Abstract
A series of green emitting persistent phosphors Sr3TaAl3Si2O14:Tb3+ were synthesized via a conventional solid-state reaction method. These phosphors show a green persistent luminescence dominated at ~542 nm at room temperature after irradiated by 254 nm ultraviolet light for minutes. X-ray diffraction, scanning micrograph images, photoluminescence spectra, decay curves, afterglow spectra and thermal luminescence were performed to investigate the physical properties of the persistent phosphors. The influence of Tb3+ concentrations on the photoluminescence and long persistent luminescence properties was studied. The optimal concentration of Tb3+ ions for the best afterglow characteristic was experimentally to be 0.5 mol%. A feasible model was proposed on the basis of experimental results to discuss mechanism of long afterglow in Sr3TaAl3Si2O14:Tb3+ in detail.
Similar content being viewed by others
References
M. Li, X. Yu, T. Wang, J. Qiu, X. Xu, White-blue long persistent luminescence in Ca2Ge7O16:Tb3+ via persistent energy transfer. Ceram. Int. 41, 11523–11527 (2015)
H. Guo, Y. Wang, W. Chen, W. Zeng, S. Han, G. Li, Y. Li, Controlling and revealing the trap distributions of Ca6BaP4O17:Eu2+, R3+ (R = Dy, Tb, Ce, Gd, Nd) by codoping different trivalent lanthanides. J. Mater. Chem. C 3, 11212–11218 (2015)
C. Liu, G. Che, Z. Xu, Q. Wang, Luminescence properties of a Tb3+ activated long-afterglow phosphor. J. Alloy. Compd. 474, 250–253 (2009)
Z. Liu, Y. Liu, Synthesis and luminescent properties of a new green afterglow phosphor CaSnO3:Tb3+. Mater. Chem. Phys. 93, 129–132 (2005)
Y. Li, Y. Li, R. Chen, K. Sharafudeen, S. Zhou, M. Gecevicius, H. Wang, G. Dong, Y. Wu, X. Qin, Tailoring of the trap distribution and crystal field in Cr3+-doped non-gallate phosphors with near-infrared long-persistence phosphorescence. NPG Asia Mater. 7(e180), 1–11 (2015)
J. Hölsä, Persistent luminescence beats the afterglow: 400 years of persistent luminescence. Electrochem. Soc. Interface 18(4), 42–45 (2009)
Q.M. de Chermont, C. Chanéac, J. Seguin, F. Pellé, S. Maîtrejean, J.-P. Jolivet, D. Gourier, M. Bessodes, D. Scherman, Nanoprobes with near-infrared persistent luminescence for in vivo imaging. Proc. Natl. Acad. Sci. 104, 9266–9271 (2007)
Z. Pan, Y.Y. Lu, F. Liu, Sunlight-activated long-persistent luminescence in the near-infrared from Cr3+-doped zinc gallogermanates. Nat. Mater. 11, 58–63 (2012)
W. Chen, J. Zhang, Using nanoparticles to enable simultaneous radiation and photodynamic therapies for cancer treatment. J. Nanosci. Nanotechnol. 6, 1159–1166 (2006)
B.Y. Wu, H.F. Wang, J.-T. Chen, X.-P. Yan, Fluorescence resonance energy transfer inhibition assay for α-fetoprotein excreted during cancer cell growth using functionalized persistent luminescence nanoparticles. J. Am. Chem. Soc. 133, 686–688 (2010)
T. Matsuzawa, Y. Aoki, N. Takeuchi, Y. Murayama, A new long phosphorescent phosphor with high brightness, SrAl2O4:Eu2+, Dy3+. J. Electrochem. Soc. 143, 2670–2673 (1996)
Y. Lin, Z. Tang, Z. Zhang, X. Wang, J. Zhang, Preparation of a new long afterglow blue-emitting Sr2MgSi2O7-based photoluminescent phosphor. J. Mater. Sci. Lett. 20, 1505–1506 (2001)
Z.X. Yuan, C.-K. Chang, D.L. Mao, W. Ying, Effect of composition on the luminescent properties of Sr4Al14O25:Eu2+, Dy3+ phosphors. J. Alloy. Compd. 377, 268–271 (2004)
H. Yamamoto, T. Matsuzawa, Mechanism of long phosphorescence of SrAl2O4:Eu2+, Dy3+ and CaAl2O4:Eu2+, Nd3+. J. Lumin. 72, 287–289 (1997)
J. Kuang, Y. Liu, J. Zhang, L. Huang, J. Rong, D. Yuan, Blue-emitting long-lasting phosphor, Sr3Al10SiO20:Eu2+, Ho3+. Solid State Commun. 136, 6–10 (2005)
R. Zhao, R. Pang, H. Li, Y. Jia, L. Jiang, W. Sun, C. Li, Luminescent properties of blue long-lasting phosphorescence phosphors Sr6Al18Si2O37:Eu2+, Re3+. J. Rare Earths 32, 797–801 (2014)
L.C. Rodrigues, H.F. Brito, J. Holsa, R. Stefani, M.C. Felinto, M. Lastusaari, T. Laamanen, L.A. Nunes, Discovery of the persistent luminescence mechanism of CdSiO3:Tb3+. J. Phys. Chem. C 116, 11232–11240 (2012)
K. Van den Eeckhout, P.F. Smet, D. Poelman, Persistent luminescence in Eu2+-doped compounds: a review. Materials 3, 2536–2566 (2010)
K. Van den Eeckhout, D. Poelman, P.F. Smet, Persistent luminescence in non-Eu2+-doped compounds: a review. Materials 6, 2789–2818 (2013)
J. Trojan-Piegza, E. Zych, J. Hölsä, J. Niittykoski, Spectroscopic properties of persistent luminescence phosphors: Lu2O3:Tb3+, M2+ (M = Ca, Sr, Ba). J. Phys. Chem. C 113, 20493–20498 (2009)
Y. Zheng, et al., in Advances in Design, Growth and Application of Piezoelectric Crystals with Langasite Structure. Symposium on Piezoelectricity, Acoustic Waves and Device Applications (SPAWDA) (IEEE, 2012)
L.L. Noto, M.L. Chitambo, O.M. Ntwaeaborwa, H.C. Swart, Photoluminescence and thermoluminescence properties of Pr3+ doped ZnTa2O6 phosphor. Powder Technol. 247, 147–150 (2013)
E.C. Karsu, E.J. Popovici, A. Ege, M. Morar, E. Indrea, T. Karali, N. Can, Luminescence study of some yttrium tantalate-based phosphors. J. Lumin. 131, 1052–1057 (2011)
T. Peng, L. Huajun, H. Yang, C. Yan, Synthesis of SrAl2O4:Eu, Dy phosphor nanometer powders by sol–gel processes and its optical properties. Mater. Chem. Phys. 85, 68–72 (2004)
M. İlhan, Synthesis, structure and photoluminescence properties of Ho3+ doped TTB–BaTa2O6 phosphors. Solid State Sci. 38, 160–168 (2014)
E.J. Popovici, M. Nazarov, L. Muresan, D.Y. Noh, M. Morar, E. Bica, E. Indrea, Studies on terbium activated yttrium based tantalate phosphors. Radiat. Meas. 45, 300–303 (2010)
A. Wiatrowska, E. Zych, Traps formation and characterization in long-term energy storing Lu2O3:Pr, Hf luminescent ceramics. J. Phys. Chem. C 117, 11449–11458 (2013)
X. Sun, J. Zhang, X. Zhang, Y. Luo, X.-J. Wang, Long lasting yellow phosphorescence and photostimulated luminescence in Sr3SiO5:Eu2+ and Sr3SiO5:Eu2+, Dy3+ phosphors. J. Phys. D Appl. Phys. 41, 195414 (2008)
Y. Liu, B. Lei, C. Shi, Luminescent properties of a white afterglow phosphor CdSiO3:Dy3+. Chem. Mater. 17, 2108–2113 (2005)
J. Trojan-Piegza, J. Niittykoski, J. Hölsä, E. Zych, Thermoluminescence and kinetics of persistent luminescence of vacuum-sintered Tb3+-doped and Tb3+, Ca2+-codoped Lu2O3 materials. Chem. Mater. 20, 2252–2261 (2008)
R. Chen, On the calculation of activation energies and frequency factors from glow curves. J. Appl. Phys. 40, 570–585 (1969)
R. Chen, Glow curves with general order kinetics. J. Electrochem. Soc. 116, 1254–1257 (1969)
T. Wang, W. Bian, D. Zhou, J. Qiu, X. Yu, X. Xu, Red long lasting phosphorescence in Ca2Ge7O16:Sm3+ via persistent energy transfer from the host to Sm3+. Mater. Res. Bull. 74, 151–155 (2016)
S. Zhang, Y. Hu, L. Chen, G. Ju, Z. Wang, J. Lin, Luminescent properties of a green emitting persistent phosphor CdGeO3:Tb3+. Opt. Mater. 47, 203–210 (2015)
Acknowledgments
The authors acknowledge the financial support from the National Natural Science Foundation of China (No. 21471038) and the National High Technology Research and Development Programs of China (2013AA03A101).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Xue, F., Hu, Y., Ju, G. et al. Photoluminescence and long persistent luminescence properties of a novel green emitting phosphor Sr3TaAl3Si2O14:Tb3+ . Appl. Phys. A 122, 612 (2016). https://doi.org/10.1007/s00339-016-0139-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00339-016-0139-z