Abstract
MgO nanoparticles and nanoflakes were prepared using sol–gel and hydrothermal methods, and the effect of size and morphology of MgO nanostructures on the thermal conductivity and stability of the transformer oil-based nanofluid containing these nanostructures was investigated. The structural properties of the samples were examined using X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). The results showed that the nanostructure’s shape depends on the fabrication method, pH, temperature, and synthesis time. Also, the measurements showed that the thermal conductivity of nanofluids containing MgO nanoflakes with different wt% has higher values than that of nanofluids containing MgO nanoparticles. It was found that by increasing the concentration of nano additives up to 1 wt%, the thermal conductivity increased and then decreased for higher concentrations. The maximum increase of 11.3% was measured for nanofluid containing 1 wt% of nanoflakes. Likewise, the stability of nanoflake’s nanofluid was observed to be higher.
Graphical Abstract
Similar content being viewed by others
Availability of data and material
No data was associated in the manuscript.
References
Choi S, Zhang Z, Yu W, Lockwood F, Grulke E (2001) Anomalous thermal conductivity enhancement in nanotube suspensions. Appl Phys Lett 79:2252–2254
Rafiq M, Shafique M, Azam A, Ateeq M (2021) Transformer oil-based nanofluid: the application of nanomaterials on thermal, electrical and physicochemical properties of liquid insulation-a review. Ain Shams Eng J 12:555–576
Bindhu M, Umadevi M, Micheal MK, Arasu MV, Al-Dhabi NA (2016) Structural, morphological and optical properties of MgO nanoparticles for antibacterial applications. Mater Lett 166:19–22
Ebrahimi M, Manafi S, Sharifianjazi S (2023) The effect of Ag2O and MgO dopants on the bioactivity, biocompatibility, and antibacterial properties of 58S bioactive glass synthesized by the sol-gel method. J Non-Crystal 606:122189
Abazari S, Shamsipur A, Bakhsheshi-Rad HR, Keshavarz M, Kehtari M, Ramakrishna S, Berto F (2022) MgO-incorporated carbon nanotubes-reinforced Mg-based composites to improve mechanical, corrosion, and biological properties targeting biomedical applications. J Mater Res Technol 20:976–990
Mylarappa M, Raghavendra N, Surendra BS, Shravana Kumar KN, Kantharjau S (2022) Electrochemical, photocatalytic and sensor studies of clay/MgO nanoparticles. Appl Surf Sci Adv 10:100268
Pilarska A, Wysokowski M, Markiewicz E, Jesionowski T (2013) Synthesis of magnesium hydroxide and its calcinates by a precipitation method with the use of magnesium sulfate and poly (ethylene glycols). Powder technol 235:148–157
Zhan J, Bando Y, Hu J, Golberg D (2004) Bulk synthesis of single-crystalline magnesium oxide nanotubes. Inorg chem 43:2462–2464
Kawaguchi Y (2000) Luminescence spectra at bending fracture of single crystal MgO. Solid State Commun 117:17–20
Jin T, He Y (2011) Antibacterial activities of magnesium oxide (MgO) nanoparticles against foodborne pathogens. J Nanopart Res 13:6877–6885
Bertinetti L, Drouet C, Combes C, Rey C, Tampieri A, Coluccia S, Martra G (2009) Surface characteristics of nanocrystalline apatites: effect of Mg surface enrichment on morphology, surface hydration species, and cationic environments. Langmuir 25:5647–5654
Tang ZX, Lv BF (2014) MgO nanoparticles as antibacterial agent: preparation and activity. Braz J Chem Eng 31:591–601
Subramania A, Kumar GV, Priya AS, Vasudevan T (2007) Polyol-mediated thermolysis process for the synthesis of MgO nanoparticles and nanowires. Nanotechnol 18:225601
Lind C, Gates SD, Pedoussaut NM, Baiz TI (2010) Novel materials through non-hydrolytic sol-gel processing: negative thermal expansion oxides and beyond. Materials 3:2567–2587
Athar T, Hakeem A, Ahmed W (2012) Synthesis of MgO nanopowder via non aqueous sol–gel method. Adv Sci Lett 7:27–29
Farbod M, Kouhpeymani asl R, Noghreh abadi AR (2015) Morphology dependence of thermal and rheological properties ofoil-based nanofluids of CuO nanostructures. Colloids Surf, A Physicochem Eng Asp 474:71–75
Farbod M, Ahangarpour A, Etemad SGh (2015) Stability and thermal conductivity of water-based carbon nanotube nanofluids. Particuology 22:59–65
Farbod M, Rafati Z, Zargar Shoushtari M (2016) Optimization of parameters for the synthesis of Y2Cu2O5 nanoparticles by Taguchi method and comparison of their magnetic and optical properties with their bulk counterpart. J Magn Magn Mater 407:266–271
Evans W, Prasher R, Fish J, Meakin P, Phelan P, Keblinski P (2008) Effect of aggregation and interfacial thermal resistance on thermal conductivity of nanocomposites and colloidal nanofluids. Int J Heat Mass Transf 51:1431–1438
Funding
The authors would like to acknowledge the Shahid Chamran University of Ahvaz for the financial support of this work.
Author information
Authors and Affiliations
Contributions
Author 1 planned the scheme, initiated the project, and suggested the experiments; Author 2 conducted the experiments and analyzed the empirical results; Author 3 was the advisor of project and held to analysis and/or interpretation of data. The manuscript was written through the contribution of all authors. All authors discussed the results and reviewed and approved the final version of the manuscript.
Corresponding author
Ethics declarations
Consent for publication
Not applicable.
Competing interests
The authors declare no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Highlights
• Transformer oil-based nanofluid containing MgO NFs and NPs were prepared.
• Effect of size and morphology of NP and NFs on thermal conductivity was measured.
• Thermal conductivity of nanofluids containing MgO NFs was higher than NPs.
• The maximum increase of 11.3% was measured for nanofluid containing 1 wt% NFs.
• Nanofluids containing NFs were more stable and remained stable for several weeks.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Farbod, M., Saki, N. & Ahangarpour, A. Investigation of size and morphology effects of MgO nanostructures on the properties of MgO/transformer oil-based nanofluids. Colloid Polym Sci 301, 1305–1311 (2023). https://doi.org/10.1007/s00396-023-05156-4
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00396-023-05156-4