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Mont-K10 Supported Fe(II) Schiff-Base Complex as an Efficient Catalyst for Hydrogenation of Ketones

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Abstract

A new Fe(II) Schiff base complex anchored on mont-K10 (Fe@imine-mont-K10) was synthesized and extensively characterized by FTIR, powder X-ray diffraction, SEM–EDX, TEM, ESR, X-ray photoelectron spectroscopy (XPS), BET surface area measurement, solid state 29Si NMR and ICP-AES analysis. The catalytic activity of the complex was investigated for hydrogenation of ketones. The results indicated that it exhibited good catalytic activity for hydrogenation of aromatic as well as aliphatic ketones in i-PrOH/CH3CN (1:1) using Na-i-OPr as base at 80 °C resulting in moderate to excellent isolated yields (51–99%) of their corresponding products. The catalyst shows good reusability.

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Acknowledgements

The authors thank SAIF, IIT Bombay for ESR and ICP-AES facilities, SAIF, NEHU, Shillong for TEM and 1H-NMR facilities, SAIF, IISC Bangalore for 29Si NMR facilities, SAIF, STIC, Kochi University, Kochi for 1H-NMR facilities, ACMS, IIT Kanpur for X-ray photoelectron spectroscopic facilities and BIT, Bangalore for BET surface area measurement facilities. S. Sultana gratefully thanks UGC-SAP-DRS-I programme (2016-2021) and UGC-Maulana Azad National Fellowship, Delhi for financial support.

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  1. Department of Chemistry, Dibrugarh University, Dibrugarh, Assam, India

    Samim Sultana, Geetika Borah & Pradip. K. Gogoi

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  1. Samim Sultana
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  2. Geetika Borah
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  3. Pradip. K. Gogoi
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Correspondence to Geetika Borah or Pradip. K. Gogoi.

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Sultana, S., Borah, G. & Gogoi, P.K. Mont-K10 Supported Fe(II) Schiff-Base Complex as an Efficient Catalyst for Hydrogenation of Ketones. Catal Lett 149, 2142–2157 (2019). https://doi.org/10.1007/s10562-019-02810-x

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