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CeO2-Promoted Ni/SiO2 Catalysts for Carbon Dioxide Reforming of Methane: The Effect of Introduction Methodologies

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Abstract

Three typical methods, subsequent coating, co-impregnation and sequential impregnation, were employed to investigate the effect of introduction methodologies for CeO2-promoted Ni/SiO2 catalysts. The CeO2@Ni/SiO2 catalyst prepared with the subsequent coating method was found to exhibit the best initial activity and superior long-term stability in CO2 reforming of methane. Comparative characterizations documented that small Ni size and intimate Ni–CeO2 contact were generated on the CeO2@Ni/SiO2 catalyst, leading to excellent reforming activity. In addition, pronounced redox property and strong surface basicity were created on the CeO2@Ni/SiO2 catalyst, resulting in exceptional coke resistance and thus superior long-term stability. This work unravels the impact of various introduction methods on the catalyst structure, which would help design robust nanocomposite catalysts with outstanding catalytic performance.

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Acknowledgements

The financial support from National Natural Science Foundation of China (21776007, 21811530293, 22078016), National Key Research and Development Project (No. 2018YFE0107400) and Fundamental Research Funds for the Central Universities (XK1802-1) is sincerely acknowledged.

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Authors and Affiliations

  1. State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Energy Environmental Catalysis, Beijing University of Chemical Technology, Beijing, 100029, People’s Republic of China

    Yu Guo, Long Tian, Wangwei Yan, Ronghua Qi, Weixia Tu & Zhou-jun Wang

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  1. Yu Guo
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  2. Long Tian
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  3. Wangwei Yan
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  4. Ronghua Qi
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  5. Weixia Tu
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Correspondence to Weixia Tu or Zhou-jun Wang.

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Guo, Y., Tian, L., Yan, W. et al. CeO2-Promoted Ni/SiO2 Catalysts for Carbon Dioxide Reforming of Methane: The Effect of Introduction Methodologies. Catal Lett 151, 2144–2152 (2021). https://doi.org/10.1007/s10562-020-03479-3

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  • DOI: https://doi.org/10.1007/s10562-020-03479-3

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