Skip to main content
SpringerLink
Log in

1H and 2H Magic Angle Spinning Nuclear Magnetic Resonance Study of Phase Transition in KH3(SeO3)2 and Deuterated KD3(SeO3)2

  • Published:
Applied Magnetic Resonance Aims and scope Submit manuscript

Abstract

The chemical shifts and spin–lattice relaxation times T 1ρ in KH3(SeO3)2 and deuterated KD3(SeO3)2 were measured in the rotating frame as functions of temperature by 1H magic angle spinning (MAS) nuclear magnetic resonance (NMR) and 2H MAS NMR, respectively. There were no significant changes in T 1ρ for 1H and 2H nuclei near T C, except for a change in the number of proton signals. The transition is driven by the number of resonance lines resulting from the crystal’s ferroelastic properties. Near T m, the chemical shifts and T 1ρ values for 1H and 2H in the two materials changed abruptly, which implies variation of the structural geometry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. L.W. Gorbatyi, W.I. Ponomarev, D.M. Kheiker, Kristallografiya 16, 899 (1971)

    Google Scholar 

  2. W. Zapart, S. Waplak, J. Stankowski, L. Shuvalov, J. Phys. Soc. Jpn. 44, 1600 (1978)

    Article  ADS  Google Scholar 

  3. A. Sakai, I. Tatsuzaki, J. Phys. Soc. Jpn. 50, 3016 (1981)

    Article  ADS  Google Scholar 

  4. L.A. Shuvalov, N.R. Ivanov, T.K. Sitnik, Kristallografiya 12, 366 (1967)

    Google Scholar 

  5. L.A. Shuvalov, N.R. Ivanov, T.K. Sitnik, Sov. Phys. Crystallogr. 12, 315 (1967)

    Google Scholar 

  6. N.R. Ivanov, L.A. Shuvalov, H. Schmidt, E. Stocp, Izv. Akad. Nauk USSR 39, 933 (1975)

    Google Scholar 

  7. Y. Makita, F. Sakurai, Phys. Lett. A 55, 435 (1976)

    Article  ADS  Google Scholar 

  8. L.V. Gorbatyi, V.I. Ponomarev, D.M. Kheiker, Sov. Phys. Crystallogr. 16, 781 (1972)

    Google Scholar 

  9. B. Prelesnik, R. Herak, L.J. Manojlovic-Muir, K.W. Muir, Acta Crystallogr. B 28, 3104 (1971)

    Article  Google Scholar 

  10. Y. Makita, F. Sakurai, T. Osaka, I. Tatsuzaki, J. Phys. Soc. Jpn. 42, 518 (1977)

    Article  ADS  Google Scholar 

  11. Y. Makita, Y. Yamaguchi, S. Suzuki, J. Phys. Soc. Jpn. 43, 181 (1977)

    Article  ADS  Google Scholar 

  12. L.A. Huvalov, N.R. Ivanov, T.K. Sitnik, Kristallografiya 12, 315 (1967)

    Google Scholar 

  13. N.R. Ivanov, L.A. Shuvalov, N.V. Gordeeva, Sov. Phys. Crystallogr. 13, 145 (1968)

    Google Scholar 

  14. T. Yagi, I. Tatsuzaki, J. Phys. Soc. Jpn. 26, 865 (1969)

    Article  ADS  Google Scholar 

  15. S. Grande, H.D. Mecke, L.A. Shuvalov, Phys. Stat. Sol. (a) 46, 547 (1978)

    Article  ADS  Google Scholar 

  16. M. Kasahara, J. Phys. Soc. Jpn. 44, 537 (1978)

    Article  ADS  Google Scholar 

  17. H. Tanaka, T. Yagi, I. Tatsuzaki, J. Phys. Soc. Jpn. 44, 1257 (1978)

    Article  ADS  Google Scholar 

  18. T. Makita, T. Osaka, A. Miyazaki, J. Phys. Soc. Jpn. 44, 225 (1978)

    Article  ADS  Google Scholar 

  19. N.R. Ivanov, Izv. Akad. Nauk SSSR Ser. Fiz. 43, 1706 (1979)

    Google Scholar 

  20. M.P. McNeal, S.J. Jan, R.E. Newham, J. Appl. Phys. 83, 3298 (1998)

    Article  ADS  Google Scholar 

  21. N.A. Pertsev, E.K.H. Salje, Phys. Rev. B 61, 902 (2000)

    Article  ADS  Google Scholar 

  22. V.N. Nechaev, A.V. Huba, Bull. Russ. Acad. Sci. Phys. 71, 1367 (2007)

    Article  Google Scholar 

  23. R. Blinc, B. Lozar, J. Slak, S. Zumer, L.A. Shuvalov, Phys. Rev. B 23, 6133 (1981)

    Article  ADS  Google Scholar 

  24. J. Seliger, V. Zagar, R. Blinc, A. Novak, J. Chem. Phys. 84, 5857 (1986)

    Article  ADS  Google Scholar 

  25. A.R. Lim, W.K. Jung, J. Phys. D Appl. Phys. 41, 135407 (2008)

    Article  ADS  Google Scholar 

  26. A.R. Lim, S.-Y. Jeong, Central. Eur. J. Phys. 11, 124 (2013)

    Google Scholar 

  27. T.V. Quynh, G. Schmidt, N.R. Ivanov, L.A. Shuvalov, Phys. Stat. Sol. (a) 36, k85 (1976)

    Article  ADS  Google Scholar 

  28. C.W. Garland, G. Park, I. Tatsuzaki, Phys. Rev. B 29, 221 (1984)

    Article  ADS  Google Scholar 

  29. F. Hansen, R.G. Hazell, S.E. Rasmussen, Acta Chem. Scand. 23, 2561 (1969)

    Article  Google Scholar 

  30. M.S. Lehmann, F.K. Larsen, Acta Chem. Scand. 25, 3859 (1971)

    Article  Google Scholar 

  31. J.L. Koening, Spectroscopy of Polymers (Case Western Reserve University Press, Cleveland, 1991)

    Google Scholar 

Download references

Acknowledgments

This research was supported by the Basic Science Research program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science, and Technology (2015R1A1A3A04001077).

Author information

Authors and Affiliations

  1. Department of Science Education, Jeonju University, Jeonju, 560-759, Korea

    Ae Ran Lim

  2. Department of Carbon Fusion Engineering, Jeonju University, Jeonju, 560-759, Korea

    Ae Ran Lim

Authors
  1. Ae Ran Lim
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ae Ran Lim.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lim, A.R. 1H and 2H Magic Angle Spinning Nuclear Magnetic Resonance Study of Phase Transition in KH3(SeO3)2 and Deuterated KD3(SeO3)2 . Appl Magn Reson 46, 1293–1300 (2015). https://doi.org/10.1007/s00723-015-0722-z

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00723-015-0722-z

Keywords

Search

Navigation