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Magnetic porous carbon derived from Zn/Co metal–organic framework as an adsorbent for extraction and determination of carbamates

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Abstract

A novel magnetic porous carbon with a high specific surface and magnetization saturation, derived from a Zn/Co-MOF-5, was fabricated by direct carbonization of Zn/Co-MOF-5 without the need of additional carbon precursors under optimum pyrolysis temperature. The material was employed as an adsorbent for magnetic solid-phase extraction of four carbamates from water and tomato samples prior to high-performance liquid chromatography–tandem quadrupole mass spectrometry analysis. Under optimum conditions, the method displayed good linearity (r > 0.9987) within the concentration range 0.05–20 ng mL−1 for water samples and 0.1–40 ng g−1 for tomato samples. The limits of detection (S/N = 3) for the four carbamate pesticides were in the range 0.0006–0.013 ng mL−1 for water samples and 0.001–0.01 ng g−1 for tomato samples and satisfactory spiked recoveries in the range 86.1 to 109.1% were obtained with the relative standard deviation values from 2.1 to 14.0%.

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Funding

This work is supported by the National Natural Science Foundation of China (Grant No. 21861035) and the Xinjiang Uygur Autonomous Region Natural Science Foundation (Grant No. 2018D01C083).

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Authors and Affiliations

  1. Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi, 830046, People’s Republic of China

    Meng Wang, Kangkang Wang, Tingxiang Chen & Jide Wang

  2. Xinjiang Uygur Autonomous Region Center for Disease Control and Prevention, Urumqi, 830002, People’s Republic of China

    Meng Wang

  3. Technical Center of Urumqi Customs, Urumqi, 830063, People’s Republic of China

    Jingjing Wang

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  1. Meng Wang
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Correspondence to Jide Wang.

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Wang, M., Wang, J., Wang, K. et al. Magnetic porous carbon derived from Zn/Co metal–organic framework as an adsorbent for extraction and determination of carbamates. Microchim Acta 187, 507 (2020). https://doi.org/10.1007/s00604-020-04426-0

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