Abstract
In this work, diglycidyl ether of bisphenol A (DGEBA) epoxy resin was cured by isophorone diamine (IPD) hardener in the presence of amine-functionalized silica nanoparticles. Depending upon the aminated silica (AS) contents, two epoxy networks labeled by EP/AS-2.5 and EP/AS-5.0 were obtained. The amine functional groups can allow the nanoparticles to be covalently incorporated into the epoxy matrix. Two controls, including epoxy network loaded by pristine silica (EP/S-2.5) as well as neat epoxy network, were also prepared via a similar protocol. Thus, thermal and mechanical behaviors of the resulting materials were studied as a function of silica surface characteristics, i.e., hydrophilic vs. organo-modified surface, and its loading content. The initial decomposition temperatures (T IDT) and the temperatures of the maximum decomposition rate (T max) were improved. The AS nanoparticles could enhance the storage moduli (E′ values) of the epoxy networks at high-temperature region. Dynamic mechanical analyses also showed that the amine-functionalization of silica can lead to a superior interaction between the nanoparticles and the resulting DGEBA/IPD epoxy networks.
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Auvergne R, Caillol S, David G, Boutevin B, Pascault JP (2014) Biobased thermosetting epoxy: present and future. Chem Rev 114:1082–1115
Tcherbi-Narteh A, Hosur M, Triggs E, Jeelani S (2013) Thermal stability and degradation of diglycidyl ether of bisphenol A epoxy modified with different nanoclays exposed to UV radiation. Polym Degrad Stabil 98:759–770
Mohtadizadeh F, Zohuriaan-Mehr MJ, Shirkavand Hadavand B, Dehghan A (2015) Tetra-functional epoxy-acrylate as crosslinker for UV curable resins: synthesis, spectral, and thermo-mechanical studies. Prog Org Coat 89:231–239
Pethrick RA, Miller C, Rhoney I (2010) Influence of nanosilica particles on the cure and physical properties of an epoxy thermoset resin. Polym Int 59:236–241
Allahverdi A, Ehsani M, Janpour H, Ahmadi S (2012) The effect of nanosilica on mechanical, thermal and morphological properties of epoxy coating. Prog Org Coat 75:543–548
Nikje MMA, Garmarudi AB, Tehrani ZM, Haghshenas M, Shakhesi S (2011) Thermal and mechanical evaluation of epoxy resin composites by synthesis of amine-based coupling agent-nano silica complex. Polym Plast Technol Eng 50:646–650
Azman NZN, Siddiqui SA, Low IM (2013) Synthesis and characterization of epoxy composites filled with Pb, Bi or W compound for shielding of diagnostic X-rays. Appl Phys A Mater 110:137–144
Fraga F, Vazquez EC, Rodriguez-Nunez E, Martinez-Ageitos JM (2008) Curing kinetics of the epoxy system diglycidyl ether of bisphenol A/isophoronediamine by Fourier transform infrared spectroscopy. Polym Adv Technol 19:1623–1628
Bittmann B, Haupert F, Schlarb AK (2011) Preparation of TiO2/epoxy nanocomposites by ultrasonic dispersion and their structure property relationship. Ultrason Sonochem 18:120–126
Srivastava S, Tiwari RK (2012) Synthesis of epoxy-TiO2 nanocomposites: a study on sliding wear behavior, thermal and mechanical properties. Int J Polym Mater 61:999–1010
Mullner M, Lunkenbein T, Schieder M, Groschel AH, Miyajima N, Fortsch M, Breu J, Caruso F, Muller AHE (2012) Template-directed mild synthesis of anatase hybrid nanotubes within cylindrical core–shell–corona polymer brushes. Macromolecules 45:6981–6988
Wan YJ, Tang LC, Gong LX, Yan D, Li YB, Wu LB, Jianga JX, Lai GQ (2014) Grafting of epoxy chains onto graphene oxide for epoxy composites with improved mechanical and thermal properties. Carbon 69:467–480
Kumar MA, Reddy KH, Reddy YVM, Reddy GR, Naidu SV (2010) Improvement of tensile and flexural properties in epoxy/clay nanocomposites reinforced with weave glass fiber reel. Int J Polym Mater 59:854–862
Chen L, Chai S, Liu K, Ning N, Gao J, Liu Q, Chen F, Fu Q (2012) Enhanced epoxy/silica composites mechanical properties by introducing graphene oxide to the interface. ACS Appl Mater Inter 4:4398–4404
Bugnicourt E, Galy J, Gerard JF, Barthel H (2007) Effect of sub-micron silica fillers on the mechanical performances of epoxy-based composites. Polymer 48:1596–1605
Wu CC, Hsu SLC (2010) Preparation of epoxy/silica and epoxy/titania hybrid resists via a sol–gel process for nanoimprint lithography. J Phys Chem C 114:2179–2183
Dittanet P, Pearson RA (2012) Effect of silica nanoparticle size on toughening mechanisms of filled epoxy. Polymer 53:1890–1905
Yu W, Fu J, Dong X, Chen I, Jia H, Shi L (2013) Highly populated and nearly monodispersed nanosilica particles in an organic medium and their epoxy nanocomposites. ACS Appl Mater Inter 5:8897–8906
Jiao J, Liu P, Wang L, Cai Y (2013) One-step synthesis of improved silica/epoxy nanocomposites with inorganic–organic hybrid network. J Polym Res 20:Article 202
Jiang T, Kuila T, Kim NH, Ku BC, Lee JH (2013) Enhanced mechanical properties of silanized silica nanoparticle attached graphene oxide/epoxy composites. Compos Sci Technol 79:115–125
Zhang FH, Wang RG, He XD, Wang C, Ren LN (2009) Interfacial shearing strength and reinforcing mechanisms of an epoxy composite reinforced using a carbon nanotube/carbon fiber hybrid. J Mater Sci 44:3574–3577
Vallo CI, Frontini PM, Williams RJJ (1991) The glass transition temperature of nonstoichiometric epoxy–amine networks. J Polym Sci Pol Phys 29:1503–1511
Eloundou JP, Feve M, Harran D, Pascault JP (1995) Comparative studies of chemical kinetics of an epoxy-amine system. Die Angew Makromol Chem 230:13–46
Abenojar J, Martinez MA, Pantoja M, Velasco F, del Real JC (2012) Epoxy composite reinforced with nano and micro SiC particles: curing kinetics and mechanical properties. J Adhesion 88:418–434
Ahmad Z, Al-Sagheer F (2014) Preparation and characterization of epoxy–silica networks chemically bonded through aminophenyl-trimethoxysilane. J Sol-Gel Sci Technol 72:334–343
Dong Y, Ni QQ, Fu Y (2015) Preparation and characterization of water-borne epoxy shape memory composites containing silica. Compos Part A Appl S 72:1–10
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Behniafar, H., Nazemi, M.K. Effect of amine-functionalized silica nanoparticles on thermal and mechanical behaviors of DGEBA/IPD epoxy networks. Polym. Bull. 74, 3739–3749 (2017). https://doi.org/10.1007/s00289-017-1928-z
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DOI: https://doi.org/10.1007/s00289-017-1928-z