Abstract
This paper focuses on stabilisation of kaolin clay at ambient temperature using fly-ash based geopolymer incorporating ground granulated blast-furnace slag (GGBFS). Comprehensive experimental programme was conducted including soil plasticity, compaction, unconfined compressive strength, durability and leaching. These tests were followed by a microstructural analysis using scanning electron microscopy (SEM) technique. An optimisation study using several combinations of geopolymer ingredients was performed, and the role of GGBFS in enhancing the geopolymer-stabilised clay was evaluated. The results indicated that introducing partial replacement of class (F) fly-ash by GGBFS assists, when synthesised in certain ratios, in achieving strength properties of geopolymer-stabilised clay comparable to those of cement stabilised clay. Although a small percentage of geopolymer can improve the soil strength, a larger amount was essential to enhance the wetting–drying durability performance. Under freezing–thawing conditions, low durability performance was detected indicating retardation in the geopolymer reaction at low temperature. For simulated water infiltration, leaching of the activator from geopolymer-stabilised clay was a minor concern in relation to the gel formation and long-term strength gain. Finally, SEM results clearly demonstrated a clay fabric modification attributed to the inter-particle contacts and the corresponding bonding due to the gel formation and hardening.
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References
American Society for Testing and Materials ASTM 559 (2003) Standard test methods for wetting and drying compacted soil-cement mixtures. ASTM, West Conshohcken
American Society for Testing and Materials ASTM D560 (2015) Standard test methods for freezing and thawing compacted soil-cement mixtures. ASTM, West Conshohcken
Bernal SA, Provis JL (2014) Durability of alkali-activated materials: progress and perspectives. J Am Ceram Soc 97:997–1008. https://doi.org/10.1111/jace.12831
Chittoori BC, Puppala AJ, Wejrungsikul T, Hoyos LR (2013) Experimental studies on stabilized clays at various leaching cycles. J Geotech Geoenviron Eng 139:1665–1675. https://doi.org/10.1061/(ASCE)GT.1943-5606.0000920
Cristelo N, Glendinning S, Pinto AT (2011) Deep soft soil improvement by alkaline activation. Proc Inst Civ Eng Ground Improv 164:73–82. https://doi.org/10.1680/grim.900032
Cristelo N, Glendinning S, Miranda T, Oliveira D, Silva R (2012a) Soil stabilisation using alkaline activation of fly ash for self compacting rammed earth construction. Constr Build Mater 36:727–735. https://doi.org/10.1016/j.conbuildmat.2012.06.037
Cristelo N, Glendinning S, Pintio A, Fernandes L (2012b) Effect of calcium content on soil stabilisation with alkaline activation. Constr Build Mater 29:167–174. https://doi.org/10.1016/j.conbuildmat.2011.10.049
Cristelo N, Glendinning S, Fernandes L, Pinto AT (2013a) Effects of alkaline-activated fly ash and Portland cement on soft soil stabilisation. Acta Geotech 8:395–405. https://doi.org/10.1007/s11440-012-0200-9
Cristelo N, Soares E, Rosa I, Miranda T, Oliveira D, Silva R, Chaves A (2013b) Rheological properties of alkaline activated fly ash used in jet grouting applications. Constr Build Mater 48:925–933. https://doi.org/10.1016/j.conbuildmat.2013.07.063
Das BM (2010) Geotechnical engineering handbook. J. Ross Publishing, Plantation
Davidovits J (2008) Geopolymer chemistry and applications. 2nd, ed edn. Institut Géopolymère, Saint-Quentin
Duxson P (2009) Geopolymer precursor design. In: Deventer JLP, Jannie SJV (eds) Geopolymers: structures, processing, properties and industrial applications. Woodhead Publishing, Abingdon, pp 37–49. https://doi.org/10.1533/9781845696382.1.37
Garcia-Lodeiro I, Palomo A, Ernandez-Jimenez AF (2014) An overview of the chemistry of alkali-activated cement-based binders. In: Pacheco-Torgal F, Labrincha J, Leonelli C, Sargent P (eds) Handbook of alkali-activated cements, mortars and concretes. Elsevier Science, Instituto Eduardo Torroja (IETcc-CSIC), Madrid, pp 47–47. https://doi.org/10.1533/9781782422884.1.19
Gianoncelli A, Zacco A, Struis RP, Borgese L, Depero LE, Bontempi E (2013) Fly ash pollutants, treatment and recycling. In: Pollutant diseases, remediation and recycling, vol 4. Environmental chemistry for a sustainable world. Springer, pp 103–213. https://doi.org/10.1007/978-3-319-02387-8_3
Han J (2015) Principles and practice of ground improvement. Wiley, New Jersey
Hardjito D (2005) Studies on fly ash-based geopolymer concrete. Ph.D. Thesis, Curtin University of Technology
Horpibulsuk S, Suksiripattanapong C, Samingthong W, Rachan R, Arulrajah A (2015) Durability against wetting-drying cycles of water treatment sludge-fly ash geopolymer and water treatment sludge-cement and silty clay-cement systems. J Mater Civ Eng 28:04015078. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001351
Hughes P, Glendinning S (2004) Deep dry mix ground improvement of a soft peaty clay using blast furnace slag and red gypsum. Q J Eng Geol Hydrogeol 37:205–216
Karol RH (2003) Chemical grouting and soil stabilization, vol 12, 3rd edn. Marcel Dekker, New Jersey
Khale D, Chaudhary R (2007) Mechanism of geopolymerization and factors influencing its development: a review. J Mater Sci 42:729–746. https://doi.org/10.1007/s10853-006-0401-4
Kirsch K, Bell A (2012) Ground improvement, 3rd edn. CRC Press, New York
Komnitsas K, Zaharaki D (2007) Geopolymerisation: a review and prospects for the minerals industry. Miner Eng 20:1261–1277. https://doi.org/10.1016/j.mineng.2007.07.011
Liew YM et al (2012) Optimization of solids-to-liquid and alkali activator ratios of calcined kaolin geopolymeric powder. Constr Build Mater 37:440–451. https://doi.org/10.1016/j.conbuildmat.2012.07.075
Liu Z, Cai C, Liu F, Fan F (2016) Feasibility study of loess stabilization with fly ash–based geopolymer. J Mater Civ Eng. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001490
Lorenzo GA, Bergado DT (2006) Fundamental characteristics of cement-admixed clay in deep mixing. J Mater Civ Eng 18:161–174. https://doi.org/10.1061/(ASCE)0899-1561(2006)18:2(161)
Markou I, Atmatzidis D (2002) Development of a pulverized fly ash suspension grout. Geotech Geol Eng 20:123–147
McCallister LD, Petry TM (1992) Leach tests on lime-treated clays. Geotech Test J 15:106–114. https://doi.org/10.1520/GTJ10232J
Pacheco-Torgal F (2014) Introduction to handbook of alkali-activated cements, mortars and concretes. In: Handbook of alkali-activated cements, mortars and concretes. Elsevier
Pacheco-Torgal F, Castro-Gomes J, Jalali S (2008) Alkali-activated binders: a review. Part 2. About materials and binders manufacture. Constr Build Mater 22:1315–1322. https://doi.org/10.1016/j.conbuildmat.2007.03.019
Phummiphan I, Horpibulsuk S, Sukmak P, Chinkulkijniwat A, Arulrajah A, Shen S-L (2016) Stabilisation of marginal lateritic soil using high calcium fly ash-based geopolymer. Road Mater Pavement Des 0629:1–15. https://doi.org/10.1080/14680629.2015.1132632
Porbaha A, Shibuya S, Kishida T (2000) State of the art in deep mixing technology. Part III: geomaterial characterization. Proc Inst Civ Eng Ground Improv 4:91–110
Provis JL, Bernal SA (2014) Geopolymers and related alkali-activated materials. Annu Rev Mater Res 44:299–327. https://doi.org/10.1146/annurev-matsci-070813-113515
Rios S, Cristelo N, Viana Da Fonseca A, Ferreira C (2016) Structural performance of alkali-activated soil ash versus soil cement. J Mater Civ Eng. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001398
Roy DM (1999) Alkali-activated cements opportunities and challenges. Cem Concr Res 29:249–254. https://doi.org/10.1016/S0008-8846(98)00093-3
Sargent P, Hughes PN, Rouainia M, White ML (2013) The use of alkali activated waste binders in enhancing the mechanical properties and durability of soft alluvial soils. Eng Geol 152:96–108. https://doi.org/10.1016/j.enggeo.2012.10.013
Shi C, Jiménez AF, Palomo A (2011) New cements for the 21st century: the pursuit of an alternative to Portland cement. Cem Concr Res 41:750–763
Siddique R, Iqbal Khan M, Chandra S, Berntsson L (2011) Fly ash vol 37. Supplementary cementing materials. Springer, Berlin. https://doi.org/10.1007/978-3-642-17866-5_1
Singhi B, Laskar AI, Ahmed MA (2017) Mechanical behavior and sulfate resistance of alkali activated stabilized clayey soil. Geotech Geol Eng 35:1907–1920. https://doi.org/10.1007/s10706-017-0216-x
Standards Australia AS 1289.4.3.1 (1997) Methods of testing soils for engineering purposes-method 4.3.1: soil chemical tests-determination of the pH value of a soil-electrometric method. Sydney
Standards Australia AS 1289.5.1.1 (2003) Method 5.1.1: soil compaction and density tests-determination of the dry density/moisture content relation of a soil using standard compactive effort. Sydney
Standards Australia AS 1289.3.2.1 (2009) Method 3.2.1: soil classification tests-determination of the plastic limit of a soil-standard method. Sydney
Standards Australia AS 1289.3.1.1 (2015) Method 3.9.1: soil classification tests-determination of the liquid limit of a soil. Sydney
Standards Australia AS 3582.1 (1998) Supplementary cementitious materials for use with Portland and blended cement-part 1: fly ash. Sydney
Standards Australia AS 3582.2 (2001) Supplementary cementitious materials for use with Portland and blended cement-part 2: slag-ground granulated iron blast-furnace. Sydney
Standards Australia AS 5101.4 (2008) Methods for preparation and testing of stabilized materials-method 4: unconfined compressive strength of compacted materials. Sydney
Sukmak P, Horpibulsuk S, Shen S-L, Chindaprasirt P, Suksiripattanapong C (2013) Factors influencing strength development in clay–fly ash geopolymer. Constr Build Mater 47:1125–1136. https://doi.org/10.1016/j.conbuildmat.2013.05.104
Verdolotti L, Iannace S, Lavorgna M, Lamanna R (2008) Geopolymerization reaction to consolidate incoherent pozzolanic soil. J Mater Sci 43:865–873. https://doi.org/10.1007/s10853-007-2201-x
Wilkinson A, Haque A, Kodikara J (2010a) Stabilisation of clayey soils with industrial by-products: part A. Proc Inst Civ Eng Ground Improv 163:149–163. https://doi.org/10.1680/grim.2010.163.3.149
Wilkinson A, Haque A, Kodikara J (2010b) Stabilisation of clayey soils with industrial by-products: part B. Proc Inst Civ Eng Ground Improv 163:165–172. https://doi.org/10.1680/grim.2010.163.3.165
Xu H, Van Deventer J (2000) The geopolymerisation of alumino-silicate minerals. Int J Miner Process 59:247–266. https://doi.org/10.1016/S0301-7516(99)00074-5
Yi Y, Li C, Liu S (2014) Alkali-activated ground-granulated blast furnace slag for stabilization of marine soft clay. J Mater Civ Eng 27:04014146. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001100
Yip CK, Lukey G, Van Deventer J (2005) The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation. Cem Concr Res 35:1688–1697
Zhang M, Guo H, El-Korchi T, Zhang G, Tao M (2013) Experimental feasibility study of geopolymer as the next-generation soil stabilizer. Constr Build Mater 47:1468–1478. https://doi.org/10.1016/j.conbuildmat.2013.06.017
Zhang M, Zhao M, Zhang G, Nowak P, Coen A, Tao M (2015) Calcium-free geopolymer as a stabilizer for sulfate-rich soils. Appl Clay Sci 108:199–207. https://doi.org/10.1016/j.clay.2015.02.029
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The authors would like to acknowledge the Higher Committee for Education Development in Iraq for the financial Ph.D. sponsorship provided to the first author.
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Abdullah, H.H., Shahin, M.A. & Sarker, P. Use of Fly-Ash Geopolymer Incorporating Ground Granulated Slag for Stabilisation of Kaolin Clay Cured at Ambient Temperature. Geotech Geol Eng 37, 721–740 (2019). https://doi.org/10.1007/s10706-018-0644-2
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DOI: https://doi.org/10.1007/s10706-018-0644-2