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Interfacial Engineering of Polymer Blend with Janus Particle as Compatibilizer

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Abstract

Mixing two or more polymers to produce the “polymer alloy” is the most versatile and economical strategy for developing new polymeric materials. The compatibility between polymer components largely determines the comprehensive performance of polymer blend. More recently, a type of unique surface partitioned materials, Janus particles, has been proposed to act as a novel interfacial compatibilizer for polymer blends. Such Janus particles integrates the amphipathicity of diblock copolymer and interfacial stabilization of nanoparticles, displaying a significant superiority in comparison with molecular compatibilizers for a wide range of polymer blends. In this review, we mainly focus on the compatibilizing effects of Janus nanofillers of various morphologies, including spherical, snowman-like, and two-dimensional nanosheets, on polymer blends. We shed light on the impacts of compatibilization of Janus particles on phase morphologies, mechanical properties, and functionalities of polymer blends. This review could provide a guidance for designing an effective Janus particle compatibilizer to develop high-performance polymer blends.

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Nos. 52173076, 52042302), China Postdoctoral Science Foundation (No. 2021M701825), Tsinghua-Foshan Innovation Special Fund (TFISF) (No. 2021THFS0212), and Joint Agency Affiliate Projects of China Petroleum & Chemical Corporation (No. 20212930037).

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  1. Institute of Polymer Science and Engineering, Department of Chemical Engineering, Tsinghua University, Beijing, 100084, China

    Hai-Ling He & Fu-Xin Liang

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  1. Hai-Ling He
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Correspondence to Fu-Xin Liang.

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Fu-Xin Liang received his Ph.D. degree from Institute of Chemistry, Chinese Academy of Sciences (ICCAS) in 2011. He started his academic career at ICCAS from assistant professor (2011–2013) to associate professor (2013–2017) to professor (2017–2019). In 2019, he joined the Department of Chemical Engineering at Tsinghua University as an associate professor. His research works focus on design of amphiphilic Janus materials and their application in polymer composite such as polymer blends, and functional coating.

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He, HL., Liang, FX. Interfacial Engineering of Polymer Blend with Janus Particle as Compatibilizer. Chin J Polym Sci 41, 500–515 (2023). https://doi.org/10.1007/s10118-022-2878-y

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