Abstract
In this work, we compared thermal conductivities of polypropylene fibers and fibrils. The polypropylene fibers were melt spun, and oriented by solid-state drawing. Both wide-angle X-ray scattering and sonic velocity measurements were performed to determine the orientation of fibers. The thermal conductivities of fibers were measured via direct electrical heating method, and that of fibrils were measured via thermal bridge method. Our results show that the thermal conductivity of polypropylene fibers increases linearly with their sonic velocity. This suggests we can use the sonic velocity to characterize the thermal conductivity of semicrystalline polymers. Our results also indicate the average thermal conductivity of fibrils is close to that of fibers. This implies that the low thermal conductivity of polymer fibers is due to the low thermal conductivity of fibrils, instead of thermal resistance between fibrils.
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The data are available from the corresponding author on reasonable request.
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Funding
This work was supported by the Department of Science and Technology of Jiangsu Province (BK20220032), the National Natural Science Foundation of China (52206092, 52127811), Natural Science Foundation of Jiangsu Province (No. BK20210565), and the Fundamental Research Funds for the Central Universities (2242022K40022).
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Investigation: Hao Yin, Chenhan Liu, Bin Wang, Yong Li, Xue Hu, Junyao Yin; Formal analysis: Hao Yin, Chenhan Liu; Visualization: Jinbo Liu; Writing - Original Draft: Hao Yin; Writing - Review & Editing: Chenhan Liu, Gutian Zhao, Juekuan Yang; Conceptualization: Gutian Zhao, Juekuan Yang; Supervision: Juekuan Yang.
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Yin, H., Liu, C., Wang, B. et al. Comparison of thermal conductivities of polypropylene fibers and fibrils. Heat Mass Transfer 60, 677–684 (2024). https://doi.org/10.1007/s00231-024-03463-2
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DOI: https://doi.org/10.1007/s00231-024-03463-2