Abstract
Development of multifunctional textile materials is a quest of research today and multifunctional fabrics particularly based on cellulose are highly demanded. Green synthesis of nanoparticles is widely reported; however, the reports on green in situ synthesis of nanoparticles on textile materials is quite limited. Another issue which needs to be addressed through research is the durability of functional properties in case of nanoparticle-containing fabrics. In the present work, linen fabric was first coated with a chitosan-based formulation and the modifed linen was utilized as a backbone for in situ synthesis of silver nanoparticles using tamarind seed coat extract. The modified fabric was characterized and further evaluated for change in appearance using reflectance spectroscopy. The functional properties of the modified linen viz. wrinkle recovery, antibacterial activity, ultraviolet protection, flame retardancy and antioxidant activity were evaluated. The retention of such functional properties against subsequent laundering treatments was evaluated. The brown-coloured modified linen showed efficient functional properties, with bacterial reduction of 100%, UPF rating of 50 + and antioxidant activity of 97% and LOI of 23. The functional properties except flame retardancy were retained to a satisfactory level even after 50 washes. The results obtained were promising enough to claim the resulting material as multifunctional textile material suitable for various technical applications.
Similar content being viewed by others
References
Abdelgawad AM, El-Naggar ME, Hudson SM, Rojas OJ (2017) Fabrication and characterization of bactericidal thiol-chitosan and chitosan iodoacetamide nanofibres. Int J Biol Macromol 94:96–105. https://doi.org/10.1016/J.IJBIOMAC.2016.07.061
Aksit A, Onar Camlibel N, Topel Zeren E, Kutlu B (2017) Development of antibacterial fabrics by treatment with Ag-doped TiO 2 nanoparticles. J Text Inst 108(12):2046–2056. https://doi.org/10.1080/00405000.2017.1311766
Attia NF, Moussa M, Sheta AMF, Taha R, Gamal H (2017) Synthesis of effective multifunctional textile based on silica nanoparticles. Prog Org Coat 106:41–49. https://doi.org/10.1016/J.PORGCOAT.2017.02.006
Bai J, Li Y, Du J, Wang S, Zheng J, Yang Q, Chen X (2007) One-pot synthesis of polyacrylamide-gold nanocomposite. Mater Chem Phys 106(2–3):412–415. https://doi.org/10.1016/J.MATCHEMPHYS.2007.06.021
Coordination compound—structure and bonding of coordination compounds| Britannica.com (1998) Retrieved January 4, 2019, from https://www.britannica.com/science/coordination-compound/Structure-and-bonding-of-coordination-compounds
Danko A, Dunca S, Popescu C, Muresan A (2013) Improving cotton textile materials properties by treating with chitosan and metallic salts. Ind Text 64(4):204–209
Deshpande RH, Chavan KG (2013) Ultraviolet-blocking cotton textiles using nano-TiO2. Melliand Int 19(4):227–229
Ding L, Xiang C, Zhou G (2018) Silica nanoparticles coated by poly(acrylic acid) brushes via host-guest interactions for detecting DNA sequence of Hepatitis B virus. Talanta 181:65–72. https://doi.org/10.1016/J.TALANTA.2017.12.061
El-Hameed El-Ebissy AA, Michael MN, Eldin Abdelhameed SK (2016) Effect of nano zinc oxide on the structural characteristic, tensile thermal properties of textile fabrics. J Ind Text 46(1):130–142. https://doi.org/10.1177/1528083715576321
El-Naggar ME, Hassabo AG, Mohamed AL, Shaheen TI (2017) Surface modification of SiO2 coated ZnO nanoparticles for multifunctional cotton fabrics. J Colloid Interface Sci 498:413–422. https://doi.org/10.1016/J.JCIS.2017.03.080
El-Shafei A, ElShemy M, Abou-Okeil A (2015) Eco-friendly finishing agent for cotton fabrics to improve flame retardant and antibacterial properties. Carbohydr Polym 118:83–90. https://doi.org/10.1016/J.CARBPOL.2014.11.007
El-Tahlawy K, Elbendary M, Elhendawy A, Hudson S (2005) The antimicrobial activity of cotton fabrics treated with different crosslinking agents and chitosan. Carbohydr Polym 60(4):421–430. https://doi.org/10.1016/j.carbpol.2005.02.019
Farouk A, Sharaf S, El-Hady MMA (2013) Preparation of multifunctional cationized cotton fabric based on TiO2 nanomaterials. Int J Biol Macromol 61:230–237. https://doi.org/10.1016/J.IJBIOMAC.2013.06.022
Faunce T, Watal A (2010) Nanosilver and global public health: international regulatory issues. Nanomedicine 5(4):617–632
Gordon O, Slenters TV, Brunetto PS, Villaruz AE, Sturdevant DE, Otto M, Fromm KM (2010) Silver coordination polymers for prevention of implant infection: thiol interaction, impact on respiratory chain enzymes, and hydroxyl radical induction. Antimicrob Agent Chemother 54(10):4208–4218. https://doi.org/10.1128/AAC.01830-09
Gouda M, Keshk SMAS (2010) Evaluation of multifunctional properties of cotton fabric based on metal/chitosan film. Carbohydr Polym 80(2):504–512. https://doi.org/10.1016/J.CARBPOL.2009.12.011
Haji A (2017) Improved natural dyeing of cotton by plasma treatment and chitosan coating; optimization by response surface methodology. Cellul Chem Technol 51(9–10):975–982
Haji A, Qavamnia SS, Bizhaem FK (2016) Salt free neutral dyeing of cotton with anionic dyes using plasma and chitosan treatments. Ind Text 67:109–113
Haji A, Qavamnia SS, Nasiriboroumand M (2018) The use of D-optimal design in optimization of wool dyeing with Juglans regia bark. Ind Text 69(2):104–110
Hassabo AG, El-Naggar ME, Mohamed AL, Hebeish AA (2019) Development of multifunctional modified cotton fabric with tri-component nanoparticles of silver, copper and zinc oxide. Carbohydr Polym 210:144–156. https://doi.org/10.1016/J.CARBPOL.2019.01.066
Hebeish A, Sharaf S, Farouk A (2013) Utilization of chitosan nanoparticles as a green finish in multifunctionalization of cotton textile. Int J Biol Macromol 60:10–17. https://doi.org/10.1016/j.ijbiomac.2013.04.078
Jeon HJ, Kim JS, Kim TG, Kim JH, Yu WR, Youk JH (2008) Preparation of poly(ε-caprolactone)-based polyurethane nanofibers containing silver nanoparticles. Appl Surf Sci 254(18):5886–5890. https://doi.org/10.1016/j.apsusc.2008.03.141
Kumar CS, Bhattacharya S (2008) Tamarind seed: properties, processing and utilization. Crit Rev Food Sci Nutr 48(1):1–20. https://doi.org/10.1080/10408390600948600
Li Y, Wang B, Sui X, Xie R, Xu H, Zhang L, Mao Z (2018) Durable flame retardant and antibacterial finishing on cotton fabrics with cyclotriphosphazene/polydopamine/silver nanoparticles hybrid coatings. Appl Surf Sci 435:1337–1343. https://doi.org/10.1016/J.APSUSC.2017.11.269
Mohamed AL, El-Naggar ME, Shaheen TI, Hassabo AG (2016) Novel nano polymeric system containing biosynthesized core shell silver/silica nanoparticles for functionalization of cellulosic based material. Microsyst Technol 22(5):979–992. https://doi.org/10.1007/s00542-015-2776-0
Mowafi S, Rehan M, Mashaly HM, Abou El-Kheir A, Emam HE (2017) Influence of silver nanoparticles on the fabrics functions prepared by in situ technique. J Text Inst 108(10):1828–1839. https://doi.org/10.1080/00405000.2017.1292649
Mulfinger L, Solomon SD, Bahadory M, Jeyarajasingam AV, Rutkowsky SA, Boritz C (2007) Synthesis and study of silver nanoparticles. J Chem Educ 84(2):322. https://doi.org/10.1021/ed084p322
Naebe M, Li Q, Onur A, Denning R (2016) Investigation of chitosan adsorption onto cotton fabric with atmospheric helium/oxygen plasma pre-treatment. Cellulose 23(3):2129–2142. https://doi.org/10.1007/s10570-016-0915-0
Prabhu KH, Teli MD (2014) Eco-dyeing using Tamarindus indica L. seed coat tannin as a natural mordant for textiles with antibacterial activity. J Saudi Chem Soc 18(6):864–872. https://doi.org/10.1016/j.jscs.2011.10.014
Rehan M, El-Naggar ME, Mashaly HM, Wilken R (2018) Nanocomposites based on chitosan/silver/clay for durable multi-functional properties of cotton fabrics. Carbohydr Polym 182:29–41. https://doi.org/10.1016/J.CARBPOL.2017.11.007
Rice-Evans C, Miller N, Paganga G (1997) Antioxidant properties of phenolic compounds. Trends Plant Sci 2(4):152–159. https://doi.org/10.1016/S1360-1385(97)01018-2
Sadu RB, Chen DH, Kucknoor AS, Guo Z, Gomes AJ (2014) Silver-doped TiO2/polyurethane nanocomposites for antibacterial textile coating. BioNanoScience 4(2):136–148. https://doi.org/10.1007/s12668-014-0125-x
Sharma VK, Yngard RA, Lin Y (2009) Silver nanoparticles: green synthesis and their antimicrobial activities. Adv Colloid Interface Sci 145(1–2):83–96. https://doi.org/10.1016/J.CIS.2008.09.002
Sheikh J, Bramhecha I (2018) Multifunctional modification of linen fabric using chitosan-based formulations. Int J Biol Macromol 118:896–902. https://doi.org/10.1016/j.ijbiomac.2018.06.150
Sinchaiyakit P, Ezure Y, Sriprang S, Pongbangpho S, Povichit N, Suttajit M (2011) Tannins of tamarind seed husk: preparation, structural characterization, and antioxidant activities. Nat Prod Commun 6(6):829–834
Song KC, Lee SM, Park TS, Lee BS (2009) Preparation of colloidal silver nanoparticles by chemical reduction method. Korean J Chem Eng 26(1):153–155. https://doi.org/10.1007/s11814-009-0024-y
Taghiyari HR (2012) Fire-retarding properties of nano-silver in solid woods. Wood Sci Technol 46(5):939–952. https://doi.org/10.1007/s00226-011-0455-6
Teli MD, Sheikh J (2012) Antibacterial and acid and cationic dyeable bamboo cellulose (rayon) fabric on grafting. Carbohydr Polym 88(4):1281–1287
Teli MD, Sheikh J (2013) Study of grafted silver nanoparticle containing durable antibacterial bamboo rayon. Cellul Chem Technol 47(1–2): 69–75
Teli MD, Sheikh J, Mahalle K, Labade V, Trivedi R (2012) Application of Tamarind seed coat in dyeing of cotton and silk using catechu and henna. J Text Assoc 73(2):90–95
Teli MD, Sheikh J, Bhavsar P (2013) Multifunctional finishing of cotton using chitosan extracted from bio-waste. Int J Biol Macromol 54:125–130. https://doi.org/10.1016/j.ijbiomac.2012.12.007
Tripathi R, Narayan A, Bramhecha I, Sheikh J (2019) Development of multifunctional linen fabric using chitosan film as a template for immobilization of in situ generated CeO2 nanoparticles. Int J Biol Macromol 121:1154–1159. https://doi.org/10.1016/J.IJBIOMAC.2018.10.067
Tsuda T, Watanabe M, Ohshima K, Yamamoto A, Kawakishi S, Osawa T (1994) Antioxidative Components Isolated from the Seed of Tamarind (Tamarindus indica L.). J Agric Food Chem 42:2671–2674
Zhang M, Pang J, Bao W, Zhang W, Gao H, Wang C, Li J (2017) Antimicrobial cotton textiles with robust superhydrophobicity via plasma for oily water separation. Appl Surf Sci 419:16–23. https://doi.org/10.1016/j.apsusc.2017.05.008
Zhou Y, Yang Z-Y, Tang R-C (2018) Green and facile fabrication of AgNPs@ silk for colorful and multifunctional textiles using baicalin as a natural reductant. J Clean Prod 170:940–949. https://doi.org/10.1016/J.JCLEPRO.2017.09.213
Acknowledgment
Authors gratefully acknowledge Science and Engineering research board (S.E.R.B.), Department of Science and Technology, Government of India for project funding (ECR/2017/001041).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Sheikh, J., Bramhecha, I. Multi-functionalization of linen fabric using a combination of chitosan, silver nanoparticles and Tamarindus Indica L. seed coat extract. Cellulose 26, 8895–8905 (2019). https://doi.org/10.1007/s10570-019-02684-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10570-019-02684-7