The published data on sulfate-containing glass in silicate, borate, and phosphate systems are reviewed. The experimental data confirm the presence of [SO4]2– groups in an isolated state in all systems, but the possible amount of SO3 in the glass composition is considerably higher in borate and phosphate systems.
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Translated from Steklo i Keramika, No. 5, pp. 7 – 11, May, 2017.
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Bobkova, N.M., Trusova, E.E. Structure of Sulfate-Containing Glasses and the Structural State of SO3 Groups in Them (Review). Glass Ceram 74, 153–157 (2017). https://doi.org/10.1007/s10717-017-9951-y
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DOI: https://doi.org/10.1007/s10717-017-9951-y