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Solvothermal Synthesis of FDU-12 Derived Ni-Phyllosilicate Using Double Solvent of H2O and n-Pentane

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Abstract

In order to inhibit the serious damage of pore structure of silica template during the conventional hydrothermal method to prepare Ni-phyllosilicate material, a solvothermal method using double solvent, a small amount of water and a large amount of hydrophobic n-pentane, was proposed to synthesize FDU-12 derived Ni-phyllosilicate in this work. Water can infiltrate the inside channels of FDU-12 owing to more hydrophilic silica hydroxyl groups, and the hydrophobic n-pentane tends to surround the outside of FDU-12. The growth of Ni-phyllosilicate occured only inside channels rather than surface, and the addition of urea could improve its formation at 180 °C in 12 h. As a result, the optimal catalyst retained the pore structure of FDU-12 and obtained fine Ni particle size of 1.5 nm after 750 °C reduction in H2 flow, which exhibited CO2 conversion of 77.0% and CH4 selectivity of 94.7% at 450 °C, 60 L·g−1·h−1. In addition, this catalyst showed high long-term stability in a 100 h-lifetime test with high anti-sintering property derived from Ni-phyllosilicate.

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Acknowledgements

The authors gratefully acknowledge the supports from Foundation of Division of Chemical Sciences of Qingdao University of Science and Technology (No. QUSTHX201912).

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Authors and Affiliations

  1. Key Laboratory of Low Carbon Energy and Chemical Engineering, Shandong University of Science and Technology, Qingdao, 266590, China

    Yaqi Chen, Hao Dong, Tengfei Zhang & Qing Liu

  2. Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, Shandong, China

    Tengfei Zhang

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  1. Yaqi Chen
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  2. Hao Dong
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  4. Qing Liu
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Correspondence to Qing Liu.

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Chen, Y., Dong, H., Zhang, T. et al. Solvothermal Synthesis of FDU-12 Derived Ni-Phyllosilicate Using Double Solvent of H2O and n-Pentane. Catal Lett 152, 1488–1494 (2022). https://doi.org/10.1007/s10562-021-03748-9

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