Abstract
Nowadays, the water ecosystem is being polluted due to the rapid industrialization and massive use of antibiotics, fertilizers, cosmetics, paints, and other chemicals. Chemical oxidation is one of the most applied processes to degrade contaminants in water. However, chemicals are often unable to completely mineralize the pollutants. Enhanced pollutant degradation can be achieved by Fenton reaction and related processes. As a consequence, Fenton reactions have received great attention in the treatment of domestic and industrial wastewater effluents. Currently, homogeneous and heterogeneous Fenton processes are being investigated intensively and optimized for applications, either alone or in a combination of other processes. This review presents fundamental chemistry involved in various kinds of homogeneous Fenton reactions, which include classical Fenton, electro-Fenton, photo-Fenton, electro-Fenton, sono-electro-Fenton, and solar photoelectron-Fenton. In the homogeneous Fenton reaction process, the molar ratio of iron(II) and hydrogen peroxide, and the pH usually determine the effectiveness of removing target pollutants and subsequently their mineralization, monitored by a decrease in levels of total organic carbon or chemical oxygen demand. We present catalysts used in heterogeneous Fenton or Fenton-like reactions, such as H2O2–Fe3+(solid)/nano-zero-valent iron/immobilized iron and electro-Fenton-pyrite. Surface properties of heterogeneous catalysts generally control the efficiency to degrade pollutants. Examples of Fenton reactions are demonstrated to degrade and mineralize a wide range of water pollutants in real industrial wastewaters, such as dyes and phenols. Removal of various antibiotics by homogeneous and heterogeneous Fenton reactions is exemplified.
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References
Acisli O, Khataee A, Karaca S, Karimi A, Dogan E (2017) Combination of ultrasonic and Fenton processes in the presence of magnetite nanostructures prepared by high energy planetary ball mill. Ultrason Sonochem 34:754–762. https://doi.org/10.1016/j.ultsonch.2016.07.011
Adams C, Wang Y, Loftin K, Meyer M (2002) Removal of antibiotics from surface and distilled water in conventional water treatment processes. J Environ Eng 128:253–260. https://doi.org/10.1061/(ASCE)0733-9372(2002)128:3(253)
Affam AC, Chaudhuri M (2013) Optimization of Fenton treatment of amoxicillin and cloxacillin antibiotics in aqueous solution. Desalin Water Treat 52:1878–1884. https://doi.org/10.1080/19443994.2013.794015
Alalm MG, Tawfik A, Ookawara S (2015) Comparison of solar TiO2 photocatalysis and solar photo-Fenton for treatment of pesticides industry wastewater: operational conditions, kinetics and costs. J Water Process Eng 8:55–63. https://doi.org/10.1016/j.jwpe.2015.09.007
Alaton IA, Dogruel S (2004) Pretreatment of penicillin formulation effluent by advanced oxidation processes. J Hazard Mater 112:105–113. https://doi.org/10.1016/j.jhazmat.2004.04.009
Alaton IA, Dogruel S, Baykal E, Gerone G (2004) Combined chemical and biological oxidation of penicillin formulation effluent. J Environ Manag 73:155–163. https://doi.org/10.1016/j.jenvman.2004.06.007
Aljuboury DDA, Palaniandy P, Abdul Aziz HB, Feroz S, Abu Amr SA (2017) Performance of the photocatalyst and Fenton processes to treat the petroleum wastewater—a review. Glob Nest J 19(3):396–411
An T, Yang H, Li G, Song W, Cooper WJ, Nie X (2010) Kinetics and mechanism of advanced oxidation processes (AOPs) in degradation of ciprofloxacin. Appl Catal B Environ 94:288–294. https://doi.org/10.1016/j.apcatb.2009.12.002
Annabi C, Fourcade F, Soutrel I, Geneste F, Floner D, Bellakhal N, Amrane A (2016) Degradation of enoxacin antibiotic by the electro-Fenton process: optimization, biodegradability improvement and degradation mechanism. J Environ Manag 165(1):96–105. https://doi.org/10.1016/j.jenvman.2015.09.018
Anquandah GAK, Sharma VK, Knight DA, Batchu SR, Gardinali PR (2011) Oxidation of trimethoprim by ferrate(VI): kinetics, products and antibacterial activity. Environ Sci Technol 45(24):10575–10581. https://doi.org/10.1021/es202237g
Anumol T, Dagnino S, Vandervort DR, Snyder SA (2016) Transformation of polyfluorinated compounds in natural waters by advanced oxidation processes. Chemosphere 144:1780–1787. https://doi.org/10.1016/j.chemosphere.2015.10.070
Augstin CA, Chaudhuri M, Mohammed K, Shamsul R (2014) Optimization of modified Fenton (FeGAC/H2O2) pretreatment of antibiotics. Pert J Sci Technol 22(1):239–254. https://doi.org/10.1080/19443994.2013.794015
Ay F, Fikret K (2010) Advanced oxidation of amoxicillin by Fenton’s reagent treatment. J Hazard Mater 179:622–627. https://doi.org/10.1016/j.jhazmat.2010.03.048
Badawy MI, Wahaab RA, EI-Kalliny AS (2009) Fenton biological treatment for the removal of some pharmaceuticals from industrial wastewater. J Hazard Mater 167:567–574. https://doi.org/10.1016/j.jhazmat.2009.01.023
Bakker K (2012) Water security: research challenges and opportunities. Science 337:914–915. https://doi.org/10.1126/science.1226337
Barbosa MO, Moreira NFF, Ribeiro AR, Pereira MFR, Silva AMT (2016) Occurrence and removal of organic micropollutants: an overview of the watch list of EU Decision 2015/495. Water Res 94:257–279. https://doi.org/10.1016/j.watres.2016.02.047
Barbusinski K (2005) Toxicity of industrial waste water treated by Fenton’s reagent. Pol J Environ Stud 14:11–16
Barbusinski K, Filipek K (2001) Toxicity of industrial waste water treated by Fenton’s reagent. Pol J Environ Stud 10:207–212
Barhoumi N, Labiadh L, Oturan MA, Oturan N, Gadri A, Ammar S, Brillas E (2015) Electrochemical mineralization of the antibiotic levofloxacin by electro-Fenton-pyrite process. Chemosphere 141:250–257. https://doi.org/10.1016/j.chemosphere.2015.08.003
Barhoumi N, Oturan N, Olvera-Vargas H, Brillas E, Gadri A, Ammar S, Oturan MA (2016) Pyrite as a sustainable catalyst in electro-Fenton process for improving oxidation of sulfamethazine. Kinetics, mechanism and toxicity assessment. Water Res 94:52–61. https://doi.org/10.1016/j.watres.2016.02.042
Bataineh H, Pestovsky O, Bakac A (2012) pH-induced mechanistic changeover from hydroxyl radicals to iron(IV) in the Fenton reaction. Chem Sci 3:1594–1599. https://doi.org/10.1039/c2sc20099f
Bautista P, Mohedano AF, Casas JA, Zazo JA, Rodriguez JJ (2008) An overview of the application of Fenton oxidation to industrial wastewaters treatment. J Chem Technol Biotechnol 83:1323–1338. https://doi.org/10.1002/jctb.1988
Ben W, Quiang Z, Pan X, Chen M (2009) Removal of veterinary antibiotics from sequencing batch reactor (SBR) pretreated swine wastewater by Fenton’s reagent. Water Res 43:4392–4402. https://doi.org/10.1016/j.watres.2009.06.057
Benatti CT, Tavares CRG (2012) Fenton’s process for the treatment of mixed waste chemicals. In: Organic pollutants ten years after the Stockholm convention-Environmental and analytical update, pp 247–270. https://doi.org/10.5772/31225
Bielski BHJ, Richter HW (1977) A study of the superoxide radical chemistry by stopped-flow radiolysis and radiation induced oxygen consumption. J Am Chem Soc 99(9):3019–3023. https://doi.org/10.1021/ja00451a028
Blum KM, Andersson PL, Ahrens L, Wiberg K, Haglund P (2018) Persistence, mobility and bioavailability of emerging organic contaminants discharged from sewage treatment plants. Sci Total Environ 612:1532–1542. https://doi.org/10.1016/j.scitotenv.2017.09.006
Bocos E, Oturan N, Pazos M, Sanromán MÁ, Oturan MA (2016) Elimination of radio contrast agent diatrizoic acid by photo-Fenton process and enhanced treatment by coupling with electro-Fenton process. Environ Sci Pollut Res 23(19):19134–19144. https://doi.org/10.1007/s11356-016-7054-x
Boczkaj G, Fernandes A (2017) Wastewater treatment by means of advanced oxidation processes at basic pH conditions: a review. Chem Eng J 320:608–633. https://doi.org/10.1016/j.cej.2017.03.084
Bouafia-Chergui S, Oturan N, Khalaf H, Oturan MA (2010) Parametric study on the effect of the ratios [H2O2]/[Fe3+] and [H2O2]/[substrate] on the photo-Fenton degradation of cationic azo dye basic blue 41. J Environ Sci Health A Tox Hazard Subst Environ Eng 45(5):622–629. https://doi.org/10.1080/10934521003595746
Brillas E, Martínez-Huitle CA (2015) Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods: an updated review. Appl Catal B 166–167:603–643. https://doi.org/10.1016/j.apcatb.2014.11.016
Brillas E, Sires I, Oturan MA (2009) Electro-Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry. Chem Rev 109:6570–6631. https://doi.org/10.1021/cr900136g
Brown KD, Kulis J, Thomson B, Chapman TH, Mawhinney DB (2006) Occurrence of antibiotics in hospital, residential, and dairy effluent, municipal wastewater and Rio Grande in Mexico. Sci Total Environ 366:772–783. https://doi.org/10.1016/j.scitotenv.2005.10.007
Cai C, Zhang Z, Liu J, Shan N, Zhang H, Dionysiou DD (2016) Visible light-assisted heterogeneous Fenton with ZnFe2O4 for the degradation of orange II in water. Appl Catal B Environ. https://doi.org/10.1016/j.apcatb.2015.09.056
Cao M, Wang L, Wang L, Chen J, Lu X (2013) Remediation of DDTs contaminated soil in a novel Fenton-like system with zero-valent iron. Chemosphere 90(8):2303–2308. https://doi.org/10.1016/j.chemosphere.2012.09.098
Chakma S, Moholkar VS (2014) Investigations in synergism of hybrid advanced oxidation processes with combinations of sonolysis + fenton process + UV for degradation of bisphenol A. Ind Eng Chem Res 53(16):6855–6865. https://doi.org/10.1021/ie500474f
Chakma S, Moholkar VS (2015) Intensification of wastewater treatment using sono-hybrid processes: an overview of mechanistic synergism. Indian Chem Eng 57:359–381. https://doi.org/10.1080/00194506.2015.1026948
Chen Y, Jin S, Liu J, Zhao B, Wang T (2013) Photo-Fenton reaction of supported cationic cyclopentadienyl iron complexes of aren and application as heterogeneous catalysts in photodegradation of dyes under visible light. Inorganic Chimie Acta 406:37–43. https://doi.org/10.1016/j.ica.2013.07.005
Chen Q, Wu P, Li Y, Zhu N, Dang Z (2009) Heterogeneous photo-Fenton degradation of reactive brilliant orange X-GN over iron pillared montmorillonite under visible irradiation. J Hazard Mater 168:901–908. https://doi.org/10.1016/j.jhazmat.2009.02.107
Cheng M, Zeng G, Huang D, Lai C, Xu P, Zhang C, Liu Y (2016) Hydroxyl radicals based advanced oxidation processes (AOPs) for remediation of soils contaminated with organic compounds: a review. Chem Eng J 284:582–598. https://doi.org/10.1016/j.cej.2015.09.001
Cizmas L, Sharma VK, Gray CM, Mcdonald TJ (2015) Pharmaceuticals and personal care products in water: occurrence, toxicity and risk. Environ Chem Lett 13(4):381–394. https://doi.org/10.1007/s10311-015-0524
Clarizia L, Russo D, Di Somma I, Marotta R, Andreozzi R (2017) Homogeneous photo-Fenton processes at near neutral pH: a review. Appl Catal B Environ 209:358–371. https://doi.org/10.1016/j.apcatb.2017.03.011
Costa RCC, Mourab FCC, Ardisson JD, Fabrisa JD, Lago RM (2008) Highly active heterogeneous Fenton-like systems based on Fe0/Fe3O4 composites prepared by controlled reduction of iron oxides. Appl Catal B Environ 83:131–139. https://doi.org/10.1016/j.apcatb.2008.01.039
Cristovao RO, Goncalves C, Botelho CM, Martins RJE (2014) Chemical oxidation of fish canning waste water by Fenton’s reagent. J Environ Chem Eng 2:237–243. https://doi.org/10.1016/j.jece.2013.12.023
Czapski G, Bielski BHJ (1993) Absorption spectra of the.OH and O·- radicals in aqueous solutions. Radiat Phys Chem 41(3):505. https://doi.org/10.1016/0969-806X(93)90012-J
Dehghani S, Jafari AJ, Farzadkia M, Gholami M (2013) Sulfonamide antibiotics reduction in aquatic environment by application of Fenton oxidation process. J Environ Health Sci Eng 10:29. https://doi.org/10.1186/1735-2746-10-29
Descorme C (2017) Catalytic wastewater treatment: oxidation and reduction processes. Recent studies on chlorophenols. Catal Today 297:324–334. https://doi.org/10.1016/j.cattod.2017.03.039
Dhakshinamoorthy A, Navalon S, Alvaro M, Garcia H (2012) Metal nanoparticles as heterogeneous Fenton catalysts. Chem Sus Chem 5(1):46–64. https://doi.org/10.1002/cssc.201100517
Diao Z, Xu X, Jiang D, Li G, Liu J, Kong L, Zuo L (2017) Enhanced catalytic degradation of ciprofloxacin with FeS2/SiO2 microspheres as heterogeneous Fenton catalyst: kinetics, reaction pathways and mechanism. J Hazard Mater 327:108–115. https://doi.org/10.1016/j.jhazmat.2016.12.045
Diao Y, Yan Z, Guo M, Wang X (2018) Magnetic multi-metal co-doped magnesium ferrite nanoparticles: an efficient visible light-assisted heterogeneous Fenton-like catalyst synthesized from saprolite laterite ore. J Hazard Mater 344:829–838. https://doi.org/10.1016/j.jhazmat.2017.11.029
Dias IN, Souza BS, Pereira JHOS, Moreira FC, Dezotti M, Boaventura RAR, Vilar VJP (2014) Enhancement of the photo-Fenton reaction at near neutral pH through the use of ferrioxalate complexes: a case study on trimethoprim and sulfamethoxazole antibiotics removal from aqueous solutions. Chem Eng J 247:302–313. https://doi.org/10.1016/j.cej.2014.03.020
Dindarsafa M, Khataee A, Kaymak B, Vahid B, Karimi A, Rahmani A (2017) Heterogeneous sono-Fenton-like process using martite nanocatalyst prepared by high energy planetary ball milling for treatment of a textile dye. Ultrason Sonochem 34:389–399. https://doi.org/10.1016/j.ultsonch.2016.06.016
Djowe AT, Nzali S, Njoyim ET, Laminsi S, Gaigneaux EM (2014) Thermal treatment of plasma-synthesized goethite improves Fenton-like degradation of orange II dye. Environ Chem Lett 12:219–224. https://doi.org/10.1007/s10311-016-0578-y
Du D, Shi W, Wang L, Zhang J (2017) Yolk shell structured Fe3O4@void@TiO2 as photo-Fenton-like catalyst for the extremely efficient elimination of tetracycline. Appl Catal B Environ 200:484–492. https://doi.org/10.1016/j.apcatb.2016.07.043
Duan X, Sun H, Shao Z, Wang S (2018) Nonradical reactions in environmental remediation processes: uncertainty and challenges. Appl Catal B Environ 224:973–982. https://doi.org/10.1016/j.apcatb.2017.11.051
Duarte F, Maldonado-Hodar FJ, Perez-Cadenas AF, Madeira LM (2009) Fenton like degradation of azo dye orange II catalysed by transition metals on carbon aerogels. Appl Catal B Environ 85:139–147. https://doi.org/10.1016/j.apcatb.2008.07.006
Durán A, Monteagudo JM, Sanmartín I, Carrasco A (2013) Solar photo-Fenton mineralization of antipyrine in aqueous solution. J Environ Manag 130:64–71. https://doi.org/10.1016/j.jenvman.2013.08.043
Elmolla ES, Chaudhuri M (2009a) Optimization of Fenton process for the treatment of amoxicillin, ampicillin, cloxacillin antibiotics in aqueous solution. J Hazard Mater 170:666–672. https://doi.org/10.1016/j.jhazmat.2009.05.013
Elmolla ES, Chaudhuri M (2009b) Degradation of the antibiotics amoxicillin, ampicillin, cloxacillin in aqueous solution by the photo-Fenton process. J Hazard Mater 172:1476–1481. https://doi.org/10.1016/j.jhazmat.2009.08.015
Elmolla ES, Chaudhuri M (2010a) Comparisons of different advanced oxidation processes for the treatment of antibiotic aqueous solution. Desalination 256:43–47. https://doi.org/10.1016/j.desal.2010.02.019
Elmolla ES, Chaudhuri M (2010b) Degradation of amoxicillin, ampicillin, cloxacillin antibiotics in aqueous solution by the UV/ZnO photocatalytic process. J Hazard Mater 173:445–449. https://doi.org/10.1016/j.jhazmat.2009.08.104
Elmolla ES, Chaudhuri M (2012) The feasibility of using combined Fenton SBR for antibiotic wastewater treatment. Desalination 285:14–21. https://doi.org/10.1016/j.desal.2011.09.022
Elmolla ES, Chaudhari M, Eltoukhy MM (2010) The use of artificial neural network (ANN) for modeling of COD removal from antibiotic aqueous solution by the Fenton process. J Hazard Mater 179:127–134. https://doi.org/10.1016/j.jhazmat.2010.02.068
Eren Z (2012) Ultrasound as a basic and auxiliary process for dye remediation: a review. J Environ Manag 104:127–141. https://doi.org/10.1016/j.jenvman.2012.03.028
Espinosa JC, Navalón S, Álvaro M, García H (2016) Reduced graphene oxide as a metal-free catalyst for the light-assisted Fenton-like reaction. Chem Cat Chem 8(16):2642–2648. https://doi.org/10.1002/cctc.201600364
Espinosa JC, Catalá C, Navalón S, Ferrer B, Álvaro M, García H (2018) Iron oxide nanoparticles supported on diamond nanoparticles as efficient and stable catalyst for the visible light assisted Fenton reaction. Appl Catal B Environ 226:242–251. https://doi.org/10.1016/j.apcatb.2017.12.060
Espinoza C, Romero J, Villegas L, Cornejo-Ponce L, Salazar R (2016) Mineralization of the textile dye acid yellow 42 by solar photo-electro-Fenton in a lab-pilot plant. J Hazard Mater 319:24–33. https://doi.org/10.1016/j.jhazmat.2016.03.003
Estrada AL, Li YY, Wang A (2012) Biodegradability enhancement of wastewater containing cefalexin by means of the electro Fenton oxidation process. J Hazard Mater 227–228:41–48. https://doi.org/10.1016/j.jhazmat.2012.04.079
Exposito AJ, Monteagudo JM, Diaz I, Duran A (2016) Photo-Fenton degradation of a beverage industrial effluent: intensification with persulfate and the study of radicals. Chem Eng J 306:1203–1211. https://doi.org/10.1016/j.cej.2016.08.048
Fan X, Hao H, Shen X, Chen F, Zhang J (2011) Removal and degradation pathway study of sulfasalazine with Fenton like reaction. J Hazard Mater 190:493–500. https://doi.org/10.1016/j.jhazmat.2011.03.069
Faust BC, Hoigné J (1990) Photolysis of Fe(III)-hydroxy complexes as sources of OH radicals in clouds, fog and rain. Atmos Environ Part A Gen Top 24(1):79–89. https://doi.org/10.1016/0960-1686(90)90443-Q
Faust BC, Zepp RG (1993) Photochemistry of aqueous Iron(III)-polycarboxylate complexes: roles in the chemistry of atmospheric and surface waters. Environ Sci Technol 27(12):2517–2527. https://doi.org/10.1021/es00048a032
Feng J, Hu X, Yue PL (2006) Effect of initial solution pH on the degradation of orange II using clay-based Fe nanocomposites as heterogeneous photo Fenton catalyst. Water Res 40:641–646. https://doi.org/10.1016/j.watres.2005.12.021
Feng L, Van Hullebusch ED, Rodrigo MA, Esposito G, Oturan MA (2013) Removal of residual anti-inflammatory and analgesic pharmaceuticals from aqueous systems by electrochemical advanced oxidation processes: a review. Chem Eng J 228:944–964. https://doi.org/10.1016/j.cej.2013.05.061
Feng M, Wang X, Chen J, Qu R, Sui Y, Cizmas L, Wang Z, Sharma VK (2016) Degradation of fluoroquinolone antibiotics by ferrate (VI): effect of water constituent and oxidized products. Water Res 103:48–57. https://doi.org/10.1016/j.watres.2016.07.014
Feng M, Wang Z, Dionysiou DD, Sharma VK (2018) Metal-mediated oxidation of fluoroquinolone antibiotics in water: a review on kinetics, transformation products, and toxicity assessment. J Hazard Mater 344:1136–1154. https://doi.org/10.1016/j.jhazmat.2017.08.067
Fenton HJH (1894) LXXIII.—oxidation of tartaric acid in presence of iron. J Chem Soc Trans 65:899. https://doi.org/10.1039/ct8946500899
Fenton HJH (1896) XLI.—the constitution of a new dibasic acid, resulting from the oxidation of tartaric acid. J Chem Soc Trans 69:575. https://doi.org/10.1039/ct8966900546
Fischbacher A, Von Sonntag C, Schmidt TC (2017) Hydroxyl radical yields in the Fenton process under various pH, ligand concentrations and hydrogen peroxide/Fe(II) ratios. Chemosphere 182:738–744. https://doi.org/10.1016/j.chemosphere.2017.05.039
Gallard H, De Laat J (2000) Kinetic modelling of Fe(III)/H2O2 oxidation reactions in dilute aqueous solution using atrazine as a model organic compound. Water Res 34(12):3107–3116. https://doi.org/10.1016/S0043-1354(00)00074-9
Gallard H, De Laat J, Legube B (1999) Spectrophotometric study of the formation of iron(III)-hydroperoxy complexes in homogeneous aqueous solutions. Water Res 33(13):2929–2936. https://doi.org/10.1016/S0043-1354(99)00007-X
Gan PP, Li SFY (2013) Efficient removal of rhodamine B using a rice hull-based silica supported iron catalyst by Fenton like process. Chem Eng J 229:351–363. https://doi.org/10.1016/j.cej.2013.06.020
Ganzenko O, Trellu C, Papirio S, Oturan N, Huguenot D, van Hullebusch ED, Esposito G, Oturan MA (2017) Bioelectro-Fenton: evaluation of a combined biological—advanced oxidation treatment for pharmaceutical wastewater. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-017-8450-6
García-Rodríguez O, Bañuelos JA, Godínez LA, Arredondo Valdez HC, Zamudio E, Ramírez V, Rodríguez-Valadez FJ (2017) Iron Supported on Ion Exchange Resin as Source of Iron for Fenton’s reagent: a Heterogeneous or a Homogeneous Fenton’s reagent Generation? Int J Chem Reactor Eng. https://doi.org/10.1515/ijcre-2017-0026
Garcia-Segura S, Brillas E (2017) Applied photoelectrocatalysis on the degradation of organic pollutants in wastewaters. J Photochem Photobiol C Photochem Rev 31:1–35. https://doi.org/10.1016/j.jphotochemrev.2017.01.005
Gassie LW, Englehardt JD (2017) Advanced oxidation and disinfection processes for onsite net-zero greywater reuse: a review. Water Res 125:384–399. https://doi.org/10.1016/j.watres.2017.08.062
Ghattas A, Fischer F, Wick A, Ternes TA (2017) Anaerobic biodegradation of (emerging) organic contaminants in the aquatic environment. Water Res 116:268–295. https://doi.org/10.1016/j.watres.2017.02.001
Ghenymy AE, Rodriguez RM, Email EB, Oturan N, Oturan MA (2014) Electro-Fenton degradation of the antibiotic sulfanilamide with Pt/carbon-felt and BDD/carbon-felt cells. Kinetics, reaction intermediates and toxicity assessment. Environ Sci Pollut Res 2(14):8368–8378. https://doi.org/10.1007/s11356-014-2773-3
Ghosh P, Samanta AN, Ray S (2011) Kinetics based on mechanism of COD reduction for industrial effluent in Fenton process. Int J Chem Technol 3(1):26–36. https://doi.org/10.3923/ijct.2011.26.36
Giraldo-Aguirre AL, Serna-Galvis A, Erazo-Erazo ED, Agredo JS, Ospina HG, Acosta OAF, Palma AT (2017) Removal of β-lactam antibiotics from pharmaceutical wastewaters using photo-Fenton process at near neutral pH. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-017-8420-z
Giri AS, Golder AK (2015) Decomposition of drug mixture in Fenton and photo Fenton processes: comparison to singly treatment, evolution of inorganic ions and toxicity assay. Chemosphere 127:254–261. https://doi.org/10.1016/j.chemosphere.2015.02.010
Gligorovski S, Strekowski R, Barbati S, Vione D (2015) Environmental implications of hydroxyl radicals (·OH). Chem Rev 115(24):13051–13092. https://doi.org/10.1021/cr500310b
Golash N, Gogate PR (2012) Degradation of dichlorvos containing wastewaters using sonochemical reactor. Ultrason Sonochem 19:1051–1060. https://doi.org/10.1016/j.ultsonch.2012.02.011
Goldstein S, Meyersteion D (1999) Comments on the mechanism of the “Fenton-like” reaction. Acc Chem Res 32:547–555. https://doi.org/10.1021/ar9800789
Gong Y, Li J, Zhang Y, Zhang M, Tian X, Wang A (2016) Partial degradation of levofloxacin for biodegradability improvement by electro Fenton process using an activated carbon fiber felt cathode. J Hazard Mater 304:320–328. https://doi.org/10.1016/j.jhazmat.2015.10.064
Gonzalez O, Sans C, Esplugas S (2007) Sulfamethoxazole abatement by photo-Fenton toxicity, inhibition and biodegradability assessment of intermediates. J Hazard Mater 146:459–464. https://doi.org/10.1016/j.jhazmat.2007.04.055
Gozzi F, Sirés I, Thiam A, de Oliveira SC, Junior AM, Brillas E (2017) Treatment of single and mixed pesticide formulations by solar photoelectro-Fenton using a flow plant. Chem Eng J 310:503–513. https://doi.org/10.1016/j.cej.2016.02.026
Gu L, Zhu N, Guo H, Huang S, Lou Z, Yuan H (2013) Adsorption and Fenton like degradation of naphthalene dye intermediate on sewage sludge derived porous carbon. J Hazard Mater 246–247:145–153. https://doi.org/10.1016/j.jhazmat.2012.12.012
Gu S, Xieb J, Li CM (2014) Hierarchically porous graphitic carbon nitride: large scale facile synthesis and its application toward photocatalytic dye degradation. RSC Adv 4:59436–59439. https://doi.org/10.1039/C4RA10958A
Gulkowska A, Leunga HW, Soa MK, Taniyasub S, Yamashit N, Yeung LWY, Richardson BJ, Lei AP, Giesy JP, Lam PKS (2008) Removal of antibiotics from wastewater by sewage treatment facilities in Hong Kong and Shenzhen, China. Water Res 42:395–403. https://doi.org/10.1016/j.watres.2007.07.031
Hajj-Mohamad M, Darwano H, Duy SV, Sauvé S, Prévost M, Arp HPH, Dorner S (2017) The distribution dynamics and desorption behaviour of mobile pharmaceuticals and caffeine to combined sewer sediments. Water Res 108:57–67. https://doi.org/10.1016/j.watres.2016.10.053
He H, Zhou Z (2017) Electro-Fenton process for water and wastewater treatment. Crit Rev Environ Sci Technol 47:2100–2131. https://doi.org/10.1080/10643389.2017.1405673
Hirsch R, Ternes TA, Haberer K, Kratz KL (1999) Occurrence of antibiotics in the aquatic environment. Sci Total Environ 225:109–118. https://doi.org/10.1016/S0048-9697(98)00337-4
Homem V, Alves A, Santos L (2010) Amoxicillin degradation at ppb levels by Fenton’s oxidation using design of experiments. Sci Total Environ 408:6272–6280. https://doi.org/10.1016/j.scitotenv.2010.08.058
Hou L, Wang L, Royer S, Zhang H (2016) Ultrasound assisted heterogeneous Fenton like degradation of tetracycline over a magnetite catalyst. J Hazard Mater 302:458–467. https://doi.org/10.1016/j.jhazmat.2015.09.033
Hsu CA, Wen TN, Su YC, Ziang ZB, Chen CW, Shyur LF (2012) Biological degradation of anthraquinone and azo dyes by a novel laccase from lentinus sp. Environ Sci Technol 46(9):5109–5117. https://doi.org/10.1021/es2047014
Huang C, Huang Y, Cheng H, Huang Y (2009) Kinetic study of an immobilized iron oxide for catalytic degradation of azo dye reactive black B with catalytic decomposition of hydrogen peroxide. Catal Commun 10(5):561–566. https://doi.org/10.1016/j.catcom.2008.10.033
Hug SJ, Leupin O (2003) Iron-catalyzed oxidation of Arsenic(III) by oxygen and by hydrogen peroxide: pH-dependent formation of oxidants in the Fenton reaction. Environ Sci Technol 37(12):2734–2742. https://doi.org/10.1021/es026208x
Hui SJ, Lan FJ, Hui SS, Qing PIY, Ke SM, Yan S (2012) Degradation of the antibiotic sulfamonomethoxine sodium in aqueous solution by photo-Fenton oxidation. Environ Sci Technol 57:558–564. https://doi.org/10.1007/s11434-011-4887-z
Isarain-Chávez E, Garrido JA, Rodríguez RM, Centellas F, Arias C, Cabot PL, Brillas E (2011) Mineralization of metoprolol by electro-Fenton and photoelectro-Fenton processes. J Phys Chem A 115(7):1234–1242. https://doi.org/10.1021/jp110753r
Jafari N, Kasra-Kermanshashi R, Soud MR, Mahvi AH, Gharavi S (2012) Degradation of a textile reactive azo dye by a combine biological-photocatalyticprocess: candidatropicalis Jks2-TiO2/UV. Iran J Environ Health Sci Eng 9(33):1–7. https://doi.org/10.1186/1735-2746-9-33
Kakavandi B, Takdastan A, Jafaarzadeh N, Azizi M, Mirzaei A, Azari A (2016) Application of Fe3O4@C catalyzing heterogeneous UV-Fenton system for tetracycline removal with a focus on optimization by a response surface method. J Photochem Photobiol A Chem 314:178–188. https://doi.org/10.1016/j.jphotochem.2015.08.008
Kalishwaralal K, Jeyabharathi S, Sundar K, Muthukumaran A (2016) A novel one-pot green synthesis of selenium nanoparticles and evaluation of its toxicity in zebrafish embryos. Artif Cells Nanomed Biotechnol 44(2):471–477. https://doi.org/10.3109/21691401.2014.962744
Kang S, Bokare AD, Park Y, Choi CH, Choi W (2017) Electron shuttling catalytic effect of mellitic acid in zero-valent iron induced oxidative degradation. Catal Today 282:65–70. https://doi.org/10.1016/j.cattod.2016.03.009
Karaolia P, Michael I, Fernandez IC, Aguera A, Malato S, Ibanez PF, Kassinos DF (2014) Reduction of clarithromycin and sulfamethoxazole resistant enterococcus by pilot scale solar driven Fenton oxidation. Sci Total Environ 468–469:19–27. https://doi.org/10.1016/j.scitotenv.2013.08.027
Karaolia P, Koradatou IM, Hapeshi E, Schwartz JT, Kassinos DF (2017) Investigation of the potential of membrane bioreactor followed by solar Fenton oxidation to remove antibiotic related microcontaminants. Chem Eng J 310:491–502. https://doi.org/10.1016/j.cej.2016.04.113
Kasiri MB, Aleboyeh H, Aleboyeh A (2008) Degradation of acid blue 74 using Fe-ZSM5 zeolite as a heterogeneous photo-Fenton catalyst. Appl Catal B Environ 84(1–2):9–15. https://doi.org/10.1016/j.apcatb.2008.02.024
Kassinos DF, Vasquez MI, Kummerer K (2011) Transformation products of pharmaceuticals in surface waters and waste water formed during photolysis and advanced oxidation processes: degradation, elucidation of byproducts and assessment of their biological potency. Chemosphere 85(5):693–709. https://doi.org/10.1016/j.chemosphere.2011.06.082
Katsoyiannis IA, Ruettimann T, Hug SJ (2008) pH dependence of Fenton reagent generation and As(III) oxidation and removal by corrosion of zero valent iron in aerated water. Environ Sci Technol 42(19):7424–7430. https://doi.org/10.1021/es800649p
Kaur R, Wani SP, Singh SP, Singh AK, Lal K (2012) Waste water production, treatment and use in India
Khataee A, Gholami P, Vahid B, Joo SW (2016) Heterogenous sono-Fenton process using pyrite nanorods prepared by non-thermal plasma for degradation of an anthraquinone dye. Ultrason Sonochem 32:357–370. https://doi.org/10.1016/j.ultsonch.2016.04.002
Kim H, Hwang YS, Sharma VK (2014) Adsorption of antibiotics and iopromide onto single-walled and multi-walled carbon nanotubes. Chem Eng J 255:23–27. https://doi.org/10.1016/j.cej.2014.06.035
Kitsiou V, Antoniadis A, Mantzavinos D, Poulios I (2014) Homogeneous photo-Fenton mineralization of the antibiotic sulfamethazine in water under UV-A visible and solar irradiation. J Chem Technol Biotechnol 89:1668–1674. https://doi.org/10.1002/jctb.4237
Klatte S, Schaefer H, Hempel M (2017) Pharmaceuticals in the environment—a short review on options to minimize the exposure of humans, animals and ecosystems. Sustain Chem Pharm 5:61–66. https://doi.org/10.1016/j.scp.2016.07.001
Kralchevska RP, Prucek R, Kolarík J, Tucek J, Machala L, Filip J, Sharma VK, Zboril R (2016) Remarkable efficiency of phosphate removal: Ferrate(VI)-induced in situ sorption on core-shell nanoparticles. Water Res 103:83–91. https://doi.org/10.1016/j.watres.2016.07.021
Le C, Liang J, Wu J, Li P, Wang X, Zhu N, Wu P, Yang B (2011) Effective degradation of para-chloronitrobenzene through a sequential treatment using zero-valent iron reduction and Fenton oxidation. Water Sci Technol 64(10):2126–2131. https://doi.org/10.2166/wst.2011.803
Li Y, Lu Y, Zhu X (2006) Photo-Fenton discoloration of the azo dye X-3B over pillared bentonites containing iron. J Hazard Mater 132:196–201. https://doi.org/10.1016/j.jhazmat.2005.07.090
Li J, Mailhot G, Wu F, Deng N (2012) Photodegradation of E2 in the presence of natural montmorillonite and the iron complexing agent ethylenediamine-N,N’-disuccinic acid. Photochem Photobiol Sci. https://doi.org/10.1039/c2pp25159k
Li H, Pan Y, Wang Z, Chen S, Guo R, Chen J (2015) An algal process treatment combined with the Fenton reaction for high concentrations of amoxicillin and cefradine. RSC Adv 5:100775–100782. https://doi.org/10.1039/C5RA21508K
Li L, Song C, Huang Y, Zhou Y (2016) Investigation of BTEX removal efficiency using the electrolytic oxidation and Fenton’s reaction. J Water Chem Technol 38:149–157. https://doi.org/10.3103/S1063455X1603005X
Li X, Zhu K, Pang J, Tian M, Liu J, Rykov AI, Zheng M, Wang X, Zhu X, Huang Y, Liu B, Wang J, Yang W, Zhang T (2018) Unique role of Mossbauer spectroscopy in assessing structural features of heterogeneous catalysts. Appl Catal B Environ 224:518–532. https://doi.org/10.1016/j.apcatb.2017.11.004
Lima MJ, Leblebici ME, Dias MM, Lopes JCB, Silva CG, Silva AMT, Faria JL (2014) Continuous flow photo-Fenton treatment of ciprofloxacin in aqueous solution using homogeneous and magnetically recoverable catalyst. Environ Sci Pollut Res 21:1116–11125. https://doi.org/10.1007/s11356-014-2515-6
Lima MJ, Silva CG, Silva AMT, Lopes JCB, Dias MM, Faria JL (2017) Homogeneous and heterogeneous photo-Fenton degradation of antibiotics using an innovative static mixer photoreactor. Chem Eng J 310:342–351. https://doi.org/10.1016/j.cej.2016.04.032
Lin H, Oturan N, Wu J, Sharma VK, Zhang H, Oturan MA (2017a) Removal of artificial sweetener aspartame from aqueous media by electrochemical advanced oxidation processes. Chemosphere 167:220–227. https://doi.org/10.1016/j.chemosphere.2016.09.143
Lin H, Oturan N, Wu J, Zhang H, Oturan MA (2017b) Cold incineration of sucralose in aqueous solution by electro-Fenton process. Sep Purif Technol 173:218–225. https://doi.org/10.1016/j.seppur.2016.09.028
Liu J, Yang W (2012a) Water sustainability for China and beyond. Science 337:649–650. https://doi.org/10.1126/science.1219471
Liu J, Yang W (2012b) Water sustainability for China and beyond. Science. https://doi.org/10.1126/science.1219471
Liu C, Wu B, ChLiu C, Wu B, Chen X (2018) Sulfate radical-based oxidation for sludge treatment: A review. Chem Eng J. https://doi.org/10.1016/j.cej.2017.10.162
Loannou L, Velegraki T, Michael C, Mantzavinos D, Kassinos DF (2013) Sunlight, iron and radicals to tackle the resistant leftovers of bio treated winery wastewater. Photochem Photobiol Sci 12:664–670. https://doi.org/10.1039/C2PP25192B
Lucas MS, Dias AA, Sampaio A, Amaral C, Peres J (2007) Degradation of a textile reactive Azo dye by a combined chemical-biological process: Fenton’s reagent-yeast. Water Res 41(5):1103–1109. https://doi.org/10.1016/j.watres.2006.12.013
Lyu L, Hu C (2017) Heterogeneous Fenton catalytic water treatment technology and mechanism. Progr Chem 29:981–999. https://doi.org/10.7536/PC170552
Ma Y (2012) Short review: current trends and future challenges in the application of sono-Fenton oxidation for wastewater treatment. Sustain Environ Res 22(5):271–278
Ma YS, Sung CF, Lin JG (2010) Degradation of carbofuran in aqueous solution by ultrasound and Fenton process: effect of system parameters and kinetic study. J Hazard Mater 178:320–325. https://doi.org/10.1016/j.jhazmat.2010.01.081
Mandal T, Maity S, Dasgupta D, Datta S (2010) Advanced oxidation process and biotreatment: their roles in combined industrial wastewater treatment. Desalination 250(1):87–94. https://doi.org/10.1016/j.desal.2009.04.012
Matafonova G, Batoev V (2018) Recent advances in application of UV light-emitting diodes for degrading organic pollutants in water through advanced oxidation processes: a review. Water Res 132:177–189. https://doi.org/10.1016/j.watres.2017.12.079
Michael I, Hapeshi E, Michael C, Varela AR, Kyriakou S, Manaia CM, Kassinos DF (2012) Solar photo-Fenton process on the abatement of antibiotics at a pilot scale: degradation kinetics, ecotoxicity and phytotoxicity assessment and removal of antibiotic resistant enterococci. Water Res 46:5621–5634. https://doi.org/10.1016/j.watres.2012.07.049
Michael I, Hapeshi E, Acena J, Perez S, Petrovic M, Zapata A, Barcelo D, Malato S, Kassinos DF (2013) Light-induced catalytic transformation of ofloxacin by solar Fenton in various water matrices at a pilot plant: mineralization and characterization of major intermediate products. Sci Total Environ 461–462:39–48. https://doi.org/10.1016/j.scitotenv.2013.04.054
Mirzaei A, Chen Z, Haghighat F, Yerushalmi L (2017) Removal of pharmaceuticals from water by homo/heterogonous Fenton-type processes—a review. Chemosphere 174:665–688. https://doi.org/10.1016/j.chemosphere.2017.02.019
Mohammadi AS, Yazdanbakhsh AR, Sardar M (2013) Chemical oxygen demand removal from synthetic wastewater containing non-beta lactam antibiotics using advanced oxidation process: a comparative study. Arch Hyg Sci 2(1):23–30. http://jhygiene.muq.ac.ir/article-1-122-en.html
Morales-Pérez AA, Arias C, Ramírez Zamora R (2016a) Removal of atrazine from water using an iron photo catalyst supported on activated carbon. Adsorpt 22:48–58. https://doi.org/10.1007/s10450-015-9739-8
Morales-Pérez AA, Maravilla P, Solís-López M, Schouwenaars R, Durán-Moreno A, Ramírez-Zamora R (2016b) Optimization of the synthesis process of an iron oxide nanocatalyst supported on activated carbon for the inactivation of Ascaris eggs in water using the heterogeneous Fenton-like reaction. Water Sci Technol 73(5):1000–1009. https://doi.org/10.2166/wst.2015.576
Moreira FC, Soler J, Alpendurada MF, Boaventura RAR, Brillas E, Vilar VJP (2016) Tertiary treatment of a municipal wastewater toward pharmaceuticals removal by chemical and electrochemical advanced oxidation processes. Water Res 105:251–263. https://doi.org/10.1016/j.watres.2016.08.036
Mousset E, Frunzo L, Esposito G, Van Hullebusch ED, Oturan N, Oturan MA (2016) A complete phenol oxidation pathway obtained during electro-Fenton treatment and validated by a kinetic model study. Appl Catal B Environ 180:189–198. https://doi.org/10.1016/j.apcatb.2015.06.014
Mousset E, Oturan N, Oturan MA (2018) An unprecedented route of ·OH radical reactivity evidenced by an electrocatalytical process: ipso-substitution with per halogeno carbon compounds. Appl Catal B Environ 226:135–146. https://doi.org/10.1016/j.apcatb.2017.12.028
Moya MP, Graells M, Castells G, Amigo J, Ortega E, Buhigas G, Perez LM, Mansilla HD (2010) Characterization of the degradation performance of the sulfamethazine antibiotic by photo-Fenton process. Water Res 44:2533–2540. https://doi.org/10.1016/j.watres.2010.01.032
Nidheesh PV, Olvera-Vargas H, Oturan N, Oturan MA (2017) Heterogeneous electro-Fenton process: principles and applications. In: Zhou M, Oturan MA, Sirés I (eds) Electro-Fenton process: new trends and scale-up. Handbook of Environmental Chemistrt, vol 61. Springer, Singapore, pp 85–110. https://doi.org/10.1007/698_2017_72
Nidheesh PV, Zhou M, Oturan MA (2018) An overview on the removal of synthetic dyes from water by electrochemical advanced oxidation processes. Chemosphere 197:210–227. https://doi.org/10.1016/j.chemosphere.2017.12.195
Olvera-Vargas H, Cocerva T, Oturan N, Buisson D, Oturan MA (2016a) Bioelectro-Fenton: a sustainable integrated process for removal of organic pollutants from water: application to mineralization of metoprolol. J Hazard Mater 319:13–23. https://doi.org/10.1016/j.jhazmat.2015.12.010
Olvera-Vargas H, Oturan N, Buisson D, Oturan MA (2016b) A coupled Bio-EF process for mineralization of the pharmaceuticals Furosemide and Ranitidine: feasibility assessment. Chemosphere 155:606–613. https://doi.org/10.1016/j.chemosphere.2016.04.091
Oturan MA, Aaron J-J (2014) Advanced oxidation processes in water/wastewater treatment: principles and applications: a review. Crit Rev Environ Sci Technol 44:2577–2641. https://doi.org/10.1080/10643389.2013.829765
Oturan E, Oturan N, Oturan MA (2018) An unprecedented route of [rad]OH radical reactivity evidenced by an electrocatalytical process: Ipso-substitution with perhalogenocarbon compounds. Appl Catal B Environ. https://doi.org/10.1016/j.apcatb.2017.12.028
Oturan MA, Sirés I, Oturan N, Pérocheau S, Laborde J, Trévin S (2008) Sonoelectro-Fenton process: a novel hybrid technique for the destruction of organic pollutants in water. J Electroanal Chem 624(1–2):329–332. https://doi.org/10.1016/j.jelechem.2008.08.005
Oturan N, Wu J, Zhang H, Sharma VK, Oturan MA (2013) Electrocatalytic destruction of the antibiotic tetracycline in aqueous medium by electrochemical advanced oxidation processes: effect of electrode materials. Appl Catal B Environ 140–141:92–97. https://doi.org/10.1016/j.apcatb.2013.03.035
Ouiriemmi I, Karrab A, Oturan N, Pazos M, Rozales E, Gadri A, Sanromán MÁ, Ammar S, Oturan MA (2017) Heterogeneous electro-Fenton using natural pyrite as solid catalyst for oxidative degradation of vanillic acid. J Electroanal Chem 797:69–77. https://doi.org/10.1016/j.jelechem.2017.05.028
Özcan A, Atilir Özcan A, Demirci Y (2016) Evaluation of mineralization kinetics and pathway of norfloxacin removal from water by electro-Fenton treatment. Chem Eng J 304:518–526. https://doi.org/10.1016/j.cej.2016.06.105
Özdemir C, Öden MK, Sahinkaya S, Kalipçi E (2011) Color removal from synthetic textile wastewater by sono-Fenton process. CLEAN Soil Air Water 39(1):60–67. https://doi.org/10.1002/clen.201000263
Pi L, Yang N, Han W, Xiao W, Wang D, Xiong Y, Zhou M, Hou H, Mao X (2018) Heterogeneous activation of peroxymonocarbonate by Co-Mn oxides for the efficient degradation of chlorophenols in the presence of a naturally occurring level of bicarbonate. Chem Eng J 334:1297–1308. https://doi.org/10.1016/j.cej.2017.11.006
Pignatello JJ, Oliveros E, MacKay A (2006) Advanced oxidation processes for organic contaminant destruction based on the Fenton reaction and related chemistry. Crit Rev Environ Sci Technol 36:1–84. https://doi.org/10.1080/10643380500326564
Pliego G, Zazo JA, Garcia-Muñoz P, Munoz M, Casas JA, Rodriguez JJ (2015) Trends in the intensification of the Fenton process for wastewater treatment: an overview. Crit Rev Environ Sci Technol 36:1–84. https://doi.org/10.1080/10643389.2015.1025646
Poerscchmann J, Trommler U, Gorecki T (2010) Aromatic intermediate formation during oxidative degradation of bisphenol A by homogeneous sub stoichiometric Fenton reaction. Chemosphere 79:975–986. https://doi.org/10.1016/j.chemosphere.2010.03.030
Prachi K, Anushree M (2009) Fungal dye decolourization: recent advances and future potential. Environ Int 35:127–141. https://doi.org/10.1016/j.envint.2008.05.010
Pulicharla R, Brar SK, Rouissi T, Auger S, Drogui P, Verma M, Surampalli RY (2017) Degradation of chlortetracycline in waste water sludge by ultrasonication, Fenton oxidation and ferro sonication. UltrasonSonochem 34:332–342. https://doi.org/10.1016/j.ultsonch.2016.05.042
Rachmilovich-Calis S, Masarwa A, Meyerstein N, Meyerstein DvE R (2009) New mechanistic aspects of the Fenton reaction. Chem Eur J 15:8303–8309. https://doi.org/10.1002/chem.200802572
Ranjit PJD, Palanivelu K, Lee CS (2008) Degradation of 2,4-dichlorophenol in aqueous solution by sono-Fenton method. Korean J Chem Eng 25:112–117. https://doi.org/10.1007/s11814-008-0020-7
Rozas O, Contreras D, Mondaca MA, Moya MP, Mansilla HD (2010) Experimental design of Fenton and photo Fenton reactions for the treatment of ampicillin solutions. J Hazard Mater 177:1025–1030. https://doi.org/10.1016/j.jhazmat.2010.01.023
Rush JD, Bielski BHJ (1985) Pulse radiolytic studies of the reactions of HO2/O2− with Fe(II)/Fe(III) ions. The reactivity of HO2/O2 − with ferric ions and its implication on the occurrence of the Haber-Weiss reaction. J Phys Chem 89(23):5062–5066. https://doi.org/10.1021/j100269a035
Salimi M, Esrafili A, Gholami M, Jonidi Jafari A, Rezaei Kalantary R, Farzadkia M, Kermani M, Sobhi HR (2017) Contaminants of emerging concern: a review of new approach in AOP technologies. Environ Monit Assess 189(8):414. https://doi.org/10.1007/s10661-017-6097-x
Sanchez PTA, Hernandez IL, Miranda VM, Lugo VL, De-oca RMGFM (2014) Waste water treatment of methyl methacrylate by Fenton’s reagent and adsorption. Catal Today 220–222:39–48. https://doi.org/10.1016/j.cattod.2013.09.006
Santos LVDS, Meireles AM, Lange LC (2015) Degradation of antibiotics norfloxacin by Fenton, UV and UV/H2O2. J Environ Manag 154:8–12. https://doi.org/10.1016/j.jenvman.2015.02.021
Sarria V, Parra S, Invernizzi M, Pulgarin C (2001) Photochemical-biological treatment of a real industrial biorecalcitrant waste water containing 5-amino-6-methyl-2-benzimidazolone. Water Sci Technol 44:93–101 PMID:11695489
Schmeller DS, Loyau A, Bao K, Brack W, Chatzinotas A, De Vleeschouwer F, Friesen J, Gandois L, Hansson SV, Haver M, Le Roux G, Shen J, Teisserenc R, Vredenburg VT (2018) People, pollution and pathogens—global change impacts in mountain freshwater ecosystems. Sci Total Environ 622–623:756–763. https://doi.org/10.1016/j.scitotenv.2017.12.006
Schrank SG, Jose HJ, Moreira RFPM, Schroder HF (2005) Applicability of Fenton and H2O2/UV reaction in the treatment of tannery waste waters. Chemosphere 60:644–655. https://doi.org/10.1016/j.chemosphere.2005.01.033
Schwarzenbach RP, Escher BI, Fenner K, Hofstetter TB, Johnson CA, Von Gunten U, Wehrli B (2006) The challenge of micropollutants in aquatic systems. Science 313:1072–1077. https://doi.org/10.1126/science.1127291
Schwarzenbach RP, Egli T, Hofstetter TB, Von Gunten U, Wehrli B (2010) Global water pollution and human health. Annu Rev Environ Resour 35:109–136. https://doi.org/10.1146/annurev-environ-100809-125342
Serpone N, Artemev YM, Ryabchuk VK, Emeline AV, Horikoshi S (2017) Light-driven advanced oxidation processes in the disposal of emerging pharmaceutical contaminants in aqueous media: a brief review. Curr Opin Green Sustain Chem 6:18–33. https://doi.org/10.1016/j.cogsc.2017.05.003
Shannon MA, Bohn PW, Elimelech M, Georgiadis JG, Mrinas BJ, Mayes AM (2008) Science and technology for water purification in the coming decades. Nature 452:301–310. https://doi.org/10.1038/nature06599
Sharma VK (2013) Oxidation of amino acids, peptides, and proteins. Wiley Inc, New Jersey
Sharma VK, Feng M (2017) Water depollution using metal-organic frameworks-catalyzed advanced oxidation processes: a review. J Hazard Mater. https://doi.org/10.1016/j.jhazmat.2017.09.043
Sharma VK, Sohn M (2009) Aquatic arsenic: toxicity, speciation, transformations, and remediation. Environ Int 35:743–759. https://doi.org/10.1016/j.envint.2009.01.005
Sharma VK, McDonald TJ, Kim H, Garg VK (2015) Magnetic graphene-carbon nanotube iron nanocomposites as adsorbents and antibacterial agents for water purification. Adv Colloid Interface Sci 225:229–240. https://doi.org/10.1016/j.cis.2015.10.006
Sharma VK, Johnson N, Cizmas L, McDonald TJ, Kim H (2016) A review of the influence of treatment strategies on antibiotic resistant bacteria and antibiotic resistance genes. Chemosphere 150:702–714. https://doi.org/10.1016/j.chemosphere.2015.12.084
Shimizu A, Tokumura M, Nakajima K, Kawase Y (2012) Phenol removal using zero-valent iron powder in the presence of dissolved oxygen: roles of decomposition by the Fenton reaction and adsorption/precipitation. J Hazard Mater 201–201:60–67. https://doi.org/10.1016/j.jhazmat.2011.11.009
Shriwas AK, Gogate PR (2011) Ultrasonic degradation of methyl parathion in aqueous solutions: intensification using additives and scale up aspects. Sep Purif Technol 79:1–7. https://doi.org/10.1016/j.seppur.2011.02.034
Sillanpää M, Ncibi MC, Matilainen A (2018) Advanced oxidation processes for the removal of natural organic matter from drinking water sources: a comprehensive review. J Environ Manag 208:56–76. https://doi.org/10.1016/j.jenvman.2017.12.009
Silva CR, Maniero MG, Rath S, Guimaraes JR (2013) Degradation of flumequine by the Fenton and photo Fenton processes: evaluation of residual antimicrobial activity. Sci Total Environ 445–446:337–346. https://doi.org/10.1016/j.scitotenv.2012.12.079
Sirés I, Brillas E, Oturan MA, Rodrigo MA, Panizza M (2014) Electrochemical advanced oxidation processes: today and tomorrow: a review. Environ Sci Pollut Res 21(14):8336–8367. https://doi.org/10.1007/s11356-014-2783-1
Sousa JCG, Ribeiro AR, Barbosa MO, Pereira MFR, Silva AMT (2018) A review on environmental monitoring of water organic pollutants identified by EU guidelines. J Hazard Mater 344:146–162. https://doi.org/10.1016/j.jhazmat.2017.09.058
Steter JR, Brillas E, Sirés I (2018) Solar photoelectro-Fenton treatment of a mixture of parabens spiked into secondary treated wastewater effluent at low input current. Appl Catal B Environ 224:410–418. https://doi.org/10.1016/j.apcatb.2017.10.060
Sum OS, Feng J, Hu X, Po L (2004) Pillared laponite clay-based Fe nanocomposites as heterogeneous catalyst for photo Fenton degradation of acid black 1. Chem Eng Sci 59:5269–5275. https://doi.org/10.1016/j.ces.2004.09.032
Tayo LL, Caparanga AR, Doma BT, Liao C (2018) A Review on the removal of pharmaceutical and personal care products (PPCPs) using advanced oxidation processes. J Adv Oxid Technol 21(1):196–214. https://doi.org/10.26802/jaots.2017.0079
Tekin H, Bilkay O, Ataberk SS, Balta TH, Ceribasi IH, Sanin FD, Dilek FB, Yetis U (2006) Use of Fenton oxidation to improve the biodegradability of a pharmaceutical waste water. J Hazard Mater 136:258–265. https://doi.org/10.1016/j.jhazmat.2005.12.012
Trellu C, Mousset E, Pechaud Y, Huguenot D, van Hullebusch ED, Esposito G, Oturan MA (2016) Removal of hydrophobic organic pollutants from soil washing/flushing solutions: a critical review. J Hazard Mater 306:149–174. https://doi.org/10.1016/j.jhazmat.2015.12.008
Trovo AG, Nogueira RFP, Aguera A, Alba ARF, Sirtori C, Malato S (2009) Degradation of sulfamethoxazole in water by solar Fenton-Chemical and toxicological evaluation. Water Res 43:3922–3931. https://doi.org/10.1016/j.watres.2009.04.006
Trovo AG, Nogueira RFP, Aguera A, Alba ARF, Malato S (2011) Degradation of the antibiotics amoxicillin by photo-Fenton process-Chemical and toxicological assessment. Water Res 45(3):1394–1402. https://doi.org/10.1016/j.watres.2010.10.029
Turbay EY, Jaen E, Graells M, Moya MP (2013) Enhanced photo Fenton process for tetracycline degradation using efficient hydrogen peroxide dosage. J Photochem Photobiol A Chem 267:11–16. https://doi.org/10.1016/j.jphotochem.2013.05.008
Uribe IO, Mosquera-Corral A, Lema JM, Esplugas S (2015) Advanced technologies for water treatment and reuse. AIChE J 61(10):3146–3159. https://doi.org/10.1002/aic.15013
Usman M, Hanna K, Haderlein S (2016) Fenton oxidation to remediate PAHs in contaminated soils: a critical review of major limitations and counter-strategies. Sci Total Environ 569–570:179–190. https://doi.org/10.1016/j.scitotenv.2016.06.135
Velichkova F, Delmas H, Julcour C, Koumanova B (2017) Heterogeneous Fenton and photo-Fenton oxidation for paracetamol removal using iron containing ZSM-5 zeolite as catalyst. AIChE J 63(2):397–854. https://doi.org/10.1002/aic.15369
Vidal J, Huiliñir C, Santander R, Silva-Agredo J, Torres-Palma RA, Salazar R (2018) Effective removal of the antibiotic nafcillin from water by combining the photoelectro-Fenton process and anaerobic biological digestion. Sci Total Environ 624:1095–1105. https://doi.org/10.1016/j.scitotenv.2017.12.159
Vilardi G, Sebastiani D, Miliziano S, Verdone N, Di Palma L (2018) Heterogeneous nZVI-induced Fenton oxidation process to enhance biodegradability of excavation by-products. Chem Eng J 335:309–320. https://doi.org/10.1016/j.cej.2017.10.152
Von Sonntag C (2008) Advanced oxidation processes: mechanistic aspects. Water Sci Technol 58:1015–1021. https://doi.org/10.2166/wst.2008.467
Von Sonntag C, Schuchmann HP (1997) Peroxy radicals in aqueous solutions. In: Alfassi ZB (ed) Peroxy radicals, Wiley, pp 173–234
Vörösmarty CJ, McIntyre PB, Gessner MO, Dudgeon D, Prusevich A, Green P, Glidden S, Bunn SE, Sullivan CA, Liermann CR, Davies PM (2010) Global threats to human water security and river biodiversity. Nature 467:555–561. https://doi.org/10.1038/nature09440
Walter MV, Vennes JW (1985) Occurrence of multiple-antibiotic resistant enteric bacteria in domestic sewage and oxidative lagoons. Appl Environ Microbiol 50:930–933
Wan Z, Hu J, Wang J (2016) Removal of sulfamethazine antibiotics using Ce-Fe-graphene nanocomposite as catalyst by Fenton-like process. J Environ Manag 182:284–291. https://doi.org/10.1016/j.jenvman.2016.07.088
Wang A, Li YY, Estrada AL (2011) Mineralization of antibiotics sulfamethoxazole by photoelectron-Fenton treatment using activated carbon fiber cathode and under UVA radiation. Appl Catal B Environ 102:378–386. https://doi.org/10.1016/j.apcatb.2010.12.007
Wang H, Jiang H, Wang S, She W, He J, Liu H, Huang Y (2014) Fe3O4-MWCNT magnetic nanocomposites as efficient peroxidase mimic catalyst in Fenton-like reaction for water purification without pH limitation. RSC Adv 4:45809–45815. https://doi.org/10.1039/C4RA07327D
Wang L, Cao M, Ai Z, Zhang L (2015) Design of a highly efficient and wide pH electro-Fenton oxidation system with molecular oxygen activated by ferrous-tetrapolyphosphate complex. Environ Sci Technol 49(5):3032–3039. https://doi.org/10.1021/es505984y
Wang N, Zheng T, Zhang G, Wang P (2016) A review on Fenton-like processes for organic wastewater treatment. J Environ Chem Eng 4(1):762–787. https://doi.org/10.1016/j.jece.2015.12.016
Watkinson AJ, Murby EJ, Costanzo SD (2007) Removal of antibiotics in conventional and advanced wastewater treatment: implications for environmental discharge and wastewater recycling. Water Res 41:4164–4176. https://doi.org/10.1016/j.watres.2007.04.005
Weller C, Horn S, Herrmann H (2013a) Effects of Fe(III)-concentration, speciation, excitation-wavelength and light intensity on the quantum yield of iron(III)-oxalato complex photolysis. J Photochem Photobiol A Chem 255:41–49. https://doi.org/10.1016/j.jphotochem.2013.01.014
Weller C, Horn S, Herrmann H (2013b) Photolysis of Fe(III) carboxylato complexes: Fe(II) quantum yields and reaction mechanisms. J Photochem Photobiol A Chem 268:24–36. https://doi.org/10.1016/j.jphotochem.2013.06.022
Werber JR, Osuji CO, Elimelech M (2016) Materials for next-generation desalination and water purification membranes. Nat Rev Mater 1(5):16018. https://doi.org/10.1038/natrevmats.2016.18
World Health Organization (2017) A report on progress on drinking water: 2017 update and Sustainable Development Goal Baselines
Wu D, Chen Y, Zhang Z, Feng Y, Liu Y, Fan J, Zhang Y (2016) Enhanced oxidation of chloramphenicol by GLDA-driven pyrite induced heterogeneous Fenton like reaction at alkaline condition. Chem Eng J 294:49–57. https://doi.org/10.1016/j.cej.2016.02.097
Xing ZP, Sun DZ (2009) Treatment of antibiotic fermentation wastewater by combined polyferric sulfate coagulation, Fenton and sedimentation process. J Hazard Mater 168:1264–1268. https://doi.org/10.1016/j.jhazmat.2009.03.008
Yahya MS, Beqqal N, Guessous A, Arhoutane MR, Kacemi KE (2017) Degradation and mineralization of moxifloxacin antibiotic in aqueous medium by electro-Fenton process: kinetic assessment and oxidation product. Cog Chem 3:1290021–1290032. https://doi.org/10.1080/23312009.2017.1290021
Yalfani MS, Contreras S, Medina F, Sueiras J (2009) Phenol degradation by Fenton’s process using catalytic in situ generated hydrogen peroxide. Appl Catal B Environ 89:519–526. https://doi.org/10.1016/j.apcatb.2009.01.007
Yuan Y, Lai B, Tang YY (2016) Combined Fe0/air and Fenton process for the treatment of dinitrodiazophenol (DDNP) industry wastewater. Chem Eng J 283:1514–1521. https://doi.org/10.1016/j.cej.2015.08.104
Zepp RG, Faust BC, Jürg H (1992) Hydroxyl radical formation in aqueous reactions (pH 3–8) of iron(II) with hydrogen peroxide: the photo-Fenton reaction. Environ Sci Technol. https://doi.org/10.1021/es00026a011
Zhang G, Ji S, Xi B (2006) Feasibility study of treatment of amoxicillin wastewater with a combination of extraction, Fenton oxidation, reverse osmosis. Desalination 196:32–42. https://doi.org/10.1016/j.desal.2005.11.018
Zhang Y, He C, Sharma VK, Li X, Tian S, Xiong Y (2011a) A coupling process of membrane separation and heterogeneous Fenton-like catalytic oxidation for treatment of acid orange II-containing wastewater. Sep Purif Technol 80:45–51. https://doi.org/10.1016/j.seppur.2011.04.004
Zhang Y, He C, Sharma V, Li X, Tian S, Xiong Y (2011b) A new reactor coupling heterogeneous Fenton-like catalytic oxidation with membrane separation for degradation of organic pollutants. J Chem Technol Biotechnol 86:1488–1494
Zhang W, Gao H, He J, Yang P, Wang D, Ma T, Xia H, Xu X (2017) Removal of norfloxacin using coupled synthesized nano scale zero valent iron (nZVI) with H2O2 system: optimization of operating conditions and degradation pathway. Sep Purif Technol 172:158–167. https://doi.org/10.1016/j.seppur.2016.08.008
Zubir NA, Yacou C, Zhang X, Diniz da Costa JC (2014a) Optimization of graphene oxide-iron oxide nanocomposite in heterogeneous Fenton like oxidation of acid orange 7. Environ Chem Eng 2:1881–1888. https://doi.org/10.1016/j.jece.2014.08.001
Zubir NA, Yacou C, Motuzas J, Zhang X, Diniz da Costa JC (2014b) Structural and functional investigation of graphene oxide-Fe3O4 nanocomposites for the heterogeneous Fenton like reaction. Sci Rep 4:1–8. https://doi.org/10.1038/srep04594
Acknowledgements
Dr. Bhawana Jain (postdoctoral fellow, No. F.15-1/2013-14/PDFWM-2013-14-GE-CHH-18784 (SA-II)) is thankful to UGC, Delhi, India, for Research Project grants. Professor Hyunook Kim appreciates the financial support by Korea Ministry of Environment (MOE) (Project ID: 2015001790002). We thank reviewers for their comments, which improved this paper greatly.
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Jain, B., Singh, A.K., Kim, H. et al. Treatment of organic pollutants by homogeneous and heterogeneous Fenton reaction processes. Environ Chem Lett 16, 947–967 (2018). https://doi.org/10.1007/s10311-018-0738-3
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DOI: https://doi.org/10.1007/s10311-018-0738-3