Skip to main content
SpringerLink
Log in

Measurement and Calculation the Excess Molar Properties of Binary Mixtures Containing Isobutanol, 1-Amino-2-Propanol, and 1-Propanol at Temperatures of (293.15 to 333.15) K

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Densities, ρ, and viscosities, η, of pure isobutanol, 1-amino-2-propanol, and 1-propanol, along with their binary mixtures of {x 1isobutanol + x 21-propanol}, {x 11-amino-2-propanol + x 21-propanol}, and {x 11-amino-2-propanol + x 2isobutanol} were measured over the entire composition range and at temperatures (293.15–333.15) K at ambient pressure (81.5 kPa). Excess molar properties such as the excess molar volume, V Em , partial molar volumes, \( \bar{V}_{1} \) and \( \bar{V}_{2} \), excess partial molar volumes, \( \bar{V}_{1}^{\text{E}} \) and \( \bar{V}_{2}^{\text{E}} \), thermal expansion coefficient, α, excess thermal expansion coefficient, α E, viscosity deviation, Δη, and the excess Gibbs energy of activation, ∆G E*, for the binary mixtures were calculated from the experimental values of densities and viscosities. The excess values of the binary mixtures are negative in the entire composition range and at all temperatures, and increase with increasing temperature. Viscosity deviations, Δη, are negative over the entire composition range and decrease with increasing temperature. The viscosities of the mixtures were correlated by the models of McAllister, Heric, Hind, Katti, and Nissan. The obtained data were correlated by Redlich–Kister equation and the fitting parameters and standard deviations were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Pires, R.M., Costa, H.F., Ferreira, A.G.M., Fonseca, I.M.A.: Viscosity and density of water + ethyl acetate+ethanol mixtures at 298.15 and 318.15 K and atmospheric pressure. J. Chem. Eng. Data 52, 1240–1245 (2007)

    Article  CAS  Google Scholar 

  2. Munoz, R., Burguet, M.C., Morlanes, N., Garcia-Usach, F.: Densities, refractive indices, and excess molar volumes of binary and ternary systems containing isobutyl alcohol, ethanol, 2-ethyl pentane, and methyl tert-butyl ether at 298.15 K. J. Chem. Eng. Data 45, 585–589 (2000)

    Article  CAS  Google Scholar 

  3. Henni, A., Li, J., Tontiwachwuthikul, P.: Reaction kinetics of CO2 in aqueous 1-amino-2-propanol, 3-amino-1-propanol and dimethylmonoethanolamine solutions in temperature range of 298–313 K, using the stopped-flow technique. Ind. Eng. Chem. Res. 47, 2213–2220 (2008)

    Article  CAS  Google Scholar 

  4. Krishna, T.V., Mohan, T.M.: Study of molecular interactions in the polar binary mixtures of N-methyl aniline and alcohols, using excess dielectric and thermodynamic parameters. J. Chem. Thermodyn. 47, 267–275 (2012)

    Article  Google Scholar 

  5. Serbanovic, S.P., Kijevcanin, M.L., Radovic, I.R., Djordjevic, B.D.: Effect of temperature on the excess molar volumes of some alcohol + aromatic mixtures and modelling by cubic EOS mixing rules. Fluid Phase Equilib. 239, 69–82 (2006)

    Article  CAS  Google Scholar 

  6. Dubey, G.P., Kumar, K.: Thermophysical properties of binary liquid mixtures of amine and alcohols at various temperatures. J. Chem. Thermodyn. 50, 7–14 (2012)

    Article  CAS  Google Scholar 

  7. Cacela, C., Duarte, M.L., Fausto, R.: Structural and vibrational characterisation of 3-amino-1-propanol a concerted SCF-MO ab initio, Raman and infrared (matrix isolation and liquid phase) spectroscopy study. Spectrochim. Acta (A) 56, 1051–1064 (2000)

    Article  CAS  Google Scholar 

  8. Dong, L., Chen, J., Gao, G.: Solubility of carbon dioxide in aqueous solutions of 3-amino-1-propanol. J. Chem. Eng. Data 55, 1030–1034 (2010)

    Article  CAS  Google Scholar 

  9. Kermanpour, F., Niakan, H.Z., Sharifi, T.: Density and viscosity measurements of binary alkanol mixtures from (293.15 to 333.15) K at atmospheric pressure. J. Chem. Eng. Data 58, 1086–1091 (2013)

    Article  CAS  Google Scholar 

  10. Dubey, G.P., Kumar, K.: Thermodynamic properties of binary mixtures of diethylene triamine with alcohols at different temperatures. Thermochim. Acta 524, 7–17 (2011)

    Article  CAS  Google Scholar 

  11. Farhan, A.M., Awwad, A.M.: Densities, viscosities, and excess molar enthalpies of 2-pyrrolidone + butanol isomers at T = (293.15, 298.15, and 303.15) K. J. Chem. Eng. Data 54, 2095–2099 (2009)

    Article  CAS  Google Scholar 

  12. Bravo-Sanchez, M.G., Iglesias-Silva, G.A., Estrada-Baltazar, A.: Densities and viscosities of binary mixtures of n-butanol with 2-butanol, isobutanol, and tert-butanol from (303.15 to 343.15) K. J. Chem. Eng. Data 55, 2310–2315 (2010)

    Article  CAS  Google Scholar 

  13. Ali, A., Nain, K., Lal, B., Chand, D.: Densities, viscosities, and refractive indices of binary mixtures of benzene with isomeric butanols at 30 °C. Int. J. Thermophys. 25, 1835–1847 (2004)

    Article  CAS  Google Scholar 

  14. Kermanpour, F., Niakan, H.Z.: Measurement and modeling the excess molar properties of binary mixtures of [C6mim][BF4] + 3-amino-1-propanol and {[C6mim][BF4] + isobutanol}: Application of Prigogine–Flory–Patterson theory. J. Chem. Thermodyn. 48, 129–139 (2012)

    Article  CAS  Google Scholar 

  15. Kermanpour, F., Niakan, H.Z.: Experimental excess molar properties of binary mixtures of (3-amino-1-propanol + isobutanol, 2-propanol) at T = (293.15 to 333.15) K and modeling the excess molar volume by PFP theory. J. Chem. Thermodyn. 54, 10–19 (2012)

    Article  CAS  Google Scholar 

  16. Mokraoui, H., Valtz, A., Coquelet, C., Richon, D.: Volumetric properties of the isopropanol amine–water mixture at atmospheric pressure from 283.15 to 353.15 K. Thermochim. Acta 440, 122–128 (2006)

    Article  CAS  Google Scholar 

  17. Czerkas, S., Burczyk, A., Jadzyn, J., Stokhausen, M.: Viscosity of some propanols and amino propanols in mixtures with 1,4-dioxane. Phys. Chem. Liq. 37, 1–7 (1998)

    Article  CAS  Google Scholar 

  18. Zarei, H.A., Shahvarpour, S.: Volumetric properties of binary and ternary liquid mixtures of 1-propanol (1) + 2-propanol (2) + water (3) at different temperatures and ambient pressure (81.5 kPa). J. Chem. Eng. Data 53, 1660–1668 (2008)

    Article  CAS  Google Scholar 

  19. Zarei, H.A., Jalili, F.: Densities and derived thermoodynamic properties of (2-methoxy ethanol + 1-propanol, or 2-propanol, or 1,2-propandiol) at temperatures from T = (293.15 to 343.15) K. J. Chem. Thermodyn. 39, 55–66 (2007)

    Article  CAS  Google Scholar 

  20. Wieser, M.E.: Atomic weights of the elements 2005 (IUPAC technical report). Pure Appl. Chem. 78, 2051–2066 (2006)

    Article  CAS  Google Scholar 

  21. Wu, T.Y., Chen, B.K., Hao, L., Kuo, C.W., Sun, I.W.: Thermophysical properties of binary mixtures {1-methyl-3-pentylimidazolium tetrafluroborate + polyethylene glycol methyl ether}. J. Taiwan Inst. Chem. Eng. 43, 313–321 (2012)

    Article  Google Scholar 

  22. Li, J.G., Hu, Y.F., Sun, F.S., Liu, Y.S., Liu, Z.C.: Densities and dynamic viscosities of the binary system (water + 1-hexyl-3-methylimidazolium bromide) at different temperatures. J. Chem. Thermodyn. 42, 904–908 (2010)

    Article  CAS  Google Scholar 

  23. Anouti, M., Vigeant, A., Jacquemin, J., Brigouleix, C., Lemordant, D.: Volumetric properties, viscosity and refractive index of the protic ionic liquid, pyrrolidiniumoctanoate, in molecular solvents. J. Chem. Thermodyn. 42, 834–845 (2010)

    Article  CAS  Google Scholar 

  24. McAllister, R.A.: The viscosity of liquid mixtures. AICHE 6, 427–431 (1960)

    Article  CAS  Google Scholar 

  25. Heric, E.L.: On the viscosity of ternary mixtures. J. Chem. Eng. Data 11, 66–68 (1966)

    Article  CAS  Google Scholar 

  26. Viswanath, D.S.: Viscosity of Liquids, Theory, Estimation, Experiment, and Data. Springer, Netherland (2007)

    Google Scholar 

  27. Oswal, S.L., Cheewala, D.B., Prajapati, K.D., Gradas, R.L., Ghael, N.Y., Ijardar, S.P.: Speeds of sound, isentropic compressibilities, viscosities, and excess molar volumes of binary mixtures of alkanoates with tetra- and trichloromethanes at 303.15 K. Thermochim. Acta 426, 141–149 (2005)

    Article  CAS  Google Scholar 

  28. Redlich, O., Kister, A.T.: Algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40, 345–348 (1948)

    Article  Google Scholar 

Download references

Acknowledgement

The research council of Bu-Ali Sina University is appreciated for financial support of this work.

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Bu-Ali Sina University, 65178-38695, Hamadan, Iran

    F. Kermanpour, T. S. Ettefagh & H. Iloukhani

Authors
  1. F. Kermanpour
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. S. Ettefagh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. Iloukhani
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to F. Kermanpour.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 171 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kermanpour, F., Ettefagh, T.S. & Iloukhani, H. Measurement and Calculation the Excess Molar Properties of Binary Mixtures Containing Isobutanol, 1-Amino-2-Propanol, and 1-Propanol at Temperatures of (293.15 to 333.15) K. J Solution Chem 46, 446–460 (2017). https://doi.org/10.1007/s10953-017-0580-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10953-017-0580-4

Keywords

Search

Navigation