Abstract
Nanocomposites films based on Poly Vinyl Pyrrolidone/Chitosan (PVP/Chitosan) filled by Vanadium pentoxide nanoparticles (V2O5 NPs) have been produced via solution casting method. Vanadium pentoxide nanoparticles were scattered direct in the blend of PVP/Chitosan by one-potential laser ablation technique. The main purpose in using Vanadium pentoxide nanoparticles is to modify the structural, optical, and electrical characterization of PVP/Chitosan composite. The complexation between Vanadium pentoxide nanoparticles and PVP/Chitosan has been approved via XRD and FTIR-ATR analyses. The average size of V2O5 was 20.5 nm. After the scattering by vanadium pentoxide nanoparticles, AC conductivity improved. The values of dielectric constant and dielectric lose decreased as the frequencies enhanced. At lower frequency, greater values of dielectric constant and dielectric lose have been detected due to the mobile charges inside the polymeric backbone. The fabricated PVP/Chitosan/V2O5 NPs films could be suggested for electrical and optoelectronic applications.
Similar content being viewed by others
References
C.V.S. Rao, M. Ravi, V. Raja, P.B. Bhargav, A.K. Sharma, V.N. Rao, Preparation and characterization of PVP-based polymer electrolytes for solid-state battery applications. Iran. Polym. J. 21(8), 531–536 (2012)
T.M. Swamy, B. Ramaraj, Thermal and morphological properties of SA/HPMC blends. J. Appl. Polym. Sci. 112(4), 2235–2240 (2009)
K.S. Reddy, M.N. Prabhakar, P.K. Babu, G. Venkatesulu, U. Rao, K.C. Rao, M.C.S. Subha, Miscibility studies of hydroxypropyl cellulose/poly (ethylene glycol) in dilute solutions and solid state. Int. J. Carbohydr. Chem. (2012). https://doi.org/10.1155/2012/906389
S.H. Lim, S.M. Hudson, Review of chitosan and its derivatives as antimicrobial agents and their uses as textile chemicals. J. Macromol. Sci. Part C Polym. Rev. 43(2), 223–269 (2003)
A. Camposeo, E. Mele, L. Persano, D. Pisignano, R. Cingolani, Role of doping concentration on the competition between amplified spontaneous emission and nonradiative energy transfer in blends of conjugated polymers. Phys. Rev. B 73(16), 165201 (2006)
X. Li, Y. Feng, B. Liu, D. Yi, X. Yang, W.P. ZhangBai, Influence of NbC particles on microstructure and mechanical properties of AlCoCrFeNi high-entropy alloy coatings prepared by laser cladding. J. Alloy. Compd. 788, 485–494 (2019). https://doi.org/10.1016/j.jallcom.2019.02.223
C. Xue, J. You, H. Zhang, S. Xiong, T. Yin, Q. Huang, Capacity of myofibrillar protein to adsorb characteristic fishy-odor compounds: Effects of concentration, temperature, ionic strength, pH and yeast glucan addition. Food chem. 363, 130304 (2021). https://doi.org/10.1016/j.foodchem.2021.130304
X. Li, X. Sheng, Y. Guo, X. Lu, H. Wu, Y. Chen, J. Gu, Multifunctional HDPE/CNTs/PW composite phase change materials with excellent thermal and electrical conductivities. J. Mater. Sci. Technol. 86, 171–179 (2021). https://doi.org/10.1016/j.jmst.2021.02.009
R. Singh, S.G. Kulkarni, Morphological and mechanical properties of poly (vinyl alcohol) doped with inorganic fillers. Int. J. Polym. Mater. Polym. Biomater. 62(6), 351–357 (2013)
K. Hu, F. Wang, Z. Shen, H. Liu, J. Xiong, Ternary heterojunctions synthesis and sensing mechanism of Pd/ZnO–SnO2 hollow nanofibers with enhanced H2 gas sensing properties. J. Alloy. Compd. 850, 156663 (2021). https://doi.org/10.1016/j.jallcom.2020.156663
K. Sreekanth, T. Siddaiah, N.O. Gopal, N.K. Jyothi, K.V. Kumar, C. Ramu, Thermal, structural, optical and electrical conductivity studies of pure and Mn2+ doped PVP films. S. Afr. J. Chem. Eng. 36, 8–16 (2021)
S. Kumar, G.K. Prajapati, A.L. Saroj, P.N. Gupta, Structural, electrical and dielectric studies of nano-composite polymer blend electrolyte films based on (70–x) PVA–x PVP–NaI–SiO2. Physica B Condens. Matter 554, 158–164 (2019)
J.T. Yeh, C.L. Chen, K.S. Huang, Y.H. Nien, J.L. Chen, P.Z. Huang, Synthesis, characterization, and application of PVP/chitosan blended polymers. J. Appl. Polym. Sci. 101(2), 885–891 (2006)
A.A. Menazea, H.A. Ezzat, W. Omara, O.H. Basyouni, S.A. Ibrahim, A.A. Mohamed, M.A. Ibrahim, Chitosan/graphene oxide composite as an effective removal of Ni, Cu, As, Cd and Pb from wastewater. Comput. Theor. Chem. 1189, 112980 (2020)
M.J. Tommalieh, H.A. Ibrahium, N.S. Awwad, A.A. Menazea, Gold nanoparticles doped polyvinyl alcohol/chitosan blend via laser ablation for electrical conductivity enhancement. Journal of Molecular Structure 1221, 128814 (2020)
W. Liu, Y. Qin, P. Li, Design of chitosan sterilization agents by a structure combination strategy and their potential application in crop protection. Molecules 26(11), 3250 (2021)
X. Zhu, F. Lin, Z. Zhang, X. Chen, H. Huang, D. Wang, Z. Wei, Enhancing performance of a GaAs/AlGaAs/GaAs nanowire photodetector based on the two-dimensional electron-hole tube structure. Nano Lett. 20(4), 2654–2659 (2020). https://doi.org/10.1021/acs.nanolett.0c00232
Z. Fan, P. Ji, J. Zhang, D. Segets, D. Chen, S. Chen, Wavelet neural network modeling for the retention efficiency of sub-15 nm nanoparticles in ultrafiltration under small particle to pore diameter ratio. J. Membr. Sci. 635, 119503 (2021). https://doi.org/10.1016/j.memsci.2021.119503
M.K. Ahmed, S.F. Mansour, R. Al-Wafi, A.A. Menazea, Composition and design of nanofibrous scaffolds of Mg/Se-hydroxyapatite/graphene oxide@ ε-polycaprolactone for wound healing applications. J. Market. Res. 9(4), 7472–7485 (2020)
G. Luo, Q. Zhang, M. Li, K. Chen, W. Zhou, Y. Luo, Z. Jiang, A flexible electrostatic nanogenerator and self-powered capacitive sensor based on electrospun polystyrene mats and graphene oxide films. Nanotechnology (2021). https://doi.org/10.1088/1361-6528/ac1019
H. Cheng, T. Li, X. Li, J. Feng, T. Tang, D. Qin, Facile synthesis of Co9S8 nanocages as an electrochemical sensor for luteolin detection. J. Electrochem. Soc. (2021). https://doi.org/10.1149/1945-7111/ac1813
T. Zhang, Z. Wang, H. Xiang, X. Xu, J. Zou, C. Lu, Biocompatible superparamagnetic europium-doped iron oxide nanoparticle clusters as multifunctional nanoprobes for multimodal in vivo imaging. ACS Appl. Mater. Interfaces 13(29), 33850–33861 (2021). https://doi.org/10.1021/acsami.1c07739
M. Sajid, J. Płotka-Wasylka, Nanoparticles: synthesis, characteristics, and applications in analytical and other sciences. Microchem. J. 154, 104623 (2020)
X. Zhang, X. Sun, T. Lv, L. Weng, M. Chi, J. Shi, S. Zhang, Preparation of PI porous fiber membrane for recovering oil-paper insulation structure. J. Mater. Sci. Mater. Electron. 31(16), 13344–13351 (2020). https://doi.org/10.1007/s10854-020-03888-5
P. Makhdoumi, H. Karimi, M. Khazaei, Review on metal-based nanoparticles: role of reactive oxygen species in renal toxicity. Chem. Res. Toxicol. 33(10), 2503–2514 (2020)
X. Xu, M. Nieto-Vesperinas, Azimuthal imaginarypoynting momentum density. Phys. Rev. Lett. 123(23), 233902 (2019). https://doi.org/10.1103/PhysRevLett.123.233902
M. Yang, Q. Kong, W. Feng, W. Yao, Q. Wang, Hierarchical porous nitrogen, oxygen, and phosphorus ternary doped hollow biomass carbon spheres for high-speed and long-life potassium storage. Carbon Energy (2021). https://doi.org/10.1002/cey2.157
F. Behzad, S.M. Naghib, S.N. Tabatabaei, Y. Zare, K.Y. Rhee, An overview of the plant-mediated green synthesis of noble metal nanoparticles for antibacterial applications. J. Ind. Eng. Chem. (2020). https://doi.org/10.1016/j.jiec.2020.12.005
Y. Hu, J.X. Qing, Z.H. Liu, Z.J. Conrad, J.N. Cao, X.P. Zhang, Hovering efficiency optimization of the ducted propeller with weight penalty taken into account. Aerosp. Sci. Technol. (2021). https://doi.org/10.1016/j.ast.2021.106937
X. Zhang, Y. Tang, F. Zhang, C. Lee, A novel aluminum-graphite dual-ion battery. Adv. Energy Mater. 6(11), 1502588 (2016). https://doi.org/10.1002/aenm.201502588
M. Wang, C. Jiang, S. Zhang, X. Song, Y. Tang, H. Cheng, Reversible calcium alloying enables a practical room-temperature rechargeable calcium-ion battery with a high discharge voltage. Nat. Chem. 10(6), 667–672 (2018). https://doi.org/10.1038/s41557-018-0045-4
Y. Yu, Y. Zhao, Y. Qiao, Y. Feng, W. Li, W. Fei, Defect engineering of rutile TiO2 ceramics: route to high voltage stability of colossal permittivity. J. Mater. Sci. Technol. 84, 10–15 (2021). https://doi.org/10.1016/j.jmst.2020.12.046
X. Tong, F. Zhang, B. Ji, M. Sheng, Y. Tang, Carbon-coated porous aluminum foil anode for high-rate, long-term cycling stability, and high energy density dual-ion batteries. Adv. Mater. 28(45), 9979–9985 (2016). https://doi.org/10.1002/adma.201603735
I.D. Ibrahim, T. Jamiru, E.R. Sadiku, Y. Hamam, Y. Alayli, A.A. Eze, Application of nanoparticles and composite materials for energy generation and storage. IET Nanodielectr. 2(4), 115–122 (2019)
A. Aldalbahi, M.E. El-Naggar, M.K. Ahmed, G. Periyasami, M. Rahaman, A.A. Menazea, Core–shell Au@ Se nanoparticles embedded in cellulose acetate/polyvinylidene fluoride scaffold for wound healing. J. Market. Res. 9(6), 15045–15056 (2020)
A.A. Menazea, N.S. Awwad, Antibacterial activity of TiO2 doped ZnO composite synthesized via laser ablation route for antimicrobial application. J. Market. Res. 9(4), 9434–9441 (2020)
S. Barcikowski, G. Compagnini, Advanced nanoparticle generation and excitation by lasers in liquids. Phys. Chem. Chem. Phys. 15(9), 3022–3026 (2013)
M.K. Ahmed, M.E. El-Naggar, A. Aldalbahi, M.H. El-Newehy, A.A. Menazea, Methylene blue degradation under visible light of metallic nanoparticles scattered into graphene oxide using laser ablation technique in aqueous solutions. J. Mol. Liq. 315, 113794 (2020)
H. Yu, X. Rui, H. Tan, J. Chen, X. Huang, C. Xu, W. Liu, D. Yu, H.H. Hung, H.E. Hoster, Q. Yan, Cu doped V 2 O 5 flowers as cathode material for high-performance lithium ion batteries. Nanoscale 5(11), 4937–4943 (2013)
S. Nalini, B. Selvakumar, P. Periasamy, Simple synthesis and characterization of V2O5 nanoparticles by microwave assisted wet chemical method. Int. J. Eng. Manuf. Sci. 7, 411–417 (2017)
J. Livage, Hydrothermal synthesis of nanostructured vanadium oxides. Materials 3(8), 4175–4195 (2010)
A.M. Abdelghany, M.S. Mekhail, E.M. Abdelrazek, M.M. Aboud, Combined DFT/FTIR structural studies of monodispersed PVP/Gold and silver nano particles. J. Alloy. Compd. 646, 326–332 (2015)
M.A.Q. Bhuiyan, M.S. Rahman, M.S. Rahaman, M. Shajahan, N.C. Dafader, Improvement of swelling behaviour of poly (vinyl pyrrolidone) and acrylic acid blend hydrogel prepared by the application of gamma radiation. Org. Chem. Curr. Res. 4(138), 2161–401 (2015)
A. Mohseni-Bandpi, B. Kakavandi, R. Kalantary, A. Azari, A. Keramati, Development of a novel magnetite–chitosan composite for the removal of fluoride from drinking water: adsorption modeling and optimization. RSC Adv. 5(89), 73279–73289 (2015)
K. Choo, Y. Ching, C. Chuah, S. Julai, N. Liou, Preparation and characterization of polyvinyl alcohol-chitosan composite films reinforced with cellulose nanofiber. Materials 9(8), 644 (2016)
A. Patterson, The Scherrer formula for X-ray particle size determination. Phys. Rev. 56(10), 978–982 (1939)
I. Safo, M. Werheid, C. Dosche, M. Oezaslan, The role of polyvinylpyrrolidone (PVP) as a capping and structure-directing agent in the formation of Pt nanocubes. Nanoscale Adv. 1(8), 3095–3106 (2019)
M.T. Elabbasy, M.F.H. Abd El-Kader, A.M. Ismail, A.A. Menazea, Regulating the function of bismuth (III) oxide nanoparticles scattered in Chitosan/Poly (Vinyl Pyrrolidone) by laser ablation on electrical conductivity characterization and antimicrobial activity. J. Mater. Res. Technol. 10, 1348–1354 (2021)
W. El Hotaby, H. Sherif, B. Hemdan, W. Khalil, S. Khalil, Assessment of in situ-prepared polyvinylpyrrolidone-silver nanocomposite for antimicrobial applications. Acta Phys. Pol. A 131(6), 1554–1560 (2017)
R. Bryaskova, D. Pencheva, S. Nikolov, T. Kantardjiev, Synthesis and comparative study on the antimicrobial activity of hybrid materials based on silver nanoparticles (AgNps) stabilized by polyvinylpyrrolidone (PVP). J. Chem. Biol. 4(4), 185–191 (2011)
Y. Gutha, J. Pathak, W. Zhang, Y. Zhang, X. Jiao, Antibacterial and wound healing properties of chitosan/poly(vinyl alcohol)/zinc oxide beads (CS/PVA/ZnO). Int. J. Biol. Macromol. 103, 234–241 (2017)
M. FernandesQueiroz, K. Melo, D. Sabry, G. Sassaki, H. Rocha, Does the use of chitosan contribute to oxalate kidney stone formation? Mar. Drugs 13(1), 141–158 (2014)
A. Kumar, P.P. Sahay, Influence of Ti doping on the microstructural and electrochromic properties of dip-coated nanocrystalline V 2 O 5 thin films. J. Sol-Gel. Sci. Technol. 95(1), 34–51 (2020)
Y. Wu, G. Gao, G. Wu, Self-assembled three-dimensional hierarchical porous V 2 O 5/graphene hybrid aerogels for supercapacitors with high energy density and long cycle life. J. Mater. Chem. A 3(5), 1828–1832 (2015)
R.M. Ahmed, Optical properties and structure of cobalt chloride doped PVA and its blend with PVP. Int. J. Mod. Phys. B 28(05), 1450036 (2014)
S.B. Aziz, O.G. Abdullah, A.M. Hussein, R.T. Abdulwahid, M.A. Rasheed, H.M. Ahmed, A.R. Mohammed, Optical properties of pure and doped PVA: PEO based solid polymer blend electrolytes: two methods for band gap study. J. Mater. Sci. Mater. Electron. 28(10), 7473–7479 (2017)
A.M. Abdelghany, A.A. Menazea, A.M. Ismail, Synthesis, characterization and antimicrobial activity of chitosan/polyvinyl alcohol blend doped with Hibiscus Sabdariffa L. extract. J. Mol. Struct. 1197, 603–609 (2019)
B. Chana, R. Kumar, Synthesis and properties of cupric sulphate doped polyvinyl pyrrolidone (PVP) solutions. J. Macromol. Sci. Part B 56(11–12), 863–872 (2017)
A.A. Menazea, A.M. Ismail, I.S. Elashmawi, The role of Li4Ti5O12 nanoparticles on enhancement the performance of PVDF/PVK blend for lithium-ion batteries. J. Mater. Res. Technol. 9(3), 5689–5698 (2020)
A.A. Menazea, A.M. Abdelghany, N.A. Hakeem, W.H. Osman, F.H. Abd El-kader, Nd: YAG nanosecond laser pulses for precipitation silver nanoparticles in silicate glasses: AC conductivity and dielectric studies. Silicon (2020). https://doi.org/10.1007/s12633-019-0094-3
M. George, S.S. Nair, K.A. Malini, P.A. Joy, M.R. Anantharaman, Finite size effects on the electrical properties of sol–gel synthesized CoFe2O4 powders: deviation from Maxwell-Wagner theory and evidence of surface polarization effects. J. Phys. D Appl. Phys. 40(6), 1593 (2007)
A. Arya, A.L. Sharma, Selection of best composition of Na+ ion conducting PEO-PEI blend solid polymer electrolyte based on structural, electrical, and dielectric spectroscopic analysis. Ionics 26(2), 745–766 (2020)
K.N. Kumar, M. Kang, K. Sivaiah, M. Ravi, Y.C. Ratnakaram, Enhanced electrical properties of polyethylene oxide (PEO) ?polyvinylpyrrolidone (PVP): Li? blended polymer electrolyte films with addition of Ag nanofiller. Ionics 22, 815–825 (2016)
O. Pravakar, T. Siddaiah, P.V.R.K. Ramacharyulu, N.O. Gopal, C. Ramu, H. Nagabhushana, Spectroscopic, thermal, structural and electrical studies on VO2? ions doped PVA/ MAA: EA polymer blend films. J. Sci. Adv. Mater. Dev. 4, 267–275 (2019)
T. Mahapatra, S. Halder, S. Bhuyan, R.N.P. Choudhary, Dielectric and electrical characterization of lead-free complex electronic ceramic: (Bi1/2Li1/2)(Zn1/2W1/2)O3. J. Mater. Sci. Mater. Electr. 29(21), 18742–50 (2014)
Acknowledgements
The authors would like to acknowledge the financial support of Taif University Researchers Supporting Project number (TURSP-2020/162), Taif University, Taif, Saudi Arabia.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Menazea, A.A., Mahmoud, K.H. & Abdel-Rahim, F.M. Tailoring modifications in the structural, optical, and electrical conductivity properties of poly vinyl pyrrolidone/chitosan doped with vanadium pentoxide nanoparticles using laser ablation technique. Appl. Phys. A 127, 826 (2021). https://doi.org/10.1007/s00339-021-04984-x
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-021-04984-x