Abstract
Liquid membrane is a prospective technology for the separation and preconcentration of metal ions from their diluted aqueous solutions prior to solid metal recovery by traditional electrowinning. To examine the technical and economic viability of integrating liquid membrane and electrowinning systems, a techno-economic analysis was conducted for a newly developed process consisting of a continuous bulk liquid membrane (CBLM) with an electrowinning cell for copper recovery from electroplating wastewater. A commercial steady-state process simulation software, SuperPro Designer v.12.3, was used for simulation and economic evaluation of the integrated CBLM-electrowinning process, based on data derived from a laboratory experiment scale-up. Three different membrane solvents, i.e. fresh vegetable oil-, waste vegetable oil (WVO)-, and kerosene-based types, were studied at various recycle rates to determine optimum membrane solvent. Before the economic performance was considered, kerosene-based solvent reported the best recovery of copper from wastewater. With economic evaluation, the WVO outperforms the other solvents, as it is available free of charge from collected waste oil, despite having the lowest revenue among all solvents. The economic analysis indicated that CBLM with WVO-based membrane solvent at 99% of membrane solvent recycle rate was the most viable with a net expenditure of $ 0.161 MM/y.
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References
Alibaba (2021) Electrowinning tank price
Bankole MT, Abdulkareem AS, Mohammed IA, Ochigbo SS, Tijani JO, Abubakre OK, Roos WD (2019) Selected heavy metals removal from electroplating wastewater by purified and polyhydroxylbutyrate functionalized carbon nanotubes adsorbents. Sci Rep 9(1):4475. https://doi.org/10.1038/s41598-018-37899-4
Bezuidenhout C (2014) An electrochemical reduction process for the recovery of copper powder from a refinery effluent stream. University of Cape Town, Cape Town
Carolin CF, Kumar PS, Saravanan A, Joshiba GJ, Naushad M (2017) Efficient techniques for the removal of toxic heavy metals from aquatic environment: a review. J Environ Chem Eng 5(3):2782–2799. https://doi.org/10.1016/j.jece.2017.05.029
Chang SH (2014) Vegetable oil as organic solvent for wastewater treatment in liquid membrane processes. Desalin Water Treat 52(1–3):88–101. https://doi.org/10.1080/19443994.2013.782829
Chang SH (2016) Types of bulk liquid membrane and its membrane resistance in heavy metal removal and recovery from wastewater. Desalin Water Treat 57(42):19785–19793. https://doi.org/10.1080/19443994.2015.1102772
Chang SH (2017) Parametric studies on an innovative waste vegetable oil-based continuous liquid membrane (WVCLM) for Cu(II) ion separation from aqueous solutions. J Ind Eng Chem 50:102–110. https://doi.org/10.1016/J.JIEC.2017.01.037
Chang SH (2018) A comparative study of batch and continuous bulk liquid membranes in the removal and recovery of Cu(II) Ions from wastewater. Water Air Soil Pollut 229(1):22. https://doi.org/10.1007/s11270-017-3659-z
Chang SH (2020) Utilization of green organic solvents in solvent extraction and liquid membrane for sustainable wastewater treatment and resource recovery—a review. Environ Sci Pollut Res 27(26):32371–32388. https://doi.org/10.1007/s11356-020-09639-7
Echemi (2021) Sulfuric acid price
Elawwad A, Matta M, Abo-Zaid M, Abdel-Halim H (2019) Plant-wide modeling and optimization of a large-scale WWTP using BioWin’s ASDM model. J Water Process Eng 31:100819. https://doi.org/10.1016/j.jwpe.2019.100819
Foo DCY, Chemmangattuvalappil N, Ng DKS, Elyas R, Chen C-L, Elms RD, Lee H-Y, Chien I-L, Chong S, Chong CH (2017) Chemical engineering process simulation. Chem Eng Process Simul
Geankoplis CJ (2013) Transport processes and separation process principles, 4th edn. Prentice-Hall international Inc, Englewood-Cliffs, NJ
GPP (2021) Kerosene price
Grimshaw P, Calo JM, Hradil G (2011) Cyclic electrowinning/precipitation (CEP) system for the removal of heavy metal mixtures from aqueous solutions. Chem Eng J 175:103–109. https://doi.org/10.1016/j.cej.2011.09.062
Halim SFA, Chang SH, Morad N (2020) Extraction of Cu(II) ions from aqueous solutions by free fatty acid-rich oils as green extractants. J Water Process Eng 33:100997. https://doi.org/10.1016/J.JWPE.2019.100997
Harun N, Othman NA, Zaki NA, Mat Rasul NA, Samah RA, Hashim H (2019) Simulation of anaerobic digestion for biogas production from food waste using superpro designer. Mater Today Proc 19:1315–1320. https://doi.org/10.1016/j.matpr.2019.11.143
Ho, L. (2021) Private Communications
Intelligen.com (2014) SuperPro designer user guide
Kemcore (2021) Raw materials price
Liu Y, Khan A, Wang Z, Chen Y, Zhu S, Sun T, Liang D, Yu H (2020) Upcycling of electroplating sludge to prepare erdite-bearing nanorods for the adsorption of heavy metals from electroplating wastewater effluent. Water 12(4):1027. https://doi.org/10.3390/w12041027
Lok X, Chan YJ, Foo DCY (2020) Simulation and optimisation of full-scale palm oil mill effluent (POME) treatment plant with biogas production. J Water Process Eng. https://doi.org/10.1016/j.jwpe.2020.101558
Mohammed AA, Hussein MA, Albdiri ADZ (2018) Application of bulk liquid membrane technique for cadmium extraction from aqueous solution. Arab J Sci Eng 43(11):5851–5858. https://doi.org/10.1007/s13369-017-3039-4
Nasdaq (2021) Copper price
Ofi (2021) Vegetable oil price
Petrides DP, Abeliotis KG, Aelion V, Venkat E, Mallick SK (1995) EnviroCAD: a computer tool for analysis and evaluation of waste recovery, treatment and disposal processes. J Hazardous Mater 42(3):225–246. https://doi.org/10.1016/0304-3894(95)00072-3
Petrides D (2001) Process modelling evaluates feasibility of water recycling. Filtr Sep 38(8):26-31. https://doi.org/10.1016/S0015-1882(01)80494-8
Prabhu PP, Prabhu B (2018) A review on removal of heavy metal ions from waste water using natural/modified bentonite. In: Raghuvir PB, Mathew TM (eds) MATEC web of conferences, 144, p 02021. https://doi.org/10.1051/matecconf/201814402021
Rahman ML, Wong ZJ, Sarjadi MS, Soloi S, Arshad SE, Bidin K, Musta B (2021) Heavy metals removal from electroplating wastewater by waste fiber-based poly(amidoxime) ligand. Water 13(9):1260. https://doi.org/10.3390/w13091260
Rounaghi GH, Ghaemi A, Chamsaz M (2016) Separation study of some heavy metal cations through a bulk liquid membrane containing 1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane. Arab J Chem 9:S490–S496. https://doi.org/10.1016/j.arabjc.2011.06.013
Sinnott RK, Towler G (2013) Chemical engineering design, chemical engineering design. Elsevier, Amsterdam. https://doi.org/10.1016/C2009-0-61216-2
Smith R (2016) Chemical process design and integration, 2nd edn. Wiley, Chichester
Song J, Huang T, Qiu H, Niu X, Li X-M, Xie Y, He T (2018) A critical review on membrane extraction with improved stability: potential application for recycling metals from city mine. Desalination 440:18–38. https://doi.org/10.1016/j.desal.2018.01.007
Sudibyo D, Junaedi A, Handoko AS, Mufakhir FK, Nurjaman F, Amin M, Supriyatna YI, Sumardi S, Salsabila P (2020) Nickel recovery from electrocoagulation sludge of hydrometallurgy wastewater using electrowinning. In: Proceedings of the 3rd international seminar on metallurgy and materials (ISMM2019): exploring new innovation in metallurgy and materials, p 020008. https://doi.org/10.1063/5.0001929
Suo C, Du K, Yuan R, Chen H, Wang F, Zhou B (2020) Adsorption study of heavy metal ions from aqueous solution by activated carbon in single and mixed system. Desalin Water Treat. https://doi.org/10.5004/dwt.2020.25236
Tialoc (2021) Private Communications
TNB (2021) Pricing & Tariffs, Tenaga Nasional Berhad
Varentsov VK, Bataev IA (2017) Ion-exchange membranes in gold electowinning processes on flow-through carbon fiber electrodes. Pet Chem 57(11):961–968. https://doi.org/10.1134/S0965544117090092
Vitanza R, Colussi I, Cortesi A, Gallo V (2016) Implementing a respirometry-based model into BioWin software to simulate wastewater treatment plant operations. J Water Process Eng 9:267–275. https://doi.org/10.1016/j.jwpe.2015.02.007
Zheng H, Chen J, Wang B, Zhao S (2013) Recovery of copper ions from wastewater by hollow fiber supported emulsion liquid membrane. Chin J Chem Eng 21(8):827–834. https://doi.org/10.1016/S1004-9541(13)60547-9
Acknowledgements
The authors would like to acknowledge Sin Yang Lim from Tialoc Malaysia Sdn Bhd who provided the local purchase price of process equipment in the study. Technical advice by Lena Ho is also gratefully acknowledged.
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All authors contributed to the study conception and design. Methodology, data collection and analysis were performed by JYL and XYC. Software model was originally developed by JYL and improved by XYC. Supervision was performed by DF and SHC. All authors read and approved the final manuscript.
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Lai, J.Y., Chua, X.Y., Foo, D.C.Y. et al. Techno-economic analysis of integrating liquid membrane with electrowinning for copper recovery from electroplating wastewater. Clean Techn Environ Policy 24, 2203–2213 (2022). https://doi.org/10.1007/s10098-022-02313-1
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DOI: https://doi.org/10.1007/s10098-022-02313-1