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Reusable 1,2,4-Triazolium Based Brønsted Acidic Room Temperature Ionic Liquids as Catalyst for Mannich Base Reaction

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Abstract

Unprecedented examples of 1-alkyl-1,2,4-triazolium methanesulfonate based Brønsted acidic room temperature ionic liquids were synthesized and characterized. Their catalytic activity and efficiency in recyclability and reusability on one pot synthesis of halide substituted β-amino carbonyl compounds are reported.

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Notes

  1. The pH was measured using Digital pH meter Deepvision Model 111/101. All RTILs (5 mmol) were dissolved in triply distilled water (10 mL) for pH measurement. pH instrument was calibrated with buffer pH 2.0.

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Acknowledgments

The authors thank the Department of Science and Technology—Science and Engineering Research Board (DST-SERB, SR/FT/CS-60/2011), India for funding. Also the authors thank Dr. G. Anantharaman, Department of Chemistry, Indian Institute of Technology Kanpur for ESI-MS measurement.

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Authors and Affiliations

  1. Department of Chemistry, Vel Tech University, Chennai, 600062, India

    Sankaranarayanan Nagarajan & Elango Kandasamy

Authors
  1. Sankaranarayanan Nagarajan
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  2. Elango Kandasamy
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Corresponding author

Correspondence to Elango Kandasamy.

Electronic Supplementary Material

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Supplementary Data

ESI mass spectra and NMR for all ionic liquids are available.

Supplementary material 1 (DOCX 4,256 kb)

Supplementary material 2 (DOC 3,204 kb)

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Nagarajan, S., Kandasamy, E. Reusable 1,2,4-Triazolium Based Brønsted Acidic Room Temperature Ionic Liquids as Catalyst for Mannich Base Reaction. Catal Lett 144, 1507–1514 (2014). https://doi.org/10.1007/s10562-014-1312-7

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  • DOI: https://doi.org/10.1007/s10562-014-1312-7

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