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Bimetallic Ni–Pd Synergism—Mixed Metal Catalysis of the Mizoroki-Heck Reaction and the Suzuki–Miyaura Coupling of Aryl Bromides

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Abstract

A combination of Pd and Ni complexes activated aryl bromides for the thermal Mizoroki-Heck reaction and Suzuki coupling giving high yields in short reaction times. A thermal redox mechanism probably occurs whereby Ni complex transfers electron and reduces the Pd (II) to Pd (0) which then takes the reactants through the standard protocol of oxidative-addition, migratory insertion and reductive elimination, typical for the Mizoroki-Heck reaction and the Suzuki coupling.

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Acknowledgements

Financial support from the CSIR Network Project, ORIGIN—under XII Five year plan CSC 0108 and PA-II post to VPP is gratefully acknowledged.

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Authors and Affiliations

  1. Organic Chemistry Division, National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune, Maharashtra, 411008, India

    Abhijit A. Kashid, Dharmaraj J. Patil, Ramling D. Mali, Vijay P. Patil, T. V. Neethu & Suresh Iyer

  2. Academy of Scientific and Innovative Research (AcSIR), New Delhi, 110025, India

    Suresh Iyer

  3. Abasaheb Garware College, Karve Road, Pune, Maharashtra, 411004, India

    Heena K. Meroliya & Shobha A. Waghmode

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  1. Abhijit A. Kashid
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Correspondence to Suresh Iyer.

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Kashid, A.A., Patil, D.J., Mali, R.D. et al. Bimetallic Ni–Pd Synergism—Mixed Metal Catalysis of the Mizoroki-Heck Reaction and the Suzuki–Miyaura Coupling of Aryl Bromides. Catal Lett 151, 353–358 (2021). https://doi.org/10.1007/s10562-020-03330-9

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