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A simple and efficient synthesis of organosilicon compounds containing 1,2,3-triazole moieties catalyzed by ZSM-5 zeolite-supported Cu–Co bimetallic oxides

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Abstract

A new efficient procedure for preparation of 1,2,3-triazole derivatives by 1,3-dipolar cycloaddition of benzyl halides, sodium azide, and propargyl alcohol over Cu–Co/ZSM-5 bimetallic nanocatalyst in aqueous media under conventional heating and ultrasonic irradiation was developed. The maximum activity of the catalyst was reported under ultrasonic irradiation with a noticeable reduction in the reaction time. The generated products were utilized as substrates for the synthesis of a series of new 1,2,3-triazole derivatives containing organosilylvinyl substituent and bulky organosilicon groups using (RSiMe2)3CLi (R = Me, Ph).

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Acknowledgments

We thank Dr. B. Eftekhari-Sis for his helpful comments. The authors also would like to acknowledge the financial support from University of Tabriz and Iranian Nanotechnology Initiative.

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Authors and Affiliations

  1. Organosilicon Research Laboratory, Faculty of Chemistry, University of Tabriz, Tabriz, 5166616471, Iran

    Kazem D. Safa & Hanieh Mousazadeh

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  1. Kazem D. Safa
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  2. Hanieh Mousazadeh
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Correspondence to Kazem D. Safa.

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Safa, K.D., Mousazadeh, H. A simple and efficient synthesis of organosilicon compounds containing 1,2,3-triazole moieties catalyzed by ZSM-5 zeolite-supported Cu–Co bimetallic oxides. Monatsh Chem 147, 1951–1961 (2016). https://doi.org/10.1007/s00706-016-1699-5

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  • DOI: https://doi.org/10.1007/s00706-016-1699-5

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