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Mathematical particle model for microwave drying of leaves

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Abstract

In this work, the model of particles for microwave drying by means of assisted force convection for blueberry leaves is described. A one-dimensional particle model is made in the direction of the thickness of the leaf. Only the phases of water during drying are considered. The mass and energy equation in the particle model develops. The effective diffusivity and the Arrhenius equation for the water phase (liquid and vapor) are considered in the mass equation. The energy equation considers the Lambert-Beer equation. The simulation is performed for different cases of microwave powers (100, 300, 400 W) and temperatures (50, 60 and 70 °C) The activation energy and the pre-exponential factor in the Arrhenius equation are taken from the kinetic analysis prior to this Work The temperature and mass profiles for some experimental and theoretical cases are compared, and it is observed that the model considered gives good results of adjustment between the experimental and the theoretical.

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Acknowledgements

V.H. Borda-Yepes wish to thank the Colombian Administrative Department of Science, Technology and Innovation (COLCIENCIAS, #617) (Departamento Administrativo de Ciencia, Tecnología e Innovacion) for financial support awarded to the program Doctoral in Engineering - Energy System of the National University of Colombia, Sede Medellin, and to the stay of doctoral training at McGill University. F. Chejne wish to thank to the project “Strategy of transformation of the Colombian energy sector in the horizon 2030” funded by the call 788 of Colciencias: Scientific Ecosystem. Contract number FP44842-210-2018.

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Appendices

Annex 1: Analysis mathematical particle model

The balance of the mass equation in a biomass can be represented by the substantial derivative (20):

$$ \frac{Dm}{Dt}=\pm {r}_{\varphi } $$
(20)
$$ \frac{\partial m}{\partial t}+\frac{\partial mv}{\partial x}=\pm {r}_{\varphi } $$
(21)

The mass m of Equation (21) can be expressed in terms of its density ρ and volume V and write the equation (22)

$$ \frac{\partial \rho V}{\partial t}+\frac{\partial \rho V v}{\partial x}=\pm {r}_{\varphi } $$
(22)
$$ \frac{\partial \rho }{\partial t}V+\rho \frac{\partial V}{\partial t}+\frac{\partial \rho }{\partial x} Vv+\rho \frac{\partial V}{\partial x}v+\rho V\frac{\partial v}{\partial x}=\pm {r}_{\varphi } $$
(23)

If we assume that the biomass does not move, that its velocity v = 0 its derivate \( \frac{\partial v}{\partial x}=0 \) of the equation (23) our that expression as:

$$ \frac{\partial \rho }{\partial t}V+\rho \frac{\partial V}{\partial t}=\pm {r}_{\varphi } $$
(24)

the equation V and by including the term as the volumetric reaction By dividing by volume V the equation (24) and by including the therm as the volumentric reaction \( {r_{\varphi}}^{\hbox{'}\hbox{'}\hbox{'}}=\frac{r_{\varphi }}{V} \) it express:

$$ {\displaystyle \begin{array}{l}\frac{\partial \rho }{\partial t}+\frac{1}{V}\rho \frac{\partial V}{\partial t}=\pm {r}_{\varphi}\frac{1}{V}\\ {}\frac{\partial \rho }{\partial t}+\frac{1}{V}\rho \frac{\partial V}{\partial t}=\pm {r_{\varphi}}^{\hbox{'}\hbox{'}\hbox{'}}\end{array}} $$
(25)

The density ρ may be represent in the solid, liquid and gas phases terms with its respectivity porosity ε and volumetric fraction γ as the equation description (5)

$$ {\displaystyle \begin{array}{c}\frac{\partial }{\partial t}\left[{\rho}_{Sol}\left(1-\varepsilon \right)+{\rho}_{Liq}\left(1-\gamma \right)\varepsilon +{\rho}_{Gas}\gamma \varepsilon \right]+\frac{1}{V}\left[{\rho}_{Sol}\left(1-\varepsilon \right)+{\rho}_{Liq}\left(1-\gamma \right)\varepsilon +{\rho}_{Gas}\gamma \varepsilon \right]\frac{\partial V}{\partial t}=\pm {r_{\varphi}}^{\hbox{'}\hbox{'}\hbox{'}}\\ {}\frac{\partial }{\partial t}\left[{\rho}_{Sol}\left(1-\varepsilon \right)+{\rho}_{Liq}\left(1-\gamma \right)\varepsilon +{\rho}_{Gas}\gamma \varepsilon \right]=\pm {r_{\varphi}}^{\hbox{'}\hbox{'}\hbox{'}}-\frac{1}{V}\left[{\rho}_{Sol}\left(1-\varepsilon \right)+{\rho}_{Liq}\left(1-\gamma \right)\varepsilon +{\rho}_{Gas}\gamma \varepsilon \right]\frac{\partial V}{\partial t}\end{array}} $$
(26)

The equation (26) represent the general balance of the mass in the terms of the desnsity ρ, the porosity γ, the volumetric fraction γ and chemical reactions rφ' ' '.

Annex 2: Thermal properties analysis on the leaf

In the thermal properties were measured with KD2Pro device [62]. The conductivity thermal, diffusivity thermal, volume-specify heat capacity, and volumetric heat.

figure a

Time [min]

Power [W]

Temperature [C]

v [m/s]

Area [cm2]

Thin [mm]

L0 [mm]

Deff [m2/s]

kt [W/m K]

Pr

Re

Sc

Nu

Sh

ht W/m^2 K

hm m/s

Bih

Bim

0

100

50

0,5

7,678

0,50

30

2,00E-10

0,445

0,703

812,1

80870

16,8

818,3

249,2

5,46E-06

16,8

818,3

30

100

50

0,5

7,355

0,40

30

2,00E-10

0,445

0,703

812,1

80870

16,8

818,3

249,2

5,46E-06

16,8

818,3

60

100

50

0,5

7,099

0,25

30

2,00E-10

0,445

0,703

812,1

80870

16,8

818,3

249,2

5,46E-06

16,8

818,3

90

100

50

0,5

6,829

0,20

30

2,00E-10

0,445

0,703

812,1

80870

16,8

818,3

249,2

5,46E-06

16,8

818,3

0

300

60

0,5

8,398

0,50

30

2,00E-10

0,670

0,701

770,4

9,24E+04

16,4

833,1

365,6

5,55E-06

16,4

833,1

15

300

60

0,5

8,091

0,35

30

2,00E-10

0,670

0,701

770,4

9,24E+04

16,4

833,1

365,6

5,55E-06

16,4

833,1

30

300

60

0,5

7,680

0,25

30

2,00E-10

0,670

0,701

770,4

9,24E+04

16,4

833,1

365,6

5,55E-06

16,4

833,1

45

300

60

0,5

7,400

0,20

30

2,00E-10

0,670

0,701

770,4

9,24E+04

16,4

833,1

365,6

5,55E-06

16,4

833,1

0

400

70

0,5

8,026

0,50

30

2,00E-10

1,064

0,699

732,8

1,02E+05

15,9

840,8

565,7

5,61E-06

15,9

840,8

5

400

70

0,5

7,890

0,35

30

2,00E-10

1,064

0,699

732,8

9,24E+04

15,9

812,5

565,7

5,42E-06

15,9

812,5

10

400

70

0,5

7,601

0,25

30

2,00E-10

1,064

0,699

732,8

9,24E+04

15,9

812,5

565,7

5,42E-06

15,9

812,5

15

400

70

0,5

7,535

0,20

30

2,00E-10

1,064

0,699

732,8

9,24E+04

15,9

812,5

565,7

5,42E-06

15,9

812,5

Annex 3: Dielectric properties for differents temperatures and 100W powers

figure b

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Borda-Yepes, V.H., Chejne, F., Granados, D.A. et al. Mathematical particle model for microwave drying of leaves. Heat Mass Transfer 55, 2959–2974 (2019). https://doi.org/10.1007/s00231-019-02626-w

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