Abstract
Graphene and P-type indium phosphide (P-InP) could be combined by van der Waals forces to form a Schottky junction, which can be applied in photodetection. This study reported a graphene/P-InP Schottky junction near-infrared photodetector with a 3-nm-thick \({\text{Al}}_{2} {\text{O}}_{3}\) passivation layer and investigated the photoelectric characteristics of such device. As a result, the near-infrared photodetector had a Schottky barrier of 0.89 eV. Besides, this device had a significant response to the wavelength of 808 nm near-infrared light with responsivity and detectivity up to 5.2 mA/W and \(1.3 \times 10^{10} \;{\text{cm Hz}}^{1/2} \;{\text{W}}^{ - 1}\), respectively, under a reverse bias voltage of 0.4 V. It is expected that the Graphene/P-InP Schottky junction near-infrared photodetector with an \({\text{Al}}_{2} {\text{O}}_{3}\) passivation layer may play a vital role in the field of optoelectronic devices in future.
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References
D. Jariwala, T.J. Marks, M.C. Hersam, Mixed-dimensional van der Waals heterostructures. Nat. Mater. 16, 170–181 (2017)
R.R. Nair, P. Blake, A.N. Grigorenko, K.S. Novoselov, T.J. Booth, T. Stauber, N.M.R. Peres, A.K. Geim, Fine structure constant defines visual transparency of graphene. Science 320, 1308 (2008)
K.I. Bolotin, K.J. Sikes, Z. Jiang, M. Klima, G. Fudenberg, J. Hone, P. Kim, H.L. Stormer, Ultrahigh electron mobility in suspended graphene. Solid State Commun. 146, 351–355 (2008)
K.S. Kim, Y. Zhao, H. Jang, S.Y. Lee, J.M. Kim, K.S. Kim, J.H. Ahn, P. Kim, J.Y. Choi, B.H. Hong, Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature 457, 706–710 (2009)
J.W. Jiang, J.S. Wang, B. Li, Young’s modulus of graphene: a molecular dynamics study. Phys. Rev. B. 80, 113405 (2009)
S. Srisonphan, Hybrid graphene−Si-based nanoscale vacuum field effect phototransistors. ACS Photonics 3, 1799–1808 (2016)
D. Periyanagounder, P. Gnanasekar, P. Varadhan, J.H. He, J. Kulandaivel, High performance, self-powered photodetectors based on graphene/silicon Schottky junction diode. J. Mater. Chem. C 6, 9545–9551 (2018)
D. Sinha, J.U. Lee, Ideal graphene/silicon Schottky junction diodes. Nano Lett. 14, 4660–4664 (2014)
W.Y. Kong, G.A. Wu, K.Y. Wang, T.F. Zhang, Y.F. Zou, D.D. Wang, L.B. Luo, Graphene–β-Ca2O3 heterojunction for highly sensitive deep UV photodetector application. Adv. Mater. 28, 10725–10731 (2016)
L.H. Zeng, M.Z. Wang, H. Hu, B. Nie, Y.Q. Yu, C.Y. Wu, L. Wang, J.G. Hu, C. Xie, F.X. Liang, L.B. Luo, Monolayer graphene/germanium schottky junction as high-performance self-driven infrared light photodetector. ACS Appl. Mater. Interfaces. 5, 9362–9366 (2013)
L.B. Luo, J.J. Chen, M.Z. Wang, H. Hu, C.Y. Wu, Q. Li, L. Wang, J.A. Huang, F.X. Liang, Near-infrared light photovoltaic detector based on GaAs nanocone array/monolayer graphene Schottky junction. Adv. Funct. Mater. 24, 2794–2800 (2014)
L.B. Luo, H. Hu, X.H. Wang, R. Lu, Y.F. Zou, Y.Q. Yu, F.X. Liang, A graphene/GaAs near-infrared photodetector enabled by interfacial passivation with fast response and high sensitivity. J. Mater. Chem. C 3, 4723–4728 (2015)
Y. Wu, X. Yan, X. Zhang, X.M. Ren, A monolayer graphene/GaAs nanowire array Schottky junction self-powered photodetector. Appl. Phys. Lett. 109, 183101 (2016)
A. Nematpour, M. Nikoufard, Plasmonic thin film InP/graphene-based Schottky-junction solar cell using nanorods. J. Adv. Res. 10, 15–20 (2018)
C. Xie, Y. Wang, Z.X. Zhang, D. Wang, L.B. Luo, Graphene/semiconductor hybrid heterostructures for optoelectronic device applications. Nano Today 19, 41–83 (2018)
X. Li, H.Y. Zhang, J.J. Yin, L. Liu, J.B. Xu, M. Li, T.C. Ye, M. Gong, Research of breakdown characteristic of InP composite channel HEMT. Acta Phys. Sin. 56, 4117–4121 (2007)
P. Wang, X.Q. Li, Z.J. Xu, Z.Q. Wu, S.J. Zhang, W.L. Xu, H.K. Zhong, H.S. Chen, E.P. Li, J.K. Luo, Q.K. Yu, S.S. Lin, Tunable graphene/indium phosphide heterostructure solar cells. Nano Energy 13, 509–517 (2015)
D.W. Wu, R. Jia, D.Q. Wu, W.C. Ding, W. Chen, C. Chen, H.H. Yue, X.Y. Liu, B.Q. Chen, Al2O3 passivation for crystalline silicon solar cells. Micronanoelectron. Technol. 48, 528–535 (2011)
M.A. Rehman, I. Akhtar, W. Choi, K. Akbar, A. Farooq, S. Hussain, M.A. Shehzad, S.H. Chun, J. Jung, Y. Seo, Influence of an Al2O3 interlayer in a directly grown graphene-silicon Schottky junction solar cell. Carbon 132, 157–164 (2018)
X. Li, W. Cai, J. An, S. Kim, J. Nah, D. Yang, R. Piner, A. Velamakanni, I. Jung, E. Tutuc, S.K. Banerjee, L. Colombo, R.S. Ruoff, Large-area synthesis of high quality and uniform graphene films on copper foils. Science 324, 1312–1314 (2009)
D.Y. Wang, I.S. Huang, P.H. Ho, S.S. Li, Y.C. Yeh, D.W. Wang, W.L. Chen, Y.Y. Lee, Y.M. Chang, C.C. Chen, C.T. Liang, C.W. Chen, Clean-lifting transfer of large-area residual-free graphene films. Adv Mater 25, 4521–4526 (2013)
X. Li, Y. Zhu, W. Cai, M. Borysiak, B. Han, D. Chen, R. Piner, L. Colombo, R.S. Ruoff, Transfer of large-area graphene films for high-performance transparent conductive electrodes. Nano Lett 9, 4359–4363 (2009)
Y.Q. Liu, Graphene: From Basics to Applications, 1st edn. (Chemical Industry Press, Beijing, 2017), p. 19
J.J. Zheng, Y.R. Wang, K.H. Yu, X.X. Xu, X.X. Sheng, E.T. Hu, W. Wei, Field effect transistor photodetector based on graphene and perovskite quantum dots. Acta Phys. Sin. 67, 118502 (2018)
C.R. Crowell, H.B. Shore, E.E. Labate, Surface-state and interface effects in Schottky barriers at n-type silicon surfaces. J. Appl. Phys. 36, 3843–3850 (1965)
Y. An, A. Behnam, E. Pop, A. Ural, Metal-semiconductor-metal photodetectors based on graphene/p-type silicon Schottky junctions. Appl. Phys. Lett. 102, 013110 (2013)
J.H. Wu, Z.W. Yang, C.Y. Qiu, Y.J. Zhang, Z.Q. Wu, J.L. Yang, Y.H. Lu, J.F. Li, D.X. Yang, R. Hao, E.P. Li, G.L. Yu, S.S. Lin, Enhanced performance of a graphene/GaAs self-driven near-infrared photodetector with upconversion nanoparticles. Nanoscale 10, 8023–8030 (2018)
V. Janardhanam, H.K. Lee, K.H. Shim, H.B. Hong, S.H. Lee, K.S. Ahn, C.J. Choi, Temperature dependency and carrier transport mechanisms of Ti/p-type InP Schottky rectifiers. J. Alloy. Compd. 504, 146–150 (2010)
J.X. Zhang, Master's thesis. School of Electronic and Information Engineering, Soochow University, China (2019)
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This project is supported by the National Natural Science Foundation of China (No. 61774108).
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Zhang, T., Chen, J. Graphene/InP Schottky junction near-infrared photodetectors. Appl. Phys. A 126, 832 (2020). https://doi.org/10.1007/s00339-020-04009-z
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DOI: https://doi.org/10.1007/s00339-020-04009-z