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Aldol Condensation of Benzaldehyde and Heptanal Over Zinc Modified Mixed Mg/Al Oxides

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Abstract

Several types of zinc modified Mg–Al layered double hydroxides were prepared. Zinc was incorporated into catalyst structure using different methods—coprecipitation, kneading or impregnation. Characterization of all solid catalysts was performed using different techniques. Acido–basic properties of prepared materials were investigated using ammonia (or carbon dioxide) temperature programmed desorption. The activity of the prepared samples was compared with pure Mg–Al oxide with Mg:Al ratio 3:1 in aldol condensation of benzaldehyde and heptanal. The influence of temperature (80–120 °C) on the reaction course was monitored. Heptanal conversion and selectivity to two main products, i.e. 2-pentylcinnamylaldehyde (jasmine aldehyde) and 2 pentylnon-2-enal, were evaluated. Zinc modified catalysts exhibited under the same conditions 15–20% higher yields of the desired jasmine aldehyde.

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Acknowledgements

The publication is a result of the project Reg. No. TH01011223, which was financially supported by TACR. The project has been integrated into the National Programme for Sustainability I of the Ministry of Education, Youth and Sports of the Czech Republic through the project Development of the UniCRE Centre, project code LO1606.

Funding

Financial support from specific university research (MSMT No 20-SVV/2017).

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Authors and Affiliations

  1. Unipetrol Centre of Research and Education, Inc., Areál Chempark 2838, Záluží 1, 436 70, Litvínov, Czech Republic

    Zdeněk Tišler, Eva Vrbková, Jaroslav Kocík & David Kadlec

  2. University of Chemistry and Technology Prague, Technická 5, Dejvice, 166 28, Prague 6, Czech Republic

    Eva Vrbková, Eliška Vyskočilová & Libor Červený

Authors
  1. Zdeněk Tišler
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  2. Eva Vrbková
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  3. Jaroslav Kocík
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  4. David Kadlec
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  5. Eliška Vyskočilová
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  6. Libor Červený
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Correspondence to Eva Vrbková.

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Tišler, Z., Vrbková, E., Kocík, J. et al. Aldol Condensation of Benzaldehyde and Heptanal Over Zinc Modified Mixed Mg/Al Oxides. Catal Lett 148, 2042–2057 (2018). https://doi.org/10.1007/s10562-018-2416-2

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  • DOI: https://doi.org/10.1007/s10562-018-2416-2

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