Abstract
High catalytic activities (TOF = 8680 h−1) have been achieved by novel rhodium catalysts modified with the chelating sulfonated phosphite ligand hexasulfonated o-phenylendiphosphite in the hydrogenation reaction of renewable methyl esters of sunflower oil under mild reaction conditions and a low rhodium concentration of 50 ppm in methanol.
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Acknowledgements
Financial support of this research by the Postgraduate Studies Programme on “Catalysis and its Applications in the Industry” of Greek Ministry of Education and by the Special Account for Research Grants of the Research Committee of the National and Kapodistrian University of Athens are gratefully acknowledged. We thank Cognis GmbH (today BASF) for the supply of the starting materials methyl esters of palm kernel oil (Edenor® ME PK 12-18 F) and of methyl esters of sunflower oil (Sunflower Fatty Acid ME®).
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Kaika, N., Panopoulou, C., Anagnostopoulou, E. et al. Novel Full Hydrogenation Reaction of Methyl Esters of Palm Kernel and Sunflower Oils Into Methyl Stearate Catalyzed by Rhodium, Ruthenium and Nickel Complexes of Bidentate Hexasulfonated o-Phenylendiphosphite Ligands. Catal Lett 149, 580–590 (2019). https://doi.org/10.1007/s10562-018-2642-7
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DOI: https://doi.org/10.1007/s10562-018-2642-7