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Carbon Sphere Anchored Hydroxylamino-Decorated Ionic Liquids for CO2 Fixation into Cyclic Carbonates at Mild Conditions

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Abstract

A series of carbon sphere supported with adjustable alkyl length substitutes polymeric ionic liquids bearing hydroxylamino-anchored functional groups by covalent connection were fabricated from copolymerization of carbon sphere with vinyl based monomeric ionic liquids, which were constructed from 1-glycidyl-3-vinylimidazolium bromide and alkyl amines. The carbon sphere hybrid polymeric ionic liquids were characterized by FT-IR, SEM–EDS, N2 adsorption/desorption isotherm, elemental analysis, 13C MAS NMR and XPS, which were candidated as heterogeneous catalysts for CO2-epoxide cycloaddition reactions to product cyclic carbonates at mild conditions without co-catalyst and metal ion. The introduced functional groups on carbon sphere could accelerate the reaction process and yields of above 90% were obtained for various cyclic carbonates under optimized conditions. Finally, kinetic experiments were also carried out to reveal reaction mechanism and the activated energy was determined as 114.9 kJ/mol. Therefore, this study provides a new approach to fabricate multifunctional heterogeneous materials for coupling reaction of CO2 under mild conditions.

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Funding

This work was supported by the Central Guidance on Local Science and Technology Development Fund of Hebei Province (226Z4304G), the Hebei Natural Science Foundation (B2023402022, E2021402017), the Science Foundation of Handan City (21422303245).

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  1. Key Laboratory of CO2 Utilization of Handan City, Hebei University of Engineering, Handan, 056038, People’s Republic of China

    Yanhui Kang, Xiaopeng Li, Jinwei Zhang, Shenjun Qin, Yongjing Hao, Balaji Panchal, Tao Chang & Zheng Zhu

  2. Key Laboratory of Heterocyclic Compounds of Hebei Province, Handan College, Handan, 056005, Hebei, China

    Tao Chang & Zheng Zhu

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  1. Yanhui Kang
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Kang, Y., Li, X., Zhang, J. et al. Carbon Sphere Anchored Hydroxylamino-Decorated Ionic Liquids for CO2 Fixation into Cyclic Carbonates at Mild Conditions. Catal Lett 154, 1611–1621 (2024). https://doi.org/10.1007/s10562-023-04443-7

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