Abstract
The polyaniline thin films were prepared by in situ chemical polymerization of aniline on polyethylene terephthalate substrate in the aqueous solutions of citric acid with ammonium peroxydisulfate as oxidant. Using ultraviolet–visible and Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron with energy-dispersive X-ray microscopy, atomic force microscopy, and four-point probe resistivity measurements, pure polyethylene terephthalate and polyaniline thin films were thoroughly characterized. Chemical analysis confirmed the formation of polyaniline with a high degree of oxidation in the form of a smooth thin film (with a thickness of ~ 80 ± 10 nm) on polyethylene terephthalate surface. However, delocalized polyaniline macromolecule aggregates in the spherical shape (with the diameter of ~ 30–40 nm) as well as in the irregular shape (the maximum size of ~ 300 nm) were found on the substrate. The values of average arithmetic roughness, average square roughness, asymmetry, kurtosis, average maximal profile height as well as average maximal height, and depth of roughness were calculated based on the atomic force microscopy data for pure polyethylene terephthalate and polyaniline thin films.
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References
Inzelt G (2017) Recent advances in the field of conducting polymers. J Solid State Electrochem 21(7):1965–1975
Bhadra S, Khastgir D, Singha NK, Lee JH (2009) Progress in preparation, processing and applications of polyaniline. Prog Polym Sci 34(8):783–810
Ćirić-Marjanović G (2013) Recent advances in polyaniline research: Polymerization mechanisms, structural aspects, properties and applications. Synth Met 177:1–47
Stejskal J (2019) Interaction of conducting polymers, polyaniline and polypyrrole, with organic dyes: polymer morphology control, dye adsorption and photocatalytic decomposition. Chem Pap 74:1–54
Malinauskas A (2001) Chemical deposition of conducting polymers. Polymer 42(9):3957–3972
Hnizdiukh YuA, Yatsyshyn MM, Reshetnyak OV (2017) Surface Modification of Polymeric Materials by Polyaniline and Application of Polyaniline/Polymeric Composites. In: Reshetnyak OV, Zaikov GE (eds) Computational and Experimental Analysis of Functional Materials. Apple Academic Press, CRC Press (Taylor & Francis Group), Toronto; New Jersey, pp 423–473
Laranjeiraa JMG, da Silva EF Jr, de Azevedo WM, de Vasconcelos EA, Khoury HJ, Simão RA, Achete CA (2003) AFMstudiesofpolyanilinenanofilmsirradiatedwithgammarays. Microelectron J 34:511–513
Syed JA, Lu H, Tang S, Meng X (2015) Enhanced corrosion protective PANI-PAA/PEI multilayer composite coatings for 316SS by spin coating technique. Appl Surf Sci 325:160–169
Tomsík E, Morávková Z, Stejskal J, Trchová M, Zemek J (2012) In situ polymerized polyaniline films: the top and the bottom. Synth Met 162:2401–2405
Dispenza C, Sabatino MA, Deghiedy N, Casaletto MP, Spadaro G, Piazza S, Abd El-Rehim HA (2015) In-situ polymerization of polyaniline in radiation functionalized polypropylene films. Polymer 67:128–138
Kim J-Y, Lee J-H, Kwon S-J (2007) The manufacture and properties of polyaniline nano-films prepared through vapor-phase polymerization. Synth Met 157(8–9):336–342
Bera A, Deb K, Kathirvel V, Bera T, Thapa R, Saha B (2017) Flexible diode of polyaniline/ITO heterojunction on PET substrate. Appl Surf Sci 418:264–269
Goktas H, Demircioglu Z, Sel K, Gunes T, Kaya I (2013) The optical properties of plasma polymerized polyaniline thin films. Thin Solid Films 548:81–85
Huyen DN, Tung NT, Thien ND, Thanh LH (2011) Effect of TiO2 on the gas sensing features of TiO2/PANi nanocomposites. Sensors 11(2):1924–1931
Sonker RK, Sabhajeet SR, Yadav BC (2016) TiO2–PANI nanocomposite thin film prepared by spin coating technique working as room temperature CO2 gas sensing. J Mater Sci: Mater Electron 27(11):11726–11732
Dhaoui W, Zarrouk H, Pron A (2007) Spectroscopic properties of thin layers of sulfamic acid-doped polyaniline and their application to reagentless determination of nitrite. Synth Met 157(13–15):564–569
Castrellon-Uribe J, Nicho ME, Reyes-Merino G (2009) Remote optical detection of low concentrations of aqueous ammonia employing conductive polymers of polyaniline. Sens Actuat B: Chem 141(1):40–44
Sambasevam KP, Mohamad S, Phang S-W (2015) Effect of dopant concentration on polyaniline for hydrazine detection. Mater Sci Semicon Process 33:24–31
Birajadar RB, Upadhye D, Mahajan S, Vyas JC, Sharma R (2015) Study of room temperature LPG sensing behavior of polyaniline thin film synthesized by cost effective oxidative polymerization technique. J Mater Sci: Mater Electron 26(7):5065–5070
Bandgar DK, Navale ST, Mane AT, Gupta SK, Aswal DK, Patil VB (2015) Ammonia sensing properties of polyaniline/α-Fe2O3 hybrid nanocomposites. Synth Met 204:1–9
Sonker RK, Yadav BC, Sabhajeet SR (2017) Preparation of PANI doped TiO2 nanocomposite thin film and its relevance as room temperature liquefied petroleum gas sensor. J Mater Sci: Mater Electron 28(19):14471–14475
Sonker RK, Yadav BC, Gupta V, Tomar M (2018) Fabrication and characterization of ZnO-TiO2-PANI (ZTP) micro/nanoballs for the detection of flammable and toxic gases. J Hazard Mater 370:126–137
Patil RB, Jatratkar AA, Devan RS, Ma Y-R, Puri RK, Puri V, Yadav JB (2015) Effect of pH on the properties of chemical bath deposited polyanilinethin film. Appl Surf Sci 327:201–204
Jin Z, Su Y, Duan Y (2000) An improved optical pH sensor based on polyaniline. Sens Actuators B 71(1–2):118–122
Sinha V, Patel MR, Patel JV (2008) Pet waste management by chemical recycling: a review. J Polym Environ 18(1):8–25
Yoshida S, Hiraga K, Takehana T, Taniguchi I, Yamaji H, Maeda Y, Toyohara K, Miyamoto K, Kimura Y, Oda K (2016) A bacterium that degrades and assimilates poly(ethylene terephthalate). Science 351(6278):1196–1199
Tabellout M, Fatyeyeva K, Baillif P-Y, Bardeau J-F, Pud AA (2005) The influence of the polymer matrix on the dielectric and electrical properties of conductive polymer composites based on polyaniline. J Non-Cryst Solids 351(33–36):2835–2841
Kelly FM, Meunier L, Cochrane C, Koncar V (2013) Polyaniline: application as solid state electrochromic in a flexible textile display. Displays 34(1):1–7
Duboriz I, Pud A (2014) Polyaniline/poly (ethylene terephthalate) film as a new optical sensing material. Sens Actuators B Chem 190:398–407
Kumar L, Rawal I, Kaur A, Annapoorni S (2017) Flexible room temperature ammonia sensor based on polyaniline. Sens Actuators B Chem 240:408–416
Huang H, Liu W (2006) Polyaniline/poly (ethylene terephthalate) conducting composite fabric with improved fastness to washing. J Appl Polym Sci 102(6):5775–5780
Yu J, Zhou T, Pang Z, Wei Q (2015) Flame retardancy and conductive properties of polyester fabrics coated with polyaniline. Text Res J 86(11):1171–1179
Mu S, Xie H, Wang W, Yu D (2015) Electroless silver plating on PET fabric initiated by in-situ reduction of polyaniline. Appl Surf Sci 353:608–614
Kutanis S, Karakışla M, Akbulut U, Saçak M (2007) The conductive polyaniline/poly(ethylene terephthalate) composite fabrics. Compos Part A-Appl S 38(2):609–614
Çetin E, Karakişla M, Saçak M (2008) The preparation and characterization of conductive poly(ethylene terephthalate)/polyaniline composite fibers using benzoyl peroxide. Fibers Polym 9(3):255–262
Najim TS, Salim AJ (2017) Polyaniline nanofibers and nanocomposites: Preparation, characterization, and application for Cr (VI) and phosphate ions removal from aqueous solution. Arabian J Chem 10:S3459–S3467
Bai S, Ye J, Luo R, Chen A, Li D (2016) Hierarchical polyaniline microspheres loading on flexible PET films for NH3 sensing at room temperature. RSC Adv 6(9):6939–6945
Liu S, Liu D, Pan Z (2018) The effect of polyaniline (PANI) coating via dielectric-barrier discharge (DBD) plasma on conductivity and air drag of polyethylene terephthalate (PET) yarn. Polymers 10(4):351
Bai S, Zhao Y, Sun J, Tian Y, Luo R, Li D, Chen A (2015) Ultrasensitive room temperature NH3 sensor based on graphene-polyaniline hybrid loading on PET thin film. Chem Commun 51:7524–7527
Gavgani JN, Hasani A, Nouri M, Mahyari M, Salehi A (2016) Highly sensitive and flexible ammonia sensor based on S and N co-doped graphene quantum dots/polyaniline hybrid at room temperature. Sens Actuators B Chem 229:239–248
Xue L, Wanga W, Guo Y, Liu G, Wan P (2017) Flexible polyaniline/carbon nanotube nanocomposite film-based electronic gas sensors. Sens Actuators B Chem 244:47–53
Mello JNPD, Mulato M (2015) Optochemical sensors using electrodeposited polyaniline films: electrical bias enhancement of reflectance response. Sens Actuators B Chem 213:195–201
Kim BR, Lee HK, Park SH, Kim HK (2011) Electromagnetic interference shielding characteristics and shielding effectiveness of polyaniline-coated films. Thin Solid Films 519:3492–3496
Stempien Z, Rybicki T, Rybicki E, Kozanecki M, Szynkowska MI (2015) In-situ deposition of polyaniline and polypyrrole electroconductive layers on textile surfaces by the reactive ink-jet printing technique. Synth Met 202:49–62
Nand AV, Ray S, Travas-Sejdic J, Kilmartin PA (2012) Characterization of polyethylene terephthalate/polyaniline blends as potential antioxidant materials. Mater Chem Phys 134:443–450
Yslas EI, Cavallo P, Acevedo DF, Barbero CA, Rivarola VA (2015) Cysteine modified polyaniline films improve biocompatibility for two cell lines. Mater Sci Eng C 51:51–56
Giz MJ, de Albuquerque Maranhão SL, Torresi RM (2000) AFM morphological study of electropolymerised polyaniline films modified by surfactant and large anions. Electrochem Commun 2:377–381
Shishkanova TV, Matějka P, Král V, Sedenková I, Trchová M, Stejskal J (2008) Optimization of the thickness of a conducting polymer, polyaniline, deposited on the surface of poly(vinyl chloride) membranes: a new way to improve their potentiometric response. Anal Chim Acta 624(2):238–246
Garg S, Hurren C, Kaynak A (2007) Improvement of adhesion of conductive polypyrrole coating on wool and polyester fabrics using atmospheric plasma treatment. Synth Met 157:41–47
Shkirskaya S, Kolechko M, Kononenko N (2015) Sensor properties of materials based on fluoride polymer F-4SF films modified by polyaniline. Curr Appl Phys 15(12):1587–1592
Travain SA, de Souza NC, Balogh DT, Giacometti JA (2007) Study of the growth process of in situ polyaniline deposited films. J Colloid Interface Sci 316(2):292–297
Faraj MG, Ibrahim K, Eisa MH (2011) Investigation of the optical and structural properties of thermally evaporated cadmium sulphide thin films on polyethylene terephthalate substrate. Mater Sci Semicond Process 14:146–150
Prasad SG, De A, De U (2011) Structural and optical investigations of radiation damage in transparent PET polymer films. Int J Spectrosc 2011:1–7
Faraj MG, Ibrahim K, Eisa MH (2011) Deposited indium tin oxide (ITO) thin films by dc-magnetron sputtering on polyethylene terephthalate substrate (PET). Roman J Phys 56(5–6):730–741
Wang S, Li Y, Huang Z, Li H (2013) Synthesis and characteristic of polyaniline/Dy2O3 composites: thermal property and electrochemical performance. J Environ Sci 25:S36–S40
Sonker RK, Yadav BC, Dzhardimalieva GI (2016) Preparation and properties of nanostructured PANI thin film and its application as low temperature NO2 sensor. J Inorg Organomet Polym Mater 26(6):1428–1433
Nguyen AS, Nguyen TD, Thai TT, Trinh AT, Pham GV, Thai H, Tran DL, To TXH, Nguyen DT (2020) Synthesis of conducting PANi/SiO2 nanocomposites and their effect on electrical and mechanical properties of antistatic waterborne epoxy coating. J Coat Technol Res 17(2):361–370
Shehzad MA, Qaiser AA, Javaid A, Saeed F (2015) In situ solution-phase polymerization and chemical vapor deposition of polyanilne on microporous cellulose ester membranes: AFM and electrical conductivity studies. Synth Met 200:166–171
Wu W, Pan D, Li Y, Zhao G, Jing L, Chen S (2015) Facile fabrication of polyaniline nanotubes using the self-assembly behavior based on the hydrogen bonding: a mechanistic study and application in high-performance electrochemical supercapacitor electrode. Electrochim Acta 152:126–134
Hou X, Wang Y, Hou J, Sun G, Zhang C (2016) Effect of polyaniline-modified glass fibers on the anticorrosion performance of epoxy coatings. J Coat Technol Res 14(2):407–415
Vijayakumar S, Rajakumar PR (2012) Infrared spectral analysis of waste pet samples. ILCPA 4:58–65
Šeděnková I, Trchová M, Blinova NV, Stejskal J (2006) In-situ polymerized polyaniline films. Preparation in solutions of hydrochloric, sulfuric, or phosphoric acid. Thin Solid Films 515(4):1640–1646
Abdiryim T, Xiao-Gang Z, Jamal R (2005) Comparative studies of solid-state synthesized polyaniline doped with inorganic acids. Mater Chem Phys 90(2–3):367–372
Jia Q, Shan S, Jiang L, Wang Y (2010) One-step synthesis of polyaniline nanofibers decorated with silver. J Appl Polym Sci 115(1):26–31
Sapurina I, Riede A, Stejskal J (2001) In-situ polymerized polyaniline films: 3. Film formation. Synth Met 123(3):503–507
Qi J, Xu X, Liu XX, Lau KTong (2014) Fabrication of textile based conductometric polyaniline gas sensor. Sens Actuators B Chem 202:732–740
Stejskal J, Hlavatá D, Holler P, Trchová M, Prokeś J, Sapurina I (2004) Polyaniline prepared in the presence of various acids: a conductivity study. Polym Int 53:294–300
Peltonen J, Järn M, Areva S, Linden M, Rosenholm JB (2004) Topographical parameters for specifying a three-dimensional surface. Langmuir 20:9428–9431
Dubal DP, Patil SV, Gund GS, Lokhande CD (2013) Polyaniline–polypyrrole nanograined composite via electrostatic adsorption for high performance electrochemical supercapacitors. J Alloys Compd 552:240–247
Li D-F, Wang W, Wang H-J, Jia X-S, Wang J-Y (2008) Polyaniline films with nanostructure used as neural probe coating surfaces. Appl Surf Sci 255:581–584
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The research work was financially supported by the Ministry of Education and Science of Ukraine (project number 0120U102184).
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Stetsiv, Y.A., Yatsyshyn, M.M., Nykypanchuk, D. et al. Characterization of polyaniline thin films prepared on polyethylene terephthalate substrate. Polym. Bull. 78, 6251–6265 (2021). https://doi.org/10.1007/s00289-020-03426-7
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DOI: https://doi.org/10.1007/s00289-020-03426-7