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Densities, Ultrasonic Speeds, and Excess Properties of Binary Mixtures of Diethylene Glycol with 1-Butanol, 2-Butanol, and 1,4-Butanediol at Different Temperatures

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Abstract

Densities \(\rho \) and ultrasonic speeds u for pure diethylene glycol, 1-butanol, 2-butanol, and 1,4-butanediol and for their binary mixtures over the entire composition range were measured at 298.15 K, 303.15 K, 308.15 K, and 313.15 K. Using these data, the excess molar volumes, \(V^{E}_\mathrm{m}\), deviations in isentropic compressibilities, \({\varDelta }k_{s}\), apparent molar volumes, \(V_{\phi ,i} \), partial molar volumes, \(\overline{V}_{m,i} \), and excess partial molar volumes, \(\overline{V}_{m,i}^E \), have been calculated over the entire composition range, and also the excess partial molar volumes of the components at infinite dilution, \(\overline{V}_{m,i}^{E,\infty }\) have been calculated. The excess functions have been correlated using the Redlich–Kister equation at different temperatures. The variations of these derived parameters with composition and temperature are presented graphically.

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Authors and Affiliations

  1. Department of Chemistry, Jamia Millia Islamia, Jamia Nagar, New Delhi, 110 025, India

    Anwar Ali, Sana Ansari & Sahar Uzair

  2. Department of Chemistry, Faculty of Medicine, Jazan University, P.O. Box 114, Jazan, Kingdom of Saudi Arabia

    Shadma Tasneem

  3. Department of Chemistry, Faculty of Science, University of Malaya, 50603, Kuala Lumpur, Malaysia

    Firdosa Nabi

Authors
  1. Anwar Ali
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  2. Sana Ansari
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  3. Sahar Uzair
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  4. Shadma Tasneem
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  5. Firdosa Nabi
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Correspondence to Firdosa Nabi.

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Ali, A., Ansari, S., Uzair, S. et al. Densities, Ultrasonic Speeds, and Excess Properties of Binary Mixtures of Diethylene Glycol with 1-Butanol, 2-Butanol, and 1,4-Butanediol at Different Temperatures. Int J Thermophys 36, 3153–3168 (2015). https://doi.org/10.1007/s10765-015-1980-6

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  • DOI: https://doi.org/10.1007/s10765-015-1980-6

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