Skip to main content

Advertisement

SpringerLink
Log in

Diphenyl diselenide grafted onto a Fe3O4-chitosan composite as a new nanosorbent for separation of metal ions by effervescent salt-assisted dispersive magnetic micro solid-phase extraction

  • Original Paper
  • Published:
Microchimica Acta Aims and scope Submit manuscript

Abstract

Diphenyl diselenide was immobilized on chitosan loaded with magnetite (Fe3O4) nanoparticles to give an efficient and cost-effective nanosorbent for the preconcentration of Pb(II), Cd(II), Ni(II) and Cu(II) ions by using effervescent salt-assisted dispersive magnetic micro solid-phase extraction (EA-DM-μSPE). The metal ions were desorbed from the sorbent with 3M nitric acid and then quantified via microflame AAS. The main parameters affecting the extraction were optimized using a one-at-a-time method. Under optimum condition, the limits of detection, linear dynamic ranges, and relative standard deviations (for n = 3) are as following: Pb(II): 2.0 ng·mL−1; 6.3–900 ng·mL−1; 1.5%. Cd(II): 0.15 ng·mL−1; 0.7–85 ng·mL−1, 3.2%; Ni(II): 1.6 ng·mL−1,.6.0–600. ng·mL−1, 4.1%; Cu(II): 1.2 ng·mL−1, 3.0–300 ng·mL−1, 2.2%. The nanosorbent can be reused at least 4 times.

Fe3O4-chitosan composite was modified with diphenyl diselenide as a sorbent for separation of metal ions by effervescent salt-assisted dispersive magnetic micro solid-phase extraction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Jin Z, Nie H, Yang Z, Zhang J, Liu Z, Xu X, Huang S (2012) Metal-free selenium doped carbon nanotube/graphene networks as a synergistically improved cathode catalyst for oxygen reduction reaction. Nanoscale 4(20):6455–6460

    Article  CAS  Google Scholar 

  2. Gamage A, Shahidi F (2007) Use of chitosan for the removal of metal ion contaminants and proteins from water. Food Chem 104(3):989–996

    Article  CAS  Google Scholar 

  3. Vold IM, Vårum KM, Guibal E, Smidsrød O (2003) Binding of ions to chitosan—selectivity studies. Carbohyd Polym 54(4):471–477

    Article  CAS  Google Scholar 

  4. Kandile NG, Mohamed HM, Mohamed MI (2015) New heterocycle modified chitosan adsorbent for metal ions (II) removal from aqueous systems. Int J Biol Macromol 72:110–116

    Article  CAS  Google Scholar 

  5. Liu L, Li C, Bao C, Jia Q, Xiao P, Liu X, Zhang Q (2012) Preparation and characterization of chitosan/graphene oxide composites for the adsorption of Au (III) and Pd (II). Talanta 93:350–357

    Article  CAS  Google Scholar 

  6. Jayakumar R, Prabaharan M, Reis R, Mano J (2005) Graft copolymerized chitosan—present status and applications. Carbohyd Polym 62(2):142–158

    Article  CAS  Google Scholar 

  7. Fahimirad B, Asghari A, Rajabi M (2017) A novel nanoadsorbent consisting of covalently functionalized melamine onto MWCNT/Fe3O4 nanoparticles for efficient microextraction of highly adverse metal ions from organic and inorganic vegetables: optimization by multivariate analysis. J Mol Liq

  8. Fan H-L, Zhou S-F, Jiao W-Z, Qi G-S, Liu Y-Z (2017) Removal of heavy metal ions by magnetic chitosan nanoparticles prepared continuously via high-gravity reactive precipitation method. Carbohyd Polym 174:1192–1200

    Article  CAS  Google Scholar 

  9. Ajmal M, Rao RA, Ahmad R, Ahmad J, Rao LA (2001) Removal and recovery of heavy metals from electroplating wastewater by using Kyanite as an adsorbent. J Hazard Mater 87(1–3):127–137

    Article  CAS  Google Scholar 

  10. Zawisza B, Baranik A, Malicka E, Talik E, Sitko R (2016) Preconcentration of Fe (III), Co (II), Ni (II), Cu (II), Zn (II) and Pb (II) with ethylenediamine-modified graphene oxide. Micro Chim Acta 183(1):231–240

    Article  CAS  Google Scholar 

  11. Shokrollahi A, Ghaedi M, Hossaini O, Khanjari N, Soylak M (2008) Cloud point extraction and flame atomic absorption spectrometry combination for copper (II) ion in environmental and biological samples. J Hazard Mater 160(2–3):435–440

    Article  CAS  Google Scholar 

  12. Jha MK, Gupta D, Choubey PK, Kumar V, Jeong J, Lee J-c (2014) Solvent extraction of copper, zinc, cadmium and nickel from sulfate solution in mixer settler unit (MSU). Sep Purif Technol 122:119–127

    Article  CAS  Google Scholar 

  13. Komjarova I, Blust R (2006) Comparison of liquid–liquid extraction, solid-phase extraction and co-precipitation preconcentration methods for the determination of cadmium, copper, nickel, lead and zinc in seawater. Anal Chim Acta 576(2):221–228

    Article  CAS  Google Scholar 

  14. Karimi M, Dadfarnia S, Shabani AMH, Tamaddon F, Azadi D (2015) Deep eutectic liquid organic salt as a new solvent for liquid-phase microextraction and its application in ligandless extraction and preconcentraion of lead and cadmium in edible oils. Talanta 144:648–654

    Article  CAS  Google Scholar 

  15. Tobiasz A, Walas S (2014) Solid-phase-extraction procedures for atomic spectrometry determination of copper. Trends Analyt Chem 62:106–122

    Article  CAS  Google Scholar 

  16. Fahimirad B, Asghari A, Rajabi M (2017) Magnetic graphitic carbon nitride nanoparticles covalently modified with an ethylenediamine for dispersive solid-phase extraction of lead (II) and cadmium (II) prior to their quantitation by FAAS. Micro Chim Acta 184(8):3027–3035

    Article  CAS  Google Scholar 

  17. Lasarte-Aragonés G, Lucena R, Cárdenas S, Valcárcel M (2011) Effervescence-assisted dispersive micro-solid phase extraction. J Chromatogr A 1218(51):9128–9134

    Article  Google Scholar 

  18. Daşbaşı T, Saçmacı Ş, Ülgen A, Kartal Ş (2016) Determination of some metal ions in various meat and baby food samples by atomic spectrometry. Food Chem 197:107–113

    Article  Google Scholar 

  19. Rajabi M, Rezaie A, Ghaedi M (2015) Simultaneous extraction and preconcentration of some metal ions using eucalyptus-wood based activated carbon modified with silver hydroxide nanoparticles and a chelating agent: optimization by an experimental design. RSC Adv 5(108):89204–89217

    Article  CAS  Google Scholar 

  20. Rangraz Y, Nemati F, Elhampour A (2018) Magnetic chitosan composite as a green support for anchoring diphenyl diselenide as a biocatalyst for the oxidation of sulfides. Int J Biol Macromol 117:820–830

  21. Gupta A, Chauhan VS, Sankararamakrishnan N (2009) Preparation and evaluation of iron–chitosan composites for removal of As (III) and As (V) from arsenic contaminated real life groundwater. Water Res 43(15):3862–3870

    Article  CAS  Google Scholar 

  22. Duran C, Senturk HB, Elci L, Soylak M, Tufekci M (2009) Simultaneous preconcentration of Co (II), Ni (II), Cu (II), and Cd (II) from environmental samples on Amberlite XAD-2000 column and determination by FAAS. J Hazard Mater 162(1):292–299

    Article  CAS  Google Scholar 

  23. Taghizadeh M, Asgharinezhad AA, Pooladi M, Barzin M, Abbaszadeh A, Tadjarodi A (2013) A novel magnetic metal organic framework nanocomposite for extraction and preconcentration of heavy metal ions, and its optimization via experimental design methodology. Micro Chim Acta 180(11–12):1073–1084

    Article  CAS  Google Scholar 

  24. Alothman ZA, Yilmaz E, Habila M, Soylak M (2015) Solid phase extraction of metal ions in environmental samples on 1-(2-pyridylazo)-2-naphthol impregnated activated carbon cloth. Ecotoxicol Environ Saf 112:74–79

    Article  CAS  Google Scholar 

  25. Yilmaz E, Soylak M (2014) Solid phase extraction of cd, Pb, Ni, cu, and Zn in environmental samples on multiwalled carbon nanotubes. Environ Monit Assess 186(9):5461–5468

    Article  CAS  Google Scholar 

  26. Mohammadi S, Afzali D, Pourtalebi D (2010) Flame atomic absorption spectrometric determination of trace amounts of lead, cadmium and nickel in different matrixes after solid phase extraction on modified multiwalled carbon nanotubes. Cent Eur J Chem 8(3):662–668

    CAS  Google Scholar 

Download references

Acknowledgments

The authors would like to thank the Semnan University Research Council for the financial support of this work.

Author information

Authors and Affiliations

  1. Department of Chemistry, Semnan University, Semnan, 35195-363, Iran

    Bahareh Fahimirad, Yalda Rangraz, Ali Elhampour & Firouzeh Nemati

Authors
  1. Bahareh Fahimirad
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yalda Rangraz
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ali Elhampour
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Firouzeh Nemati
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Firouzeh Nemati.

Ethics declarations

The author(s) declare that they have no competing interests.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

ESM 1

(DOCX 482 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fahimirad, B., Rangraz, Y., Elhampour, A. et al. Diphenyl diselenide grafted onto a Fe3O4-chitosan composite as a new nanosorbent for separation of metal ions by effervescent salt-assisted dispersive magnetic micro solid-phase extraction. Microchim Acta 185, 560 (2018). https://doi.org/10.1007/s00604-018-3094-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s00604-018-3094-x

Keywords

Search

Navigation