Abstract
This paper explains some properties of gel polymer electrolytes, which are mostly used in lithium ion batteries. An emphasis is laid on the internal structure and its influence on the mobility of ions in the substance. The ions are solvated and located randomly in the liquid base of the gel, and their movement is predominantly determined by the Stokes law for liquid electrolytes. Polymethylmethacrylate gel is used as a model substance here. This report is based on the experience of the authors and their associates.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10008-017-3563-x/MediaObjects/10008_2017_3563_Fig1_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10008-017-3563-x/MediaObjects/10008_2017_3563_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10008-017-3563-x/MediaObjects/10008_2017_3563_Fig3_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10008-017-3563-x/MediaObjects/10008_2017_3563_Fig4_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10008-017-3563-x/MediaObjects/10008_2017_3563_Fig5_HTML.gif)
Similar content being viewed by others
References
Natarajan A, Stephan AM, Chan CH, Kalarikkal N, Thomas S (2017) Electrochemical studies on composite gel polymer electrolytes for lithium sulfur-batteries. J Appl Polym Sci 234:44594
Hicham BY, Oihane G-C, Nerea L et al (2016) Cross-linked solid polymer electrolyte for all-solid-state rechargeable lithium batteries. Electrochemica Acta 220:487–594
Wang J-Y, Wang M-CH, Jan D-J (2017) Synthesis of poly(methyl methacrylate)-succinonitrile composite polymer electrolyte and its application for flexible electrochromic devices. Sol Energy Mater Sol Cells 160:476–483
Xueyi L, Youhao L, Huili X et al (2016) Enhancement of cyclic stability for high voltage lithium ion battery at elevated temperature by using polyethylene-supported poly(methyl methacrylate–butyl acrylate–acrolonitrile–styrene)-based novel gel electrolyte. Electrochemica Acta 220:47–56
Kim J-K (2017) Hybrid gel polymer electrolyte for high-safety lithium-sulfur batteries. Mater Lett 187:40–43
Virya A, Keryn L (2017) Polyacrolamide-lithiumchloride polymer electrolyte and its applications in electrochemical capacitors. Electrochem Commun 74:33–37
Selter P, Grote S, Brunklaus G (2016) Synthesis and li-ion dynamics in polyarylene-ethersulfone-phenylene-oxide-based poylmer electrolytes. Macromol Chem Phys 217(23):2584–2594
Wang J, Mai Y, Luo H (2016) Fluorosilane compounds with oligo(ethylene oxide) substituent as safe electrolyte solvents for high-voltage lithium-ion batteries. J Power Sources 334:58–64
Hsu C-Y, Liu R-J, Hsu C-H et al (2016) High thermal and electrochemical stability of PVDF-graft-PAN copolymer hybrid PEO membrane for safety reinforced lithium-ion battery. RSC Adv 6(22):18082–18088
Rezrazi M, Mullet M, Bohnke O, Aride J, Bendriss A, Benkhouja K, et al (1993) Conductivity and viscosity studies od lithium ion conductive electrolytes gelled with poly(methylmethacrylate), Conference: 6th International Seminar on the Physical Chemistry of Solid State Materials (REMCES VI) Location: El Jadida, Morocco
Bohnke O et al (1992) Gel electrolyte for solid-state electrochromic cell. J Electrochem Soc 139(7):1862–1865
Zaccaria M, Gualandi C, Fabiani D (2012) Effect of oxide nanoparticles on thermal and mechanical properties of electrospun separators for lithium-ion batteries. J Nanomater 2012:216012
Stichova Z, Sedlaříkova M, Vondrák J, Maca J (2012) Sulfolane based electrolytes for li-ion accumulators. ECS Trans 40(1):59–64
Maca J, Sedlaříkova M, Vondrák J, Bartušek K (2012) Physical properties of sulfolane-dimethylcarbonate mixture for using in electrolytes for lithium-ion batteries. ECS Trans 40(1):53–57
Jahn M, Gel polymer electrolyte with addition of ionic liquid, unpublished
Korinek R, Vondrák J, Bartušek K, Macalik M (2010) NMR measurement of gel electrolytes during polymerization process. ECS Trans 32(1):11–16
Vondrák J, Sedlaříkova M, Velicka J (2003) Gel polymer electrolytes based on PMMA III. PMMA gels containing cadmium. Electrochim Acta 48:1001–1004
Musil M, Transference number in GPE, unpublished
Vondrák J, Conductivity of various GPE, unpublished
Reiter J, Vondrák J, Micka Z (2005) The electrochemical redox processes in PMMA gel electrolytes—behavior of transition metal complexes. Electrochim Acta 52:4469–4476
Krejza O, Vondrák J, Sedlaříkova M, Velicka J (2008) The presence of nanostructured Al2O3 in PMMA-based gel electrolytes. J Power Sources 178:774–778
Evans J, Vincent C, Bruce P (1987) Conductivity and transference number measurements on polymer electrolytes. Solid State Ionics 28:2324–2328
Vondrák J, Sedlaříkova M, Velická J, Klápště B, Novák V, Reiter J (2001) Gel polymer electrolytes based on PMMA. Electrochim Acta 46:2047–2048
Acknowledgements
This research work has been carried out in the Centre for Research and Utilization of Renewable Energy (CVVOZE). Authors gratefully acknowledge the financial support from the Ministry of Education, Youth and Sports of the Czech Republic under NPU I program (project No. LO1210).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Vondrák, J., Sedlaříková, M., Libich, J. et al. Insights on electrochemical properties of gel polymer electrolytes based on methylmethacrylate. J Solid State Electrochem 21, 2615–2620 (2017). https://doi.org/10.1007/s10008-017-3563-x
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-017-3563-x