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Synergistic effect of impure/pure graphene oxide and TiO2 fillers on the dielectric properties of poly (vinylidene fluoride- hexafluoropropylene) for electroadhesive high load bearing applications

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Abstract

Poly (vinylidene fluoride- hexafluoroproylene) PVDF-HFP has been employed as a host polymer because of its strong chemical resistance, mechanical and dielectric properties and low cost. However, further changes employing other polymers, nanomaterials, additives and fillers to improve the properties of the host polymers are of significant interest. TiO2 has gained a lot of attention because of its high k dielectric and photo catalytic capabilities. Graphene oxide (GO) has received a lot of attention because of its larger mechanical strength, dielectric behavior and other qualities. Using the doctor blade coating process, varied amounts of TiO2 and GO were successfully integrated into PVDF-HFP to form composite films. The XRD result reveals that TiO2/GO has been successfully incorporated into the PVDF-HFP polymer matrix, while FTIR, SEM experiments have demonstrated the effectiveness of TiO2/GO fillers on PVDF-HFP film. AC impedance spectroscopy reveals the dielectric behavior and resistivity of polymer nanocomposite film. The film has been tested for its loading bearing capacity during electroadhesion with different applied voltages. The maximum load bearing capacity based on electroadhesion has been estimated.

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Acknowledgements

The authors are thankful to the Centre for Research in Material Science and Thermal Management (CRM & TM) lab, Karunya Institute of technology and sciences for providing contact angle analysis. The graphical abstract work was supported by Ms. Vinodhini Subramaniyam, Department of Nanoscience and Technology, Sri Ramakrishna Engineering College, Coimbatore.

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Authors and Affiliations

  1. Centre for Nanosciences and Genomics, Karunya Institute of Technology and Sciences, 641 114, Coimbatore, Tamil Nadu, India

    J. Deepak Rosario & B. Vidhya

  2. Department of Applied Physics, Karunya Institute of Technology and Sciences, 641 114, Coimbatore, Tamil Nadu, India

    R. Ranjithkumar, V. Deepthi, B. Vidhya, Rajesh Swaminathan & Sakunthala Ayyasamy

  3. Department of Applied Chemistry, Karunya Institute of Technology and Sciences, 641 114, Coimbatore, Tamil Nadu, India

    Raju Nandhakumar

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  1. J. Deepak Rosario
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Contributions

Deepak J contributed to Analysis, Interpretation and drafting, Ranjith R performed the Analysis and Interpretation of data, Deepthi V worked on the photocatalysis part, Vidhya B contributed in Conception or design of the work, final drafting and revision for important intellectual content, Rajesh S, Sakunthala A and Nandhakumar R involved in all aspects of the work in ensuring that questions related to the accuracy or integrity of any part of the work are appropriately investigated and resolved.

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Correspondence to B. Vidhya.

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Rosario, J.D., Ranjithkumar, R., Deepthi, V. et al. Synergistic effect of impure/pure graphene oxide and TiO2 fillers on the dielectric properties of poly (vinylidene fluoride- hexafluoropropylene) for electroadhesive high load bearing applications. J Electroceram 50, 23–36 (2023). https://doi.org/10.1007/s10832-022-00301-x

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