Abstract
LiNi0.6Co0.2Mn0.2O2 (NCM622) materials with shuttle-like hierarchical micro architecture are prepared by sodium dodecyl benzene sulfonate (SDBS) assisted hydrothermal method and followed heat treatment method. The effects of SDBS mass percentage on the crystalline structure, morphology, and electrochemical performance of NCM622 are studied. The results show that SDBS adjunction improves the crystallinity and reduces the degree of cation mixing. With the addition of SDBS, the particle size of synthesized sample becomes smaller and the distribution is more uniform. Electrochemical results show that the introduction of SDBS can facilitate the electrochemical properties of NCM622. When the weight percentage of SDBS is up to 2.5 wt %, the obtained NCM622 sample displays the best electrochemical properties: its discharge specific capacities are 184.2 mAh g−1 and 114 mAh g−1at 0.2 C and 10 C, respectively, which are higher than those prepared by other liquid methods, displaying a favorable rate capacity. And the capacity retention rate of 91.06% with 160.2 mAh g−1 after 100 cycles at 1 C rate. It is verified that the appropriate addition of SDBS can able to effectively improve the electrochemical performance of NCM622 as cathode materials for lithium-ion batteries.
Similar content being viewed by others
References
Wang X, Ding YL, Deng YP, Chen Z (2020) Ni‐rich/Co‐poor layered cathode for automotive Li‐ion batteries: promises and challenges. Adv Energy Mater 10(12)
Duan J, Wu C, Cao Y, Huang D, Du K, Peng Z, Hu G (2017) Enhanced compacting density and cycling performance of Ni-riched electrode via building mono dispersed micron scaled morphology. J Alloys Compd 695(91–99)
Kim J, Lee H, Cha H, Yoon M, Park M, Cho J (2018) Prospect and reality of Ni-rich cathode for commercialization. Adv Energy Mater 8(6)
Zybert M, Ronduda H, Szczęsna A, Trzeciak T, Ostrowski A, Żero E, Wieczorek W, Rarog-Pilecka W, Marcinek M (2020) Different strategies of introduction of lithium ions into nickel-manganese-cobalt carbonate resulting in LiNi0.6Mn0.2Co0.2O2 (NMC622) cathode material for Li-ion batteries. Solid State Ion 348
Ansah S, Hyun H, Shin N, Lee JS, Lim J, Cho HH (2021) A modeling approach to study the performance of Ni-rich layered oxide cathode for lithium-ion battery. Comput Mater Sci 196
Larcher D, Tarascon JM (2015) Towards greener and more sustainable batteries for electrical energy storage. Nat Chem 7(1):19–29
Liu W, Oh P, Liu X, Lee MJ, Cho W, Chae S, Kim Y, Cho J (2015) Nickel-rich layered lithium transition-metal oxide for high-energy lithium-ion batteries. Angew Chem Int Ed Engl 54(15):4440–4457
Jamil S, Yu R, Wang Q, Fasehullah M, Huang Y, Yang Z, Yang X, Wang X (2020) Enhanced cycling stability of nickel-rich layered oxide by tantalum doping. J Power Sources 473
Sun HH, Kim UH, Park JH, Park SW, Seo DH, Heller A, Mullins CB, Yoon CS, Sun YK (2021) Transition metal-doped Ni-rich layered cathode materials for durable Li-ion batteries. Nat Commun 12(1):6552
Zhao X, An L, Sun J, Liang G (2018) LiNi0.5Co0.2Mn0.3O2 hollow microspheres-synthesis, characterization and application as cathode materials for power lithium ion batteries. J Electroanal Chem 810(1–10)
Chae BJ, Yim T (2018) Effect of surface modification using a sulfate-based surfactant on the electrochemical performance of Ni-rich cathode materials. Mater Chem Phys 214(66–72)
Liu W, Li X, Xiong D, Hao Y, Li J, Kou H, Yan B, Li D, Lu S, Koo A, Adair K, Sun X (2018) Significantly improving cycling performance of cathodes in lithium ion batteries: The effect of Al2O3 and LiAlO2 coatings on LiNi0.6Co0.2Mn0.2O2. Nano Energy 44(111–120)
Zhao X, Liu B, Yang J, Hou J, Wang Y, Zhu Y (2020) Synthesizing LiNi0.5Co0.2Mn0.3O2 with microsized peanut-like structure for enhanced electrochemical properties of lithium ion batteries. J Alloys Compd 832
Lin S, Wang Z, Lu T, Wang H, Li P, Yang F, Guo Z (2020) One-step preparation of homogeneous single crystal Li-rich cathode materials with encouraging electrochemical performance. J Alloys Compd 822
Zhan X, Gao S, Cheng YT (2019) Influence of annealing atmosphere on Li2ZrO3-coated LiNi0.6Co0.2Mn0.2O2 and its high-voltage cycling performance. Electrochim Acta 300(36–44)
Zhu Y, Tian X, Zhou X, Zhang P, Angulakshmi N, Zhou Y (2019) Controlling the oxygen deficiency for improving the insertion performance of the layered LiNi0.6Co0.2Mn0.2O2. Electrochim Acta 328
Tao T, Chen C, Yao Y, Liang B, Lu S, Chen Y (2017) Enhanced electrochemical performance of ZrO2 modified LiNi0.6Co0.2Mn0.2O2 cathode material for lithium ion batteries. Ceram Int 43(17):15173–15178
Lee SW, Kim H, Kim MS, Youn HC, Kang K, Cho BW, Roh KC, Kim KB (2016) Improved electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathode material synthesized by citric acid assisted sol-gel method for lithium ion batteries. J Power Sources 315(261–268)
Wang R, Li Z, Yang Z, Zhang M, Zhang D, Yan Y (2021) Synergistic effect of Ce4+ modification on the electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathode materials at high cut-off voltage. Ceram Int 47(1):1268–1276
Wang J, Lu X, Zhang Y, Zhou J, Wang J, Xu S (2022) Grain size regulation for balancing cycle performance and rate capability of LiNi0.9Co0.055Mn0.045O2 single crystal nickel-rich cathode materials. J Energy Chem 65(681–687)
Liu G, Li M, Wu N, Cui L, Huang X, Liu X, Zhao Y, Chen H, Yuan W, Bai Y (2018) Single-crystalline particles: an effective way to ameliorate the intragranular cracking, thermal stability, and capacity fading of the LiNi0.6Co0.2Mn0.2O2 electrodes. J Electrochem Soc 165(13):A3040–A3047
Ashoka S, Nagaraju G, Thipperudraiah KV, Chandrappa GT (2010) Controlled synthesis of cadmium carbonate nanowires, nanoribbons, nanorings and sphere like architectures via hydrothermal method. Mater Res Bull 45(11):1736–1740
Ju X, Huang H, He W, Zheng H, Deng P, Li S, Qu B, Wang T (2018) Surfactant-assisted synthesis of high energy {010} facets beneficial to li-ion transport kinetics with layered LiNi0.6Co0.2Mn0.2O2. ACS Sustain Chem Eng 6(5):6312–6320
Zhou M, Gong J, Deng Z, Lang Y, Zong B, Guo J, Wang L (2019) Synthesis and electrochemical performances of LiNi0.5Mn1.5O4 spinels with different surface orientations for lithium-ion batteries. Ionics 26(5):2187–2200
Yin C, Li Y, Zhang T, Liu J, Yuan Y, Huang M (2020) Effects of exposure to anionic surfactants (SDBS and SDS) on nitrogen removal of aerobic denitrifier. Water Environ Res 92(12):2129–2139
Zhou H, Yang Z, Yin C, Yang S, Li J (2018) Fabrication of nanoplate Li-rich cathode material via surfactant-assisted hydrothermal method for lithium-ion batteries. Ceram Int 44(16):20514–20523
Zhao X, An L, Sun J, Liang G (2018) LiNi0.5Co0.2Mn0.3O2-LiMn0.6Fe0.4PO4 mixture with both excellent electrochemical performance and low cost as cathode material for power lithium ion batteries. J Electrochem Soc 165(2):A142-A148
Lang Y, Sun X, Xue G, Duan X, Wang L, Liang G (2022) Synthesis and enhanced electrochemical performance of LiNi0.5Mn1.5O4 materials with porous hierarchical microsphere structure by a surfactant-assisted method. J Mater Sci 57(7):4664–4683
Yang X, Weitong Y, Junqi P, Xiaoying L, Qi J, Fangcheng C, Guoping W (2021) Preparation of LiNi0.6Co0.2Mn0.2O2 by PVP modified liquid-phase assisted solid-phase method and its electrochemical energy storage performance. Ceram Int 47(21):30266–30272
Fu F, Xu GL, Wang Q, Deng YP, Li X, Li JT, Huang L, Sun SG (2013) Synthesis of single crystalline hexagonal nanobricks of LiNi1/3Co1/3Mn1/3O2 with high percentage of exposed {010} active facets as high rate performance cathode material for lithium-ion battery. J Mater Chem A 1(12)
Huang B, Wang M, Zuo Y, Zhao Z, Zhang X, Gu Y (2020) The effects of reheating process on the electrochemical properties of single crystal LiNi0.6Mn0.2Co0.2O2. Solid State Ion 345
Langdon J, Manthiram A (2021) A perspective on single-crystal layered oxide cathodes for lithium-ion batteries. Energy Storage Mater 37(143–160)
Lee SH, Sim SJ, Jin BS, Kim HS (2020) High performance well-developed single crystal LiNi0.91Co0.06Mn0.03O2 cathode via LiCl-NaCl flux method. Mater Lett 270
Jiang H, Li J, Lei Y, Chen Y, Lai C, Shi L, Peng C (2020) Stabling LiNi0.8Co0.1Mn0.1O2 by PVP-assisted LiF-LaF3 layer for lithium ion batteries with improved electrochemical properties at high cut-off voltage. J Taiwan Institute Chem Eng 114(331–340)
Wang X, Hao H, Liu J, Huang T, Yu A (2011) A novel method for preparation of macroposous lithium nickel manganese oxygen as cathode material for lithium ion batteries. Electrochim Acta 56(11):4065–4069
Funding
This work was financially supported by the basic research plan in Shanxi Province (Grant No. 202203021222215), the Award Fund for Outstanding Doctors in Shanxi Province (Grant No. 20192026), the Technology Innovation of Colleges in Shanxi Province (Grant No. 2020L0340), and the Graduate innovation training program in Taiyuan University of Science and Technology (Grant No. XCX212008).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Zhao, X., Liu, H., He, P. et al. Synthesis and enhanced electrochemical properties of LiNi0.6Co0.2Mn0.2O2 cathode materials via SDBS-assisted hydrothermal method. J Solid State Electrochem 27, 2479–2488 (2023). https://doi.org/10.1007/s10008-023-05533-7
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-023-05533-7