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Removal of remazol black b, cationic brill red-x and acid erionyl yellow dyes from aqueous solutions using chitosan grafted copolymers

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Abstract

Chitosan graft copolymers were synthesized using a mixture of monomers, itaconic acid (IA)–methacrylamide (MAm) and a mixture of IA–MAm–bentonate in the presence of primer 4,4 Azobis 4-cyanovalric acid and ethylene glycol dimethacrylate. Characterization of both copolymers was accomplished by XRD, FTIR and SEM methods. The copolymers were used for adsorbtion of acid erionyl yellow (AEY), cationic brill red-x (CBR) and remazol black b (RBB). For all dyes, the important adsorption parameters including pH, adsorption time, adsorbent concentration and adsorbent amount were optimized. The results showed that the tendency to absorb CBR and RBB dyes is more than AEY dye. The best adsorption conditions were recorded for CBR (pH = 2.0, time = 60 min, [CBR] = 300 mg/L, adsorbent = 0.03 g, qmax = 538 mg/g). The important and well-known Langmuir isotherm models and the pseudo-second-order model were well consistent in the CBR adsorption study.

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  1. Department of Chemistry and Chemical Engineering, College of Science, Varamin‐Pishva Branch, Islamic Azad University, Varamin, Iran

    Fariborz Azizinezhad

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Azizinezhad, F. Removal of remazol black b, cationic brill red-x and acid erionyl yellow dyes from aqueous solutions using chitosan grafted copolymers. Polym. Bull. 80, 8745–8757 (2023). https://doi.org/10.1007/s00289-022-04480-z

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  • DOI: https://doi.org/10.1007/s00289-022-04480-z

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