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Metal organic framework derived Zn/N co-doped hydrophilic porous carbon for efficient solid phase microextraction of polar phenols

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Abstract

MOF-derived zink and nitrogen co-doped porous carbon (ZNPC) was synthesized through the pyrolysis of MOF-5-NH2 and used as a solid-phase microextraction (SPME) coating material. Coupled with gas chromatography-mass spectrometry (GC–MS), headspace SPME (HS-SPME) based on ZNPC was adopted for the determination of phenols in food samples. The co-existence of N and Zn in ZNPC endows the derived carbon superior hydrophilicity, which is highly beneficial for phenols capture. After optimizing the conditions of extraction and desorption, a sensitive analytical method was established with low limits of detections (LODs, 0.73–2.3 ng g−1) and wide linear ranges (5–5000 ng g−1). Both the intra-fiber repeatability (RSDs from 2.8–7.3%) and inter-fiber reproducibility (RSDs from 9.7–11.7%) were satisfactory. The established method was applied to phenol determination in beef jerky and duck neck with satisfactory recoveries of 81.2–120.4% and RSDs of 2.8–9.9%, which met well with the requirement of practical application.

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Funding

This work was supported by the National Natural Science Foundation of China (21806148) and the Natural Science Foundation of Zhejiang Province (LY21B070009).

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Authors and Affiliations

  1. State Key Laboratory of Biogeology and Environmental Geology, Faculty of Materials Science and Chemistry, China University of Geosciences, Hongshan District, No. 388, Lumo Road, Wuhan, 430074, People’s Republic of China

    Qian Yan, Lijin Huang, Weikang Guo, Lei Ouyang & Qin Shuai

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  1. Qian Yan
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  2. Lijin Huang
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  3. Weikang Guo
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  4. Lei Ouyang
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  5. Qin Shuai
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Correspondence to Lijin Huang or Qin Shuai.

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The authors declare no competing interest.

Credit authorship statement

Qian Yan: investigation, software, and writing—original draft; Lijin Huang: conception, review and editing, and funding acquisition; Weikang Guo: data analysis and review; Lei Ouyang: review and editing; Qin Shuai: resource acquisition.

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Yan, Q., Huang, L., Guo, W. et al. Metal organic framework derived Zn/N co-doped hydrophilic porous carbon for efficient solid phase microextraction of polar phenols. Microchim Acta 188, 400 (2021). https://doi.org/10.1007/s00604-021-05060-0

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  • DOI: https://doi.org/10.1007/s00604-021-05060-0

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