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Assessing magmatic volatile equilibria through FTIR spectroscopy of unexposed melt inclusions and their host quartz: a new technique and application to the Mesa Falls Tuff, Yellowstone

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Abstract

Fourier transform infrared spectroscopy (FTIR) is a precise, non-destructive, and highly sensitive means of measuring volatile species in melt inclusions. Existing methods of applying FTIR to quartz-hosted melt inclusions, however, require challenging physical manipulation of the host quartz crystals, which can present a significant limitation. Here, we describe a technique for measuring the H2O and CO2 concentrations of melt inclusions fully enclosed in quartz crystals using transmission FTIR, where melt inclusion thickness is calculated using the host quartz silicate overtones. The greater thickness of quartz crystals permitted by this technique allows an additional assessment of volatile equilibrium by measuring structural OH− within the quartz host itself. To demonstrate the advantages of this technique, we applied it to quartz crystals from the Mesa Falls Tuff, Yellowstone. The majority of melt inclusions consist of transparent or brown glassy melt inclusions and record concentrations of 2.9–3.3 wt% H2O and 181–561 ppm CO2, with precision similar to that obtained by standard double-exposed FTIR. Based on volatile saturation models, such concentrations reflect a largely un-degassed magma body equilibrated at pre-eruptive pressures of 100–150 MPa. These H2O concentrations and equilibrium conditions are supported by independent assessments using mineral–mineral and mineral-melt thermohygrometry and thermodynamic modelling using rhyolite-MELTS. The preservation of pre-eruptive volatile concentrations is further corroborated by measurements of OH− in the quartz hosts. A clear decrease in hydroxyl concentrations from core to rim matches closely the zoning in Al, which, combined with the position of quartz infrared bands, most likely reflects variations in Al-moderated OH− solubility rather than diffusive loss. The outermost 200 µm rims, however, show a sharper decline in OH− and corresponding increase in Li+ which is interpreted to record minor diffusive H+ loss and incorporation of Li+ to maintain charge balance. Our FTIR-based technique is simple, effective, and widely applicable to other quartz-bearing magmatic systems, opening up new possibilities to trace pre- syn- and post-eruptive volatile behaviour.

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References

  • Aubaud C, Withers AC, Hirschmann MM, Guan YB, Leshin LA, Mackwell SJ, Bell DR (2007) Intercalibration of FTIR and SIMS for hydrogen measurements in glasses and nominally anhydrous minerals. Am Miner 92:811–828

    Article  Google Scholar 

  • Befus KS, Gardner JE (2016) Magma storage and evolution of the most recent effusive and explosive eruptions from Yellowstone Caldera. Contrib Miner Petrol 171:30

    Article  Google Scholar 

  • Befus KS, Gardner JE, Zinke RW (2012) Analyzing water contents in unexposed glass inclusions in quartz crystals. Am Miner 97:1898–1904

    Article  Google Scholar 

  • Behrens H, Tamic N, Holtz F (2004) Determination of the molar absorption coefficient for the infrared absorption band of CO2 in rhyolitic glasses. Am Miner 89:301–306

    Article  Google Scholar 

  • Bindeman IN, Valley JW (2001) Low-δ18O rhyolites from Yellowstone: magmatic evolution based on analyses of Zircons and individual phenocrysts. J Petrol 42:1491–1517

    Article  Google Scholar 

  • Biró T, Kovács IJ, Karátson D, Stalder R, Király E, Falus G, Fancsik T, Sándorné JK (2017) Evidence for post-depositional diffusional loss of hydrogen in quartz phenocryst fragments within ignimbrites. Am Miner 102:1187–1201

    Article  Google Scholar 

  • Blundy J, Cashman K, Humphreys M (2006) Magma heating by decompression-driven crystallisation beneath andesite volcanoes. Nature 443:76–80

    Article  Google Scholar 

  • Bucholz CE, Gaetani GA, Behn MD, Shimizu N (2013) Post-entrapment modification of volatiles and oxygen fugacity in olivine-hosted melt inclusions. Earth Planet Sci Lett 374:145–155

    Article  Google Scholar 

  • Charlier BLA, Morgan DJ, Wilson CJN, Wooden JL, Allan ASR, Baker JA (2012) Lithium concentration gradients in feldspar and quartz record the final minutes of magma ascent in an explosive supereruption. Earth Planet Sci Lett 319–320:218–227

    Article  Google Scholar 

  • Cherniak DJ (2010) Diffusion in quartz, melilite, silicate perovskite, and mullite. Rev Miner Geochem 72:735–756

    Article  Google Scholar 

  • Cherniak DJ, Dimanov A (2010) Diffusion in pyroxene, mica and amphibole. Rev Miner Geochem 72:641–690

    Article  Google Scholar 

  • Christiansen RL (2001) The Quaternary and Pliocene Yellowstone Plateau volcanic field of Wyoming, Idaho, and Montana. U.S. Geol Surv Prof Pap 729-G, G1-G143

  • Demouchy S, Bolfan-Casanova N (2016) Distribution and transport of hydrogen in the lithospheric mantle: a review. Lithos 240–243:402–425

    Article  Google Scholar 

  • Dixon JE, Stolper EM (1995) An Experimental Study of Water and Carbon Dioxide Solubilities in Mid-Ocean Ridge Basaltic Liquids Part II: Applications to Degassing. J Petrol 36:1633–1646

    Google Scholar 

  • Ellis B, Mark D, Troch J, Bachmann O, Guillong M, Kent A, von Quadt A (2017) Split-grain 40Ar/39Ar dating: integrating temporal and geochemical data from crystal cargoes. Chem Geol 457:15–23

    Article  Google Scholar 

  • Farrell J, Smith RB, Husen S, Diehl T (2014) Tomography from 26 years of seismicity revealing that the spatial extent of the Yellowstone crustal magma reservoir extends well beyond the Yellowstone caldera. Geophys Res Lett 41(9):3068–3073

    Article  Google Scholar 

  • Ferriss E, Plank T, Walker D (2016) Site-specific diffusion rates during clinopyroxene dehydration. Contrib Miner Petrol 171:55–79

    Article  Google Scholar 

  • Frigo C, Stalder R, Hauzenberger CA (2016) OH defects in quartz in granitic systems doped with spodumene, tourmaline and/or apatite: experimental investigations at 5–20 kbar. Phys Chem Miner 43:717–729

    Article  Google Scholar 

  • Gaetani GA, O’Leary JA, Shimizu N, Bucholz CE, Newville M (2012) Rapid reequilibration of H2O and oxygen fugacity in olivine-hosted melt inclusions. Geology 40:915–918

    Article  Google Scholar 

  • Grove TL, Elkins-Tanton LT, Parman SW, Chatterjee N, Müntener O, Gaetani GA (2003) Fractional crystallisation and mantle-melting controls on calc-alkaline differentiation trends. Contrib Miner Petrol 145:515–533

    Article  Google Scholar 

  • Gualda GA, Ghiorso MS, 2015. MELTS_Excel: a microsoft excel-based MELTS interface for research and teaching of magma properties and evolution. Geochem Geophys Geosyst 16:315–324

    Article  Google Scholar 

  • Gualda GAR, Ghiorso MS, Lemons RV, Carley TL (2012) Rhyolite-MELTS: a modified calibration of MELTS optimized for silica-rich, fluid-bearing magmatic systems. J Petrol 53:875–890

    Article  Google Scholar 

  • Hirschmann MM (2006) Water, melting and the deep earth H2O Cycle. Annu Rev Earth Planet Sci 34:629–653

    Article  Google Scholar 

  • Izett GA (1981) Volcanic ash beds: recorders of Upper Cenozoic silicic pyroclastic volcanism in the western United States. J Geophys Res 86(B11):10200–10222

    Article  Google Scholar 

  • Jackson A, Parker RL, Sambridge M, Constable C, Wolf AS (2018) The inverse problem of unpolarized infrared spectroscopy of geological materials: estimation from noisy random sampling of a quadratic form. Am Miner 103:1176–1184

    Article  Google Scholar 

  • Kats A (1962) Hydrogen in alpha-quartz. Philips Res Rep 17:133–279

    Google Scholar 

  • Koga K, Hauri E, Hirschmann M, Bell D (2003) Hydrogen concentration analyses using SIMS and FTIR: comparison and calibration for nominally anhydrous minerals. Geochem Geophys Geosyst. https://doi.org/10.1029/2002GC000378

    Article  Google Scholar 

  • Kovács I, Hermann J, O’Neill HSC, FitzGerald J, Sambridge M, Horváth G (2008) Quantitative absorbance spectroscopy with unpolarized light: part II. Experimental evaluation and development of a protocol for quantitative analysis of mineral IR spectra. Am Miner 93:765–778

    Article  Google Scholar 

  • Kronenberg AK, Kirby SH (1986) Solubility and diffusional uptake of hydrogen in Quartz at high water pressures: implications for hydrolytic weakening. J Geophys Res 91:12723–12744

    Article  Google Scholar 

  • Kronenberg AK, Kirby SH (1987) Ionic conductivity of quartz: DC time dependence and transition in charge carriers. Am Miner 72:739–747

    Google Scholar 

  • Kumamoto KM, Warren JM, Hauri EH (2017) New SIMS reference materials for measuring water in upper mantle minerals. Am Miner 102:537–547

    Article  Google Scholar 

  • Le Voyer M, Asimow PD, Mosenfelder JL, Guan Y, Wallace PJ, Schiano P, Stolper EM, Eiler JM (2014) Zonation of H2O and F concentrations around melt inclusions in Olivines. J Petrol 55:685–707

    Article  Google Scholar 

  • Lloyd AS, Plank T, Ruprecht P (2013) Volatile loss from melt inclusions in pyroclasts of differing sizes. Contrib Miner Petrol 165:129–153

    Article  Google Scholar 

  • Lloyd AS, Ruprecht P, Hauri EH, Rose W, Gonnermann HM, Plank T (2014) NanoSIMS results from olivine-hosted melt embayments: Magma ascent rate during explosive basaltic eruptions. J Volcanol Geotherm Res 283:1–18

    Article  Google Scholar 

  • Lowenstern JB, Pitcher BW (2013) Analysis of H2O in silicate glass using attenuated total reflectance (ATR) micro-FTIR spectroscopy. Am Miner 98:1660–1668

    Article  Google Scholar 

  • Mavrogenes JA, Bodnar RJ (1994) Hydrogen movement into and out of fluid inclusions in quartz: Experimental evidence and geologic implications. Geochim Cosmochim Acta 58:141–148

    Article  Google Scholar 

  • Métrich N, Wallace PJ (2008) Volatile abundances in basaltic magmas and their degassing paths tracked by melt inclusions. Rev Miner Geochem 69:363–402

    Article  Google Scholar 

  • Mosenfelder JL, Le Voyer M, Rossman GR (2011) Analysis of hydrogen in olivine by SIMS: evaluation of standards and protocol. Am Miner 96:1725–1741

    Article  Google Scholar 

  • Myers ML, Wallace PJ, Wilson CJN, Morter BK, Swallow EJ (2016) Prolonged ascent and episodic venting of discrete magma batches at the onset of the Huckleberry Ridge supereruption, Yellowstone. Earth Planet Sci Lett 451:285–297

    Article  Google Scholar 

  • Myers ML, Wallace PJ, Wilson CJN (2019) Inferring magma ascent timescales and reconstructing conduit processes in explosive rhyolitic eruptions using diffusive losses of hydrogen from melt inclusions. J Volcanol Geotherm Res 369:95–112

    Article  Google Scholar 

  • Neukampf J, Ellis BS, Magna T, Laurent O, Bachmann O (2019) Partitioning and isotopic fractionation of lithium in mineral phases of hot, dry rhyolites: the case of the Mesa Falls Tuff, Yellowstone. Chem Geol 506:175–186

    Article  Google Scholar 

  • Newman S, Lowenstern JB (2002) VolatileCalc: a silicate melt-H2O–CO2 solution model written in Visual Basic for excel. Comput Geosci 28:597–604

    Article  Google Scholar 

  • Nichols ARL, Wysoczanski RJ (2007) Using micro-FTIR spectroscopy to measure volatile contents in small and unexposed inclusions hosted in olivine crystals. Chem Geol 242:371–384

    Article  Google Scholar 

  • Padrón-Navarta JA, Hermann J, O’Neill HStC (2014) Site-specific hydrogen diffusion rates in forsterite. Earth Planet Sci Lett 392:100–112

    Article  Google Scholar 

  • Perkins ME, Nash BP (2002) Explosive silicic volcanism of the Yellowstone hotspot: the ash fall tuff record. Geol Soc Am Bull 114:367–381

    Article  Google Scholar 

  • Plank T, Kelley KA, Zimmer MM, Hauri EH, Wallace PJ (2013) Why do mafic arc magmas contain ~ 4 wt% on average? Earth Planet Sci Lett 364:168–179

    Article  Google Scholar 

  • Portnyagin M, Almeev R, Matveev S, Holtz F (2008) Experimental evidence for rapid water exchange between melt inclusions in olivine and host magma. Earth Planet Sci Lett 272:541–552

    Article  Google Scholar 

  • Putirka KD (2008) Thermometers and barometers for volcanic systems. Rev Miner Geochem 69:61–120

    Article  Google Scholar 

  • Rivera TA, Schmitz MD, Jicha BR, Crowley JL (2016) Zircon petrochronology and 40Ar/39Ar sanidine dates for the Mesa Falls Tuff: crystal-scale records of magmatic evolution and the short lifespan of a large Yellowstone magma chamber. J Petrol 57(9):1677–1704

    Google Scholar 

  • Severs MJ, Azbej T, Thomas JB, Mandeville CW, Bodnar RJ (2007) Experimental determination of H2O loss from melt inclusions during laboratory heating: evidence from Raman spectroscopy. Chem Geol 237:358–371

    Article  Google Scholar 

  • Skirius CM, Peterson JW, Anderson AT (1990) Homogenizing rhyolitic glass inclusions from the Bishop Tuff. Am Miner 75:1381–1398

    Google Scholar 

  • Stalder R, Konzett J (2012) OH defects in quartz in the system quartz-albite-water and granite-water between 5 and 25 kbar. Phsy Chem Miner 39:817–827

    Article  Google Scholar 

  • Stalder R, Potrafke A, Billström K, Skogby H, Meinhold G, Gögele C, Berberich T (2017) OH defects in quartz as monitor for igneous, metamorphic, and sedimentary processes. Am Miner 102:1832–1842

    Article  Google Scholar 

  • Stelten ME, Cooper KM, Vazquez JA, Calvert AT, Glessner JJ (2015) Mechanisms and timescales of generating eruptible rhyolitic magmas at Yellowstone Caldera from Zircon and Sanidine geochronology and geochemistry. J Petrol 56:1607–1642

    Article  Google Scholar 

  • Stolper E, Newman S (1994) The role of water in the petrogenesis of Mariana trough magmas. Earth Planet Sci Lett 121:293–325

    Article  Google Scholar 

  • Swallow EJ, Wilson CJN, Myers ML, Wallace PJ, Collins KS, Smith EGC (2018) Evacuation of multiple magma bodies and the onset of caldera collapse in a supereruption, captured in glass and mineral compositions. Contrib Miner Petrol 173:33

    Article  Google Scholar 

  • Szymanowski D, Fehr M, Guillong M, Coble MA, Wotzlaw JF, Nasdala L, Ellis BS, Bachmann O, Schönbächler M (2018) Isotope-dilution anchoring of zircon reference materials for accurate Ti-in-zircon thermometry. Chem Geol 481:146–154

    Article  Google Scholar 

  • Thomas S-M, Koch-Müller M, Reichart P, Rhede D, Thomas R, Wirth R, Matsyuk S (2009) IR calibrations for water determination in olivine, r-GeO2 and SiO2 polymorphs. Phsy Chem Miner 36:489–509

    Article  Google Scholar 

  • Tollan PME, O’Neill HStC, Hermann J (2018) The role of trace elements in controlling H incorporation in San Carlos olivine. Contrib Miner Petrol 173:89. https://doi.org/10.1007/s00410-018-1517-7

    Article  Google Scholar 

  • Troch J, Ellis BS, Mark DF, Bindeman IN, Kent AJR, Guillong M, Bachmann O (2017) Rhyolite generation prior to a Yellowstone supereruption: Insights from the Island Park-Mount Jackson rhyolite series. J Petrol 0(0):1–24

    Google Scholar 

  • Vazquez JA, Kyriazis SF, Reid MR, Sehler RC, Ramos FC (2009) Thermochemical evolution of young rhyolites at Yellowstone: evidence for a cooling but periodically replenished postcaldera magma reservoir. J Volcanol Geotherm Res 188:186–196

    Article  Google Scholar 

  • von Aulock FW, Kennedy BM, Schipper CI, Castro JM, Martin DE, Oze C, Watkins JM, Wallace PJ, Puskar L, Bégué F, Nichols ARL, Tuffen H (2014) Advances in Fourier transform infrared spectroscopy of natural glasses: from sample preparation to data analysis. Lithos 206–207:52–64

    Article  Google Scholar 

  • Wallace PJ (2005) Volatiles in subduction zone magmas: concentrations and fluxes based on melt inclusion and volcanic gas data. J Volcanol Geotherm Res 140:217–240

    Article  Google Scholar 

  • Wallace PJ, Kamenetsky VS, Cervantes P (2015) Melt inclusion CO2 contents, pressures of olivine crystallization, and the problem of shrinkage bubbles. Am Miner 100:787–794

    Article  Google Scholar 

  • Waters LE, Lange RA (2015) An updated calibration of the plagioclase-liquid hygrometer-thermometer applicable to basalts through rhyolites. Am Miner 100:2172–2184

    Article  Google Scholar 

  • Watts KE, Bindeman IN, Schmitt AK (2012) Crystal scale anatomy of a dying supervolcano: an isotope and geochronology study of individual phenocrysts from voluminous rhyolites of the Yellowstone caldera. Contrib Miner Petrol 164:45–67

    Article  Google Scholar 

  • Zhang Y, Ni H (2010) Diffusion of H, C, and O components in silicate melts. Rev Miner Geochem 72:171–226

    Article  Google Scholar 

  • Zhang Y, Belcher R, Ihinger PD, Wang L, Xu Z, Newman S (1997) New calibration of infrared measurement of dissolved water in rhyolitic glasses. Geochim Cosmochim Acta 61:3089–3100

    Article  Google Scholar 

  • Zhang Y, Xu Y, Zhu M, Wang H (2007) Silicate melt properties and volcanic eruptions. Rev Geophys 45:1–27

    Article  Google Scholar 

  • Zhang Y, Ni H, Chen Y (2010) Diffusion data in silicate melts. Rev Miner Geochem 72:311–408

    Article  Google Scholar 

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Acknowledgements

Jörg Hermann is thanked for many engaging discussions during development of the FTIR protocol. This work was supported by the Swiss National Science Foundation (grant 200021_166281 to BE) and by the ETH foundation (ETH-05 13-2 covering JT). The LA–ICP–MS dataset was acquired with the support of Swiss National Science Foundation Grant 206021_170722. We thank Francesca Piccoli for her assistance with lab operations, Gordon Moore for his editorial work and Kayla Iacovino, Jacob Lowenstern and Paul Wallace for their detailed reviews.

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  1. Institut für Geologie, Universität Bern, Baltzerstrasse 1+3, 3012, Bern, Switzerland

    Peter Tollan

  2. Institut für Geochemie und Petrologie, ETH Zürich, NW Clausiusstrasse 25, 8092, Zurich, Switzerland

    Ben Ellis, Juliana Troch & Julia Neukampf

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  1. Peter Tollan
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Correspondence to Peter Tollan.

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Communicated by Gordon Moore.

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Tollan, P., Ellis, B., Troch, J. et al. Assessing magmatic volatile equilibria through FTIR spectroscopy of unexposed melt inclusions and their host quartz: a new technique and application to the Mesa Falls Tuff, Yellowstone. Contrib Mineral Petrol 174, 24 (2019). https://doi.org/10.1007/s00410-019-1561-y

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