Abstract
Thermal runaway (TR) behavior of 38 Ah lithium-ion batteries with various states of charge (SOC) is experimentally investigated in this work using extended volume plus accelerating rate calorimeter (EV+ ARC). Some of the critical kinetic parameters, such as onset exothermic temperature (Tonset), temperature of TR (TTR), and maximum temperature (Tmax), can be obtained to characterize the risks of TR event. The impact of SOC on thermal stability of the battery is researched. It is found that the higher the SOC state, the lower the battery safety. Thermal features of both the cathode and anode, as well as the materials, are also investigated. The morphology and the structure change of the materials are characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD). Finally, a general theory is proposed and detailed reactions are summarized in this work. The thermal runaway follows a mechanism of chain reactions, during which the decomposition reactions of the battery component materials occur one after another.
Similar content being viewed by others
References
Sasaki T, Ukyo Y, Novák P (2013) Nat Mater 12(6):569–575
Wang XC, Huang YD, Jia DZ, Guo ZP, Ni D, Miao M (2012) J Solid State Electrochem 16(1):17–24
Feng XN, Ouyang MG, Liu X, Lu LG, Xia Y, He XM (2018) Energy Storage Mater 10:246–267
Spotnitz R, Franklin J (2003) J Power Sources 113(1):81–100
Wen J, Yu Y, Chen C (2012) Mater Express 2(3):197–212
Ren DS, Liu X, Feng XN, Lu LG, Ouyang MG, Li JQ, He XM (2018) Appl Energy 228:633–644
Feng XN, Zheng SQ, Ren DS, He XM, Wang L, Cui H, Liu X, Jin CY, Zhang FS, Xu CS, Hsu HJ, Gao S, Chen TY, Li YL, Wang TZ, Wang H, Li MG, Ouyang MG (2019) Appl Energy 246:53–64
Feng XN, Ren DS, He XM, Ouyang MG (2020) Joule 4(4):743–770
Ren DS, Hsu HJ, Li RH, Feng XN, Guo DX, Han XB, Lu LG, He XM, Gao S, Hou JX, Li Y, Wang YL, Ouyang MG (2019) eTransportation 2:100034
Richard MN, Dahn JR (1999) J Electrochem Soc 146:2068–2077
Jiang J, Dahn JR (2004) Electrochem Commun 6(7):724–728
Ishikawa H, Mendoza O, Sone Y, Umeda M (2012) J Power Sources 198:236–242
Feng XN, Fang M, He XM, Ouyang MG, Lu LG, Wang H, Zhang MX (2014) J Power Sources 255:294–301
Dai JH, Shi C, Li C, Shen X, Peng LQ, Wu DZ, Sun DH, Zhang P, Zhao JB (2016) Energy Environ Sci 9(10):3252–3261
Zhu YS, Wang FX, Liu LL, Xiao SY, Chang Z, Wu YP (2013) Energy Environ Sci 6(2):618–624
Croce F, Focarete ML, Hassoun J, Meschini I, Scrosati B (2011) Energy Environ Sci 4(3):921–927
Choudhury S, Azizi M, Raguzin I, Gobel M, Michel S, Simon F, Willomitzer A, Mechtcherine V, Stamm M, Ionov L (2017) Phys Chem Chem Phys 19(18):11239–11248
Miao YE, Zhu GN, Hou H, Xia YY, Liu T (2013) J Power Sources 226:82–86
Liu X, Ren DS, Hsu HJ, Feng XN, Xu GL, Zhuang MH, Gao H, Lu LG, Han XB, Chu ZY, He XM, Amine K, Ouyang MG (2018) Joule 2:1–18
Kvasha A, Gutiérrez C, Osa U, Meatza I, Blazquez JA, Macicior H, Urdampilleta I (2018) Energy 159:547–557
Mendoza-Hernandez OS, Ishikawa H, Nishikawa Y, Maruyama Y, Umeda M (2015) J Power Sources 280:499–504
Kim JH, Lee KH, Ko DC, Lee SB, Kim BM (2017) J Mecha Sci Tech 31(5):2505–2511
Wuersig A, Scheifele W, Novák P (2007) J Electrochem Soc 154(5):A449–A454
Yang H, Bang H, Amine K, Prakash J (2005) J Electrochem Soc 152(1):A73–A79
Hu EY, Bak SM, Liu J, Yu XQ, Zhou YN, Ehrlich SN, Yang XQ, Nam KW (2014) Chem Mater 26(2):1108–1118
Zhang Z, Fouchard D, Rea JR (1998) J Power Sources 70(1):16–20
Huang XS (2011) J Solid State Electrochem 15(4):649–662
Morcrette M, Chabre Y, Vaughan G, Amatucci G, Leriche JB, Patoux S, Masquelier C, Tarascon JM (2002) Electrochim Acta 47(19):3137–3149
Ohzuku T, Iwakoshi Y, Sawai K (1993) J Electrochem Soc 140(9):2490–2496
Wu K, Yang J, Liu Y, Zhang Y, Wang CY, Xu JM, Ning F, Wang DY (2013) J Power Sources 237:285–290
Chen CH, Liu J, Amine K (2001) J Power Sources 96(2):321–328
Acknowledgments
This work is supported by the National Key R&D Program of China (2016YFB0100304) and Gotion High-Tech Power Energy CO., Ltd., Hefei, Anhui, China.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Lu, D., Lin, S., Hu, S. et al. Thermal behavior and failure mechanism of large format lithium-ion battery. J Solid State Electrochem 25, 315–325 (2021). https://doi.org/10.1007/s10008-020-04810-z
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-020-04810-z