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A reactive fluorine-free, efficient superhydrophobic and flame-retardant finishing agent for cotton fabrics

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Abstract

A novel finishing agent, N,N-dimethyl-octadecyl phosphate acrylamide (NDOPA), was synthesized with octadecanol, phosphorous acid, formaldehyde and acrylamide, and applied to cotton fabrics by ultraviolet curing to endow cotton fabrics with superhydrophobicity and flame retardancy. Results showed that NDOPA could be grafted onto cotton fabrics through C–O–C covalent bonds during the ultraviolet curing process. The contact angle of cotton fabric treated with the 10% NDOPA agent could reach 157.5°. The treated cotton fabrics exhibited clear flame retardancy. The treated cotton retained strong hydrophobicity and flame retardancy after 30 laundering cycles, indicating that the treated cotton fabrics had excellent durability. Thermogravimetric analysis revealed that the treated samples had flame-retardant properties. The results of Fourier-transform infrared spectroscopy, energy dispersive X-ray analysis and scanning electron micrography showed that NDOPA was successfully grafted onto the cotton fabrics; X-ray diffraction analysis indicated that the crystallized structure of treated cotton fibers nearly did not change.

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References

  • Alongi J, Malucelli G (2015) Cotton flame retardancy: state of the art and future perspectives. RSC Adv 5:24239–24263

    Article  CAS  Google Scholar 

  • Alongi J, Carosio F, Malucelli G (2012a) Influence of ammonium polyphosphate-/poly(acrylic acid)-based layer by layer architectures on the char formation in cotton, polyester and their blends. Polym Degrad Stab 97:1644–1653

    Article  CAS  Google Scholar 

  • Alongi J, Colleoni C, Malucelli G, Rosaceb G (2012b) Hybrid phosphorus-doped silica architectures derived from a multistep sol–gel process for improving thermal stability and flame retardancy of cotton fabrics. Polym Degrad Stab 97:1334–1344

    Article  CAS  Google Scholar 

  • Alongi J, Milnes J, Malucelli G, Bourbigot S, Kandola B (2014) Thermal degradation of DNA-treated cotton fabrics under different heating conditions. J Anal Appl Pyrolysis 108:212–221

    Article  CAS  Google Scholar 

  • Annalisa C, Francesca B, Giulio M, Chiara M, Monica P (2016) DNA-chitosan cross-linking and photografting to cotton fabrics to improve washing fastness of the fire-resistant finishing. Cellulose 23:3963–3984

    Article  CAS  Google Scholar 

  • Chang SC, Slopek RP, Condon B, Grunlan JC (2014) Surface coating for flame-retardant behavior of cotton fabric using a continuous layer-by-layer process. Ind Eng Chem Res 53:3805–3812

    Article  CAS  Google Scholar 

  • Cheema HA, Elshafei A, Hauser PJ (2013) Conferring flame retardancy on cotton using novel halogen-free flame retardant bifunctional monomers: synthesis, characterizations and applications. Carbohydr Polym 92:885–893

    Article  CAS  PubMed  Google Scholar 

  • Colleoni C, Donelli I, Freddi G, Guido E, Migani V, Rosace G (2013) A novel sol–gel multi-layer approach for cotton fabric finishing by tetraethoxysilane precursor. Surf Coat Technol 235:192–203

    Article  CAS  Google Scholar 

  • Feng Y, Zhou Y, Li D, He S, Zhang F, Zhang G (2017) A plant-based reactive ammonium phytate for use as a flame-retardant for cotton fabric. Carbohydr Polym 175:636–644

    Article  CAS  PubMed  Google Scholar 

  • French AD (2013) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896

    Article  CAS  Google Scholar 

  • Gao W-W, Zhang G-X, Zhang F-X (2015) Enhancement of flame retardancy of cotton fabrics by grafting a novel organic phosphorous-based flame retardant. Cellulose 22:2787–2796

    Article  CAS  Google Scholar 

  • Horrocks AR (2013) Textile flammability research since 1980—personal challenges and partial solutions. Polym Degrad Stab 98:2813–2824

    Article  CAS  Google Scholar 

  • Huang Z, Gurney RS, Wang T, Liu D (2018) Environmentally durable superhydrophobic surfaces with robust photocatalytic self-cleaning and self-healing properties prepared via versatile film deposition methods. J Colloid Interface Sci 527:107–116

    Article  CAS  PubMed  Google Scholar 

  • Jia Y, Hu Y, Zheng D, Zhang G, Zhang F, Liang Y (2016) Synthesis and evaluation of an efficient, durable, and environmentally friendly flame retardant for cotton. Cellulose 24:1159–1170

    Article  CAS  Google Scholar 

  • Jing J, Zhang Y, Fang Z-P, Wang D-Y (2018) Core-shell flame retardant/graphene oxide hybrid: a self-assembly strategy towards reducing fire hazard and improving toughness of polylactic acid. Compos Sci Technol 165:161–167

    Article  CAS  Google Scholar 

  • Keil DE, Mehlmann T, Butterworth L, Pedenadams MM (2008) Gestational exposure to perfluorooctane sulfonate suppresses immune function in B6C3F1 mice. Toxicol Sci 103:77–85

    Article  CAS  PubMed  Google Scholar 

  • Lee CH, Johnson N, Drelich J, Yap YK (2011) The performance of superhydrophobic and superoleophilic carbon nanotube meshes in water–oil filtration. Carbon 49:669–676

    Article  CAS  Google Scholar 

  • Li Y, Li L, Sun J (2010) Bioinspired self-healing superhydrophobic coatings. Angew Chem Int Ed 49:6129–6133

    Article  CAS  Google Scholar 

  • Li Z-F, Zhang C-J, Cui L, Zhu P, Yan C, Liu Y (2017) Fire retardant and thermal degradation properties of cotton fabrics based on APTES and sodium phytate through layer-by-layer assembly. J Anal Appl Pyrolysis 123:216–223

    Article  CAS  Google Scholar 

  • Lin D, Zeng X, Li H, Lai X (2018) Facile fabrication of superhydrophobic and flame-retardant coatings on cotton fabrics via layer-by-layer assembly. Cellulose 25:3135–3149

    Article  CAS  Google Scholar 

  • Lin D, Zeng X, Li H, Lai X, Wu T (2019) One-pot fabrication of superhydrophobic and flame-retardant coatings on cotton fabrics via sol-gel reaction. J Colloid Interface Sci 533:198–206

    Article  CAS  PubMed  Google Scholar 

  • LTD DVRPRTP (1934) International year of natural fibres: 2009. Carnegie Endowment for International Peace

  • Maciejewski H, Karasiewicz J, Dutkiewicz M, Marciniec B (2015) Hydrophobic materials based on fluorocarbofunctional spherosilicates. Silicon 7:1–9

    Article  CAS  Google Scholar 

  • Mckeen LW (2006) Fluorinated coatings and finishes handbook. Elsevier, p 395

  • Nguyen TM, Chang SC, Condon B, Slopek R, Graves E, Yoshiokatarver M (2013) Structural effect of phosphoramidate derivatives on the thermal and flame retardant behaviors of treated cotton cellulose. Ind Eng Chem Res 52:4715–4724

    Article  CAS  Google Scholar 

  • Pan H et al (2015) Construction of layer-by-layer assembled chitosan/titanate nanotubes based nanocoating on cotton fabrics: flame retardant performance and combustion behavior. Cellulose 22:911–923

    Article  CAS  Google Scholar 

  • Qian Y, Zhou S, Chen X (2018) Synergistic flame retardant effect between nano-silicon dioxide and layered double hydroxides in ethylene vinyl acetate composites. J Thermoplast Compos Mater 31:1295–1309

    Article  CAS  Google Scholar 

  • Rosace G, Colleoni C, Trovato V, Iacono G, Malucelli G (2017) Vinylphosphonic acid/methacrylamide system as a durable intumescent flame retardant for cotton fabric. Cellulose 24:3095–3108

    Article  CAS  Google Scholar 

  • Shanti R, Bella F, Salim YS, Chee SY, Ramesh S, Ramesh K (2016) Poly(methyl methacrylate-co-butyl acrylate-co-acrylic acid): physico-chemical characterization and targeted dye sensitized solar cell application. Mater Des 108:560–569

    Article  CAS  Google Scholar 

  • Sun D, Wang W, Yu D (2017) Highly hydrophobic cotton fabrics prepared with fluorine-free functionalized silsesquioxanes. Cellulose 24:4519–4531

    Article  CAS  Google Scholar 

  • Suryaprabha T, Sethuraman MG (2018) Fabrication of superhydrophobic and enhanced flame-retardant coatings over cotton fabric. Cellulose 25:3151–3161

    Article  CAS  Google Scholar 

  • Tragoonwichian S, Kothary P, Siriviriyanun A, O’Rear EA, Yanumet N (2011) Silicon-compound coating for preparation of water repellent cotton fabric by admicellar polymerization. Colloids Surf 384:381–387

    Article  CAS  Google Scholar 

  • Wei C, Tang Y, Zhang G, Zhang Q, Zhan X, Chen F (2016) Facile fabrication of highly omniphobic and self-cleaning surfaces based on water mediated fluorinated nanosilica aggregation. RSC Adv 6:74340–74348

    Article  CAS  Google Scholar 

  • Xing W, Jie G, Song L, Hu S, Lv X, Wang X, Hu Y (2011) Flame retardancy and thermal degradation of cotton textiles based on UV-curable flame retardant coatings. Thermochim Acta 513:75–82

    Article  CAS  Google Scholar 

  • Xue C-H, Chen J, Yin W, Jia S-T, Ma J-Z (2012) Superhydrophobic conductive textiles with antibacterial property by coating fibers with silver nanoparticles. Appl Surf Sci 258:2468–2472

    Article  CAS  Google Scholar 

  • Zhang D et al (2017) Flame retardant and hydrophobic coatings on cotton fabrics via sol-gel and self-assembly techniques. J Colloid Interface Sci 505:892–899

    Article  CAS  PubMed  Google Scholar 

  • Zheng D, Zhou J, Zhong L, Zhang F, Zhang G (2016) A novel durable and high-phosphorous-containing flame retardant for cotton fabrics. Cellulose 23:2211–2220

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. College of Textile and Garment, Southwest University, No. 2 Tiansheng Street, Beibei, Chongqing, 400716, China

    Shengnan Li, Shuo Huang, Dingfei Wang & Guangxian Zhang

  2. Chongqing Municipality Fiber Inspection Bureau, Chongqing, 401121, China

    Ling Zhong

  3. China Institute of Bioorganic and Medicinal Chemistry, College of Chemistry and Chemical Engineering, Southwest University, Chongqing, 400716, China

    Fengxiu Zhang

  4. Chongqing Engineering Research Center of Biomaterial Fiber and Modem Textile, Chongqing, 400716, China

    Shengnan Li, Shuo Huang, Dingfei Wang & Guangxian Zhang

Authors
  1. Shengnan Li
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  2. Ling Zhong
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  3. Shuo Huang
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  4. Dingfei Wang
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  5. Fengxiu Zhang
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  6. Guangxian Zhang
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Correspondence to Guangxian Zhang.

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Li, S., Zhong, L., Huang, S. et al. A reactive fluorine-free, efficient superhydrophobic and flame-retardant finishing agent for cotton fabrics. Cellulose 26, 6333–6347 (2019). https://doi.org/10.1007/s10570-019-02503-z

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  • DOI: https://doi.org/10.1007/s10570-019-02503-z

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