Skip to main content
SpringerLink
Log in

One-step synthesis of hybrid magnetic material based on polyphenoxazine and bimetallic Co–Fe nanoparticles

  • Original Paper
  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Abstract

A simple method for preparation of hybrid magnetic nanocomposites consisting of bimetallic Co–Fe nanoparticles and polyphenoxazine (PPOA) is described. The nanocomposites were prepared by IR heating of precursors based on PPOA, cobalt (II) acetate, and iron (III) chloride in an inert atmosphere at T = 400–600 °C in a short time (2–10 min). Hybrid nanomaterials were characterized by means of X-ray diffraction, Fourier transform infrared spectroscopy, elemental analysis, thermogravimetric analysis, differential scanning calorimetry, transmission and field emission scanning electron microscopy, atomic absorption spectrometry, and vibrating sample magnetometry. Based on the value of hysteresis loop squareness (k S = 0.021–0.034), it was concluded that almost 100% of Co–Fe nanoparticles in the nanocomposite are superparamagnetic.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. Tang BZ, Geng YH, Lam JW, Li BS, Jing XB, Wang XH, Wang FS, Pakhomov AB, Zhang XX (1999) Processible nanostructured materials with electrical conductivity and magnetic susceptibility: preparation and properties of maghemite/polyaniline nanocomposite films. Chem Mater 11:1581–1589

    Article  CAS  Google Scholar 

  2. Wan M, Zhou W, Li J (1996) Composite of polyaniline containing iron oxides with nanometer size. Synth Met 78:27–31

    Article  CAS  Google Scholar 

  3. Wan M, Li W (1997) A composite of polyaniline with both conducting and ferromagnetic functions. J Polym Sci A Polym Chem 35:2129–2136

    Article  CAS  Google Scholar 

  4. Fan J, Wan M, Zhu D (1998) Synthesis and characterization of water-soluble conducting copolymer poly(aniline-co-o-aminobenzenesulfonic acid). J Polym Sci A Polym Chem 36:3013–3019

    Article  CAS  Google Scholar 

  5. Wan M, Fan J (1998) Synthesis and ferromagnetic properties of composites of a water-soluble polyaniline copolymer containing iron oxide. J Polym Sci A Polym Chem 36:2749–2755

    Article  CAS  Google Scholar 

  6. Wan M, Li J (1998) Synthesis and electrical magnetic properties of polyaniline composites. J Polym Sci A Polym Chem 36:2799–2805

    Article  CAS  Google Scholar 

  7. Aphesteguy JC, Jacobo SE (2004) Composite of polyaniline containing iron oxides. Phys B 354:224–227

    Article  Google Scholar 

  8. Yang C, Du J, Peng Q, Qiao R, Chen W, Xu C, Shuai Z, Gao M (2009) Polyaniline/Fe3O4 nanoparticle composite: synthesis and reaction mechanism. J Phys Chem B 113:5052–5058

    Article  CAS  Google Scholar 

  9. Qiu G, Wang Q, Nie M (2006) Polyaniline/Fe3O4 magnetic nanocomposite prepared by ultrasonic irradiation. J Appl Polym Sci 102:2107–2111

    Article  CAS  Google Scholar 

  10. Mallikarjuna NN, Manohar SK, Kulkarni PV, Venkataraman A, Aminabhavi TM (2005) Novel high dielectric constant nanocomposites of polyaniline dispersed with γ-Fe2O3 nanoparticles. J Appl Polym Sci 97:1868–1874

    Article  CAS  Google Scholar 

  11. Li L, Jiang J, Xu F (2006) Novel polyaniline-LiNi0.5La0.02Fe1.98O4 nanocomposites prepared via an in situ polymerization. Eur Polym J 42:2221–2227

    Article  CAS  Google Scholar 

  12. Li L, Jiang J, Xu F (2007) Synthesis and ferrimagnetic properties of novel Sm-substituted LiNi ferrite–polyaniline nanocomposite. Mater Lett 61:1091–1096

    Article  CAS  Google Scholar 

  13. Prasanna GD, Jayanna HS, Prasad V (2011) Preparation, structural, and electrical studies of polyaniline/ZnFe2O4 nanocomposites. J Appl Polym Sci 120:2856–2862

    Article  CAS  Google Scholar 

  14. Bhaumik M, Leswifi TY, Maity A, Shrinivasu VV, Onyango MS (2011) Removal of fluoride from aqueous solution by polypyrrole/Fe3O4 magnetic nanocomposite. J Hazard Mater 186:150–159

    Article  CAS  Google Scholar 

  15. Jokar M, Foroutani R, Safaralizadeh MH, Farhadi K (2014) Synthesis and characterization of polyaniline/Fe3O4 magnetic nanocomposite as practical approach for fluoride removal process. Ann Res Rev Biol 4:3262–3273

    Article  Google Scholar 

  16. Reddy KR, Lee K-P, Iyengar AG (2007) Synthesis and characterization of novel conducting composites of Fe3O4 nanoparticles and sulfonated polyanilines. J Appl Polym Sci 104:4127–4134

    Article  CAS  Google Scholar 

  17. Reddy KR, Lee KP, Gopalan AI (2007) Novel electrically conductive and ferromagnetic composites of poly(aniline-co-aminonaphthalenesulfonic acid) with iron oxide nanoparticles: synthesis and characterization. J App Polym Sci 106:1181–1191

    Article  CAS  Google Scholar 

  18. Jambor JL, Dutrizas JE (1998) Occurrence and constitution of natural and synthetic ferrihydrite, a widespread iron oxyhydroxide. Chem Rev 98:2549–2586

    Article  CAS  Google Scholar 

  19. Umare SS, Ninghthoujam RS, Sharma SJ, Kurian S, Gajbhiye NS (2008) Mössbauer and magnetic studies on nanocrystalline NiFe2O4 particles prepared by ethylene glycol route. Hyperfine Interact 184:235–243

    Article  CAS  Google Scholar 

  20. Umare SS, Shambharkar BH, Ninghthoujam RS (2010) Synthesis and characterization of polyaniline–Fe3O4 nanocomposite: electrical conductivity, magnetic, electrochemical studies. Synth Met 160:1815–1821

    Article  CAS  Google Scholar 

  21. Shambharkar BH, Umare SS (2010) Production and characterization of polyaniline/Co3O4 nanocomposite as a cathode of Zn–polyaniline battery. Mater Sci Eng, B 175:120–128

    Article  CAS  Google Scholar 

  22. Shambharkar BH, Umare SS (2011) Synthesis and characterization of polyaniline/NiO nanocomposite. J Appl Polym Sci 122:1905–1912

    Article  CAS  Google Scholar 

  23. Umare SS, Shambharkar BH (2013) Synthesis, characterization, and corrosion inhibition study of polyaniline-α-Fe2O3 nanocomposite. J Appl Polym Sci 127:3349–3355

    Article  CAS  Google Scholar 

  24. Chen A, Wang H, Zhao B, Wang J, Li X (2004) Preparation and characterization of Fe3O4/polypyrrole(PPy) composites. Acta Mater Compos Sin 21:157–160

    CAS  Google Scholar 

  25. Zhu YF, Zhang L, Nadsuki T, Fu YQ, Ni QQ (2012) Synthesis of hollow poly(aniline-co-pyrrole)–Fe3O4 composite nanospheres and their microwave absorption behavior. Synth Met 162:337–343

    Article  CAS  Google Scholar 

  26. Karpacheva G, Ozkan S (2013) Polymer-metal hybrid structures based on polydiphenylamine and Co nanoparticles. Procedia Mater Sci 2:52–59

    Article  CAS  Google Scholar 

  27. Ozkan S, Dzidziguri EL, Chernavskii PA, Karpacheva GP, Efimov MN, Bondarenko GN (2013) Metal-polymer nanocomposites based on polydiphenylamine and cobalt nanoparticles. Nanotechnol Russ 8:452–460

    Article  Google Scholar 

  28. Ozkan S, Dzidziguri EL, Karpacheva GP, Chernavskii PA, Efimov MN, Bondarenko GN (2015) A magnetic metal-polymer nanocomposite material based on polydiphenylamine and Fe3O4 nanoparticles. Russ Chem Bull 64:196–201

    Article  CAS  Google Scholar 

  29. Karpacheva GP, Ozkan S, Dzidziguri EL, Chernavskii PA, Eremeev IS, Efimov MN, Ivantsov MI, Bondarenko GN (2015) Hybrid metal-polymer nanocomposites based on polyphenoxazine and cobalt nanoparticles. Eur Chem Bull 4:135–141

    CAS  Google Scholar 

  30. Ozkan S, Karpacheva GP, Bondarenko GN (2011) Polymers of phenoxazine: synthesis, structure. Russ Chem Bull 60:1651–1656

    Article  CAS  Google Scholar 

  31. Zemtsov LM, Karpacheva GP, Efimov MN, Muratov DG, Bagdasarova KA (2006) Carbon nanostructures based on IR-pyrolyzed polyacrylonitrile. Polym Sci A 48:633–637

    Article  Google Scholar 

  32. Chernavskii PA, Pankina GV, Lunin VV (2011) Magnetometric methods of investigation of supported catalysts. Russ Chem Rev 80:579–604

    Article  CAS  Google Scholar 

  33. Ozkan S, Dzidziguri EL, Karpacheva GP, Bondarenko GN (2011) Synthesis, structure, and properties of new Cu/polydiphenylamine metallopolymer nanocomposites. Nanotechnol Russ 6:750–756

    Article  CAS  Google Scholar 

  34. Novotortsev VM, Kozlov VV, Korolev Y, Karpacheva GP, Kozhitov LV (2008) Formation of nanoparticles of a new metastable copper compound in the copper acetate hydrate/poly(acrylonitrile) heterogeneous system. Russ J Inorganic Chem 53:1006–1008

    Article  Google Scholar 

  35. Barabash OM, Koval YN (1986) Structure and properties of metals and alloys: handbook. Naukova Dumka, Kiev, p 598

    Google Scholar 

  36. Dzidziguri EL (2009) Dimensional characteristics of nanopowders. Nanotechnol Russ 4:857–870

    Article  Google Scholar 

Download references

Acknowledgements

The authors express their sincere gratitude to G.A. Shandryuk (TIPS RAS) for conducting the thermal analysis of Co–Fe/PPOA nanocomposite and N.N. Dremova (IPChPh RAS) for FE-SEM analysis.

Author information

Authors and Affiliations

  1. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, Moscow, 119991, Russia

    Sveta Zhiraslanovna Ozkan, Galina Petrovna Karpacheva, Galina Nikolaevna Bondarenko & Mikhail Nikolaevich Efimov

  2. National University of Science and Technology MISIS, 4 Leninsky Prospect, Moscow, 119049, Russia

    Ella Leont’evna Dzidziguri

  3. Department of Chemistry, Lomonosov Moscow State University, 1-3 Leninskie Gory, Moscow, 119991, Russia

    Petr Aleksandrovich Chernavskii & Galina Viktorovna Pankina

Authors
  1. Sveta Zhiraslanovna Ozkan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Galina Petrovna Karpacheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ella Leont’evna Dzidziguri
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Petr Aleksandrovich Chernavskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Galina Nikolaevna Bondarenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Mikhail Nikolaevich Efimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Galina Viktorovna Pankina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sveta Zhiraslanovna Ozkan.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ozkan, S.Z., Karpacheva, G.P., Dzidziguri, E.L. et al. One-step synthesis of hybrid magnetic material based on polyphenoxazine and bimetallic Co–Fe nanoparticles. Polym. Bull. 74, 3043–3060 (2017). https://doi.org/10.1007/s00289-016-1878-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00289-016-1878-x

Keywords

Search

Navigation