Skip to main content
SpringerLink
Log in

Variation of local magnetism in a perovskite manganite La0.7Ca0.3MnO3 by Fe doping

  • Conference Proceeding
  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

Fe doping effect on the local magnetic property of La0.7Ca0.3Mn1−xFexO3 (0.4 ≤ x ≤ 0.55) was investigated by means of 57Fe Mössbauer spectroscopy. The X-ray diffraction patterns and the isomer shifts of the 57Fe Mössbauer spectra demonstrate that all the Fe ions are high-spin trivalent and share the B site lattice positions with Mn ions. The sample of La0.7Ca0.3Mn0.6Fe0.4O3 (x = 0.4) was found to be in the paramagnetic state even at 8 K. For the samples with high Fe contents, however, magnetic sextet(s) arising from local magnetic ordering were observed in the low-temperature spectrum of La0.7Ca0.3Mn0.5Fe0.5O3 (x = 0.5), and also in all the spectra of La0.7Ca0.3Mn0.45Fe0.55O3 (x = 0.55) measured in the range of 8 K—room temperature. These observations suggest that randomly distributed Fe3+ ions interfere with the double exchange interaction in Mn3+–O–Mn4+, and antiferromagnetic ordering arises from superexchange interaction in Fe3+–O–Fe3+ at high Fe content.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

Data availability

The data that support the findings of this study are available from the corresponding author upon reasonable request.

References

  1. Huang, H.Y., Cheong, S.-W., Radaelli, P.G., Marezio, M., Batlogg, B.: Lattice effects on the magnetoresistance in doped LaMnO3. Phys. Rev. Lett. 75, 914 (1995)

    Article  ADS  Google Scholar 

  2. Zener, C.: Interaction between the d-shells in the transition metals. II. Ferromagnetic compounds of manganese with perovskite structure. Phys. Rev. 82, 403 (1951)

    Article  ADS  Google Scholar 

  3. Jin, S., Tiefel, T.H., McCormack, M., Fastnacht, R.A., Ramesh, R., Chen, L.H.: Thousandfold change in resistivity in magnetoresistive La-Ca-Mn-O films. Science. 264, 413–415 (1994)

    Article  ADS  Google Scholar 

  4. Ramirez, A.P.: Colossal magnetoresistance. J. Phys. Condens. Matter. 9, 8171 (1997)

    Article  ADS  Google Scholar 

  5. Govindaraj, R., Sundar, C.S., Lakshmi, L.S., Sridharan, V., Premila, M., Natarajan, D.V.: Perturbed-angular-correlation studies in hafnium doped La0.67Ca0.33MnO3. Chem. Phys. 302, 185–192 (2004)

    Article  Google Scholar 

  6. Lopes, A.M.L., Araújo, J.P., Amaral, V.S., Correia, J.G., Tomioka, Y., Tokura, Y.: New phase transition in the Pr1−xCaxMnO3 system: Evidence for electrical polarization in charge ordered manganites. Phys. Rev. Lett. 100, 155702 (2008)

    Article  ADS  Google Scholar 

  7. Chechersky, V., Nath, A., Isaac, I., Franck, J.P., Ghosh, K., Ju, H., Greene, R.L.: Evidence for breakdown of ferromagnetic order below TC in the manganite La0.8Ca0.2MnO3. Phys. Rev. B. 59, 497 (1999)

    Article  ADS  Google Scholar 

  8. Vanitha, P.V., Nagarajan, R., Rao, C.N.R.: A 57Fe Mössbauer study of charge ordering and phase separation in the rare-earth manganates, Nd0.5Ca0.5MnO3 and Nd0.5Sr0.5MnO3. J. Solid State Chem. 174, 74–76 (2003)

    Article  ADS  Google Scholar 

  9. Reddy, V.R., Rawat, R., Reddy, T.G., Gupta, A., Reddy, P.Y., Reddy, K.R.: 57Fe Mössbauer study of La0.67Ca0.33Mn1-xFexO3 CMR system. Hyperfine Interact. 187, 109 (2008)

    Article  ADS  Google Scholar 

  10. Park, I.J., Kim, S.J., Kim, C.S.: Mössbauer and Magneto Caloric effect for La0.7Ca0.3Mn0.9957Fe0.01O3. J. Supercond. Nov. Magn. 24, 689–692 (2011)

    Article  Google Scholar 

  11. Sanchez, L.C., Durango, D., Arnache, O.: Structural magnetic and Mossbauer study of 57Fe doped La2/3Ca1/3Mn1−xFexO3 (0 ≥ x ≥ 0.1) manganites. J. Phys. Conf. Ser. 687, 012096 (2016)

    Article  Google Scholar 

  12. Terai, T., Kakeshita, T., Fukuda, T., Saburi, T., Takamoto, N., Kindo, K., Honda, M.: Electronic and magnetic properties of (La − Dy)0.7Ca0.3MnO3. Phys. Rev. B. 58, 14908 (1998)

    Article  ADS  Google Scholar 

  13. Sato, W., Komatsuda, S., Shimizu, H., Moriichi, R., Abe, S., Watanabe, S., Komatsu, S., Terai, T., Kawata, S., Ohkubo, Y.: Dynamic motion and freezing of polaronic local structures in a colossal-magnetoresistive perovskite manganite La0.7Ca0.3MnO3 detected with radioactive nuclei. Phys. Rev. B. 100, 184111 (2019)

    Article  ADS  Google Scholar 

  14. Prescher, C., McCammon, C., Dubrovinsky, L.: MossA: a program for analyzing energy-domain Mössbauer spectra from conventional and synchrotron sources. J. Appl. Cryst. 45, 329 (2012)

    Article  ADS  Google Scholar 

  15. Wickman, H.H., Klein, M.P., Shirley, D.A.: Paramagnetic hyperfine structure and relaxation effects in Mössbauer spectra: Fe57 in ferrichrome A. Phys. Rev. 152, 345 (1966)

    Article  ADS  Google Scholar 

  16. Leung, L.K., Morrish, A.H., Evans, B.J.: Magnetic properties of iron-doped manganites. Phys. Rev. B. 13, 4069 (1976)

    Article  ADS  Google Scholar 

  17. Ezekiel, I.P., Moyo, T.: Magnetic properties and Mössbauer investigations of La0.67Sr0.33FexMn1−xO3 (x = 0 and 0.5) perovskites. J. Supercond Nov Magn. 32, 1981–1989 (2019)

    Article  Google Scholar 

  18. Young, S.L., Chen, H.Z., Kao, M.C., Horng, L., Shih, Y.T.: Magnetization processes of polycrystalline La0.7Pb0.3Mn1−xFexO3. J. Magn. Magn. Mater. 303, e351–e354 (2006)

  19. Muthukrishnan, R.M., Mohammed, P., Ansari, Y., Kader, S.M.A.: Analysing the super exchange interaction of Fe3+-O2–Cr3+ on multiferroic structured BiFeO3/LaCrO3 nanocomposite. Phys. B. 665, 415030 (2023)

    Article  Google Scholar 

  20. Tong, W., Zhang, B., Tan, S., Zhang, Y.: Probability of double exchange between Mn and Fe in LaMn1−xFexO3. Phys. Rev. B. 70, 014422 (2004)

    Article  ADS  Google Scholar 

Download references

Acknowledgements

The authors are grateful to Professor Yoshio Kobayashi of The University of Electro-Communications for his technical advice in the Mössbauer measurements. The present work was supported in part by JSPS KAKENHI Grants No. 26286075, 18H03692, and 22K12661.

Funding

W. Sato was supported by JSPS KAKENHI Grants No. 26286075, 18H03692, and 22K12661.

Author information

Authors and Affiliations

  1. Institute of Science and Engineering, Kanazawa University, Kanazawa, Ishikawa, 920-1192, Japan

    W. Sato

  2. Graduate School of Natural Science and Technology, Kanazawa University, Kanazawa, Ishikawa, 920-1192, Japan

    H. Uchino

  3. School of Chemistry, Kanazawa University, Kanazawa, Ishikawa, 920-1192, Japan

    K. Takanashi

Authors
  1. W. Sato
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Uchino
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. Takanashi
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

All the authors contributed to this study and approve the manuscript.

Corresponding author

Correspondence to W. Sato.

Ethics declarations

Ethical approval

Not applicable.

Competing interests

The authors declare no competing interests.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sato, W., Uchino, H. & Takanashi, K. Variation of local magnetism in a perovskite manganite La0.7Ca0.3MnO3 by Fe doping. Hyperfine Interact 244, 17 (2023). https://doi.org/10.1007/s10751-023-01832-7

Download citation

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10751-023-01832-7

Keywords

Search

Navigation