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Synthesis of Porous Polymer Based Solid Acid Catalyst Towards Room Temperature Thioacetal/Thioketal Formation

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Abstract

Both the alkyl sulfonic acid and phenyl sulfonic acid groups were incorporated onto a hypercrosslinked porous polymer through copolymerization and post-sulfonation to form novel PDVB-SO3H-SO3H catalyst. The porous polymer based solid acid. PDVB-SO3H-SO3H was applied to the cayaltic synthesis of thioacetal (thioketal) at room temperature. N2 adsorption isotherm experiments demonstrated that the catalyst possessed the significantly high BET surface area. In comparison with conventional homogeneous acid catalysts such as sulfuric acid and p-toluenesulfonic acid, the porous polymer based solid acid. PDVB-SO3H-SO3H showed several noteworthy advantages, including remarkable catalytic activity at room temperature and mild reaction conditions, broad substrates scope, high specific surface area, exceptional acid strength, flexible hydrophobicity, and excellent recyclability. These exceptional features make the polymer a highly promising candidate for diverse industrial applications.

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Acknowledgements

Financial supports from the Natural Science Foundation of Zhejiang Province (LQ22B040003, LY24B040001), the Key Research and Development Program of Zhejiang Province (2021C01080), the Fundamental Research Funds of Zhejiang Sci-Tech University (23062110-Y, 21062113-Y), are gratefully acknowledged.

Funding

The Natural Science Foundation of Zhejiang Province, LQ22B040003, LY24B040001, the Fundamental Research Funds of Zhejiang Sci-Tech University, 21062113-Y, 23062110-Y, the Key Research and Development Program of Zhejiang Province, 2021C01080.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Zhejiang Sci-Tech University, Hangzhou, Zhejiang, 310018, People’s Republic of China

    Bojiang Chen,  Rukhsana, Fu-Gang Zhao, Xunshan Liu & Yong-Miao Shen

  2. Kente Catalysts Inc, Xianju, 317300, People’s Republic of China

    Jianping Wu & Fei-Yong Xiang

  3. School of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing, 312000, People’s Republic of China

    Xuezheng Liang

  4. Zhejiang Sci-Tech University Shengzhou Innovation Research Institute, Shengzhou, 312400, People’s Republic of China

    Xunshan Liu & Yong-Miao Shen

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  1. Bojiang Chen
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Contributions

Xunshan Liu has made the draft and appropriate revision of the article, and put forward some suggestions for modification. Xuezheng Liang has made the planning of the experiment. Yong‑Miao Shen provided the ideas of this paper. In the process of the work, all of us has made efficient discussions, which played a good role in promoting the completion of the whole work.

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Correspondence to Yong-Miao Shen.

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Chen, B., Wu, J., Rukhsana et al. Synthesis of Porous Polymer Based Solid Acid Catalyst Towards Room Temperature Thioacetal/Thioketal Formation. Catal Lett (2024). https://doi.org/10.1007/s10562-024-04606-0

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