. J Incl Phenom Macrocycl Chem 98, 213–221 (2020). https://doi.org/10.1007/s10847-020-01021-x

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