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Wide near-infrared II emissions and LED application of Y2Ti2O7: Cr3+/Yb3+/Nd3+ phosphors

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Abstract

Y2Ti2O7:Cr3+/Yb3+/Nd3+ phosphors with broadband near-infrared emission were developed by a high-temperature solid-state method. Under the excitation of 405 nm light, it shows broadband near-infrared emission from 650 to 1050 nm. Y2Ti2O7:Cr3+/Yb3+/Nd3+ phosphors present excellent bright luminescence and thermal quenching resistance. The energy transfer mechanism between Cr3+/Nd3+/Yb3+ ions was elucidated. By using the energy transfer from Cr3+-Nd3+-Yb3+, the excitation efficiency of Yb3+ at 405 nm is greatly improved, and the strong NIR emission centered at approximately 975 nm is well coupled with the absorption band of silicon solar cells. The Y2Ti2O7:0.005Cr3+/0.1Yb3+/0.01Nd3+ phosphors were assembled with a commercial 365 nm InGaN chip to fabricate a near-infrared LED device that can work under operating electric currents of 100–900 mA. In short, Y2Ti2O7:Cr3+/Yb3+/Nd3+ phosphors are suitable for near-infrared LED applications.

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Data that support the findings of this study are available from the corresponding author upon reasonable request.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Grant Nos. 11704056, 12274049 and 11774042) and Fundamental Research Funds for the Central Universities (grant No. 3132023519).

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ZH and HY managed the long-term experiments and data analyses and processed the main manuscript. Other authors contributed to the discussion and revision of the experimental results.

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Han, Z., Yu, H., Cong, S. et al. Wide near-infrared II emissions and LED application of Y2Ti2O7: Cr3+/Yb3+/Nd3+ phosphors. Appl. Phys. A 129, 764 (2023). https://doi.org/10.1007/s00339-023-07023-z

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