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The Rosie pyrite hydrothermal system in the McArthur Basin: tectono-sedimentary constraints on mineralization and alkali metasomatism in stratiform sediment-hosted sulfide deposits of northern Australia

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Abstract

The world-class McArthur River Zn-Pb-Ag deposit is the type example of stratiform sediment-hosted deposits found in the Proterozoic basins of northern Australia. However, the McArthur River deposit is enigmatic in that, aside from a few sub-economic deposits within the same camp, other deposits of this type have not been discovered regionally. Understanding the key components of McArthur River-type mineral systems and the regional distribution of these components is crucial to further discovery. The recent discovery of the similar but pyrite-dominated system at Rosie ~ 90 km north of the McArthur River Mine sheds new light on the formation of this deposit class and provides a counterpoint to compare and contrast with the high base metal endowment at McArthur River. Stratiform pyrite mineralization at Rosie is finely laminated and is affected by erosional sedimentary processes superficially indicating it formed during sedimentation to early diagenesis and at or near the sediment–water interface. The conventional ore horizon in the McArthur River camp is the HYC Pyritic Shale Member in the lower Barney Creek Formation (~ 1640 Ma) within sub-basin architecture. Rosie is contained within a similar sub-basin architecture, but it occurs in the upper Barney Creek Formation. The absence of mineralization in the lower Barney Creek Formation at Rosie is attributed in part to prohibitive tectono-sedimentary conditions during early sub-basin development. The HYC Pyritic Shale Member equivalent is relatively thin beneath the Rosie mineralization and is only weakly enriched in hydrothermal elements. Its deposition was abruptly superseded by infill of the sub-basin by a thick barren sequence of fine turbidites. The fine turbidites were a rapid phase of accommodation space fill that diluted brines entering the sediment pile and effectively precluded hydrothermal sulfide mineralization as well as low temperature alkali metasomatism. Permissible tectono-sedimentary conditions did not return until late in sub-basin development, and by this time, sub-basin geometry had broadened and shallowed, and the hydrothermal fluid had evolved. Rosie mineralization is subsequently poorly focused and base metal deficient. The observation that sedimentation rate may play a role in mineralization is a significant addition to the field of basin-hosted mineral systems.

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Fig. 1

adapted from Ahmad et al. (2013); (c) new interpreted solid geology at the Rosie field site; this interpretation uses Betts et al. (2015) linework and is constrained by recent drill core represented by the black dots; (d) BCF lithofacies distribution map of the Rosie field site with mineralization thickness contours in yellow. Red dotted line is the section and red numbers are the drill holes in Figs. 5a–d and 9e–f; (e) schematic cross-sections of the Rosie area interpreted from drill core. The location for the cross-sections is shown in c. Note that Rosie West is not mineralized (cross-section A-A’)

Fig. 2

adapted from Ahmad et al. (2013) and incorporating age constraints reported in Page and Sweet (1998) and Page et al. (2000); (b) a revised stratigraphic scheme for the Rosie area—it incorporates two new LA-ICPMS zircon age dates; (c) conventional stratigraphy of the S.E. McArthur Basin. Note that the S.E. McArthur Basin has a major unconformity between the Tawallah and Nathan Groups, and some sections typical of the Batten Fault Zone are absent in the Rosie section. The mineralization at Rosie is contained within BCF-2 consisting of shale to siltstone with quartz-carbonate and volcaniclastic-rich turbidites. Gp., group; Fm., formation; Mem., member; Dol., dolostone; Sst., sandstone; Ssh., shale; Py., pyritic; UFTU, upper fine-turbidite unit; LSU, lower shale unit; D.C, depositional cycle; undif., undifferentiated

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References

  • Adams JE, Rhodes ML (1960) Dolomitization by seepage refluxion. Am Assoc Pet Geol Bull 44:1912–1920. https://doi.org/10.1306/0BDA6263-16BD-11D7-8645000102C1865D

    Article  Google Scholar 

  • Ahmad M, Dunster JN, Munson TJ (2013) Geology and mineral resources of the Northern Territory. Special Publication, Northern Territory Geological Survey, p 5

    Google Scholar 

  • Andrews TM (2018) Pyrite trace element geochemistry and sedimentology of the Barney Creek Formation, Rosie Creek sub-basin, N.T. Honours Thesis, University of Tasmania

  • Bennett WW, Canfield DE (2020) Redox-sensitive trace metals as paleoredox proxies: a review and analysis of data from modern sediments. Earth Sci Rev 204:103175. https://doi.org/10.1016/j.earscirev.2020.103175

    Article  Google Scholar 

  • Betts PG, Giles D, Mark G, Lister GS, Goleby BR, Aillères L (2006) Synthesis of the proterozoic evolution of the Mt Isa Inlier. Aust J Earth Sci 53:187–211. https://doi.org/10.1080/08120090500434625

    Article  Google Scholar 

  • Betts PG, Armit RJ, Ailleres L (2015) Potential‑field interpretation mapping of the greater McArthur Basin. PGN Geoscience Report 15/2014: in ‘Geophysical and structural interpretation of the greater McArthur Basin’. Northern Territory Geological Survey, Digital Information Package DIP 015.

  • Blaikie TN, Kunzmann M (2020) Geophysical interpretation and tectonic synthesis of the Proterozoic southern McArthur Basin, northern Australia. Precambrian Res 343:105728. https://doi.org/10.1016/j.precamres.2020.105728

    Article  Google Scholar 

  • Bull SW (1998) Sedimentology of the Palaeoproterozoic Barney Creek formation in DDH BMR McArthur 2, southern McArthur Basin, Northern Territory. Aust J Earth Sci 45:21–31. https://doi.org/10.1080/08120099808728364

    Article  Google Scholar 

  • Champion DC, Huston D, Cross A, Jarrett AJM, Bastrakov E, Thorne JP (2020) Geochemistry and age of the greater McArthur Basin: base line geochemical studies and implications for basin-hosted mineral systems.Annual Geoscience Exploration Seminar (AGES) Proceedings, Alice Springs, Northern Territory, 24–25 March 2020. Northern Territory Geological Survey, Darwin.

  • Cooke DR, Bull SW, Large RR, McGoldrick PJ (2000) The importance of oxidized brines for the formation of Australian Proterozoic stratiform sediment-hosted Pb-Zn (sedex) deposits. Econ Geol 95:1–18. https://doi.org/10.2113/gsecongeo.95.1.1

    Article  Google Scholar 

  • Cooke DR, Bull SW, Donovan S, Rogers JR (1998) K-metasomatism and base metal depletion in volcanic rocks from the McArthur Basin, Northern Territory; implications for base metal mineralization Econ Geol 93:1237–1263 doi:https://doi.org/10.2113/gsecongeo.93.8.1237

  • Cooke DR (1997) Iron Transport in Sedimentary Basins - Implications for SEDEX Deposits, Sediment-Hosted Base Metal Deposits, AMIRA/ARC Project 384A Report No. 3: Hobart, University of Tasmania, Centre for Ore Deposit and Exploration Studies.

  • Croxford NJW, Jephcott S (1972) The McArthur lead-zinc-silver deposit, NT. Transactions of the Australasian Institute of Mining and Metallurgy 243:1–27

    Google Scholar 

  • Davidson GJ (1998) Alkali alteration styles and mechanisms, and their implications for a ‘brine factory’ source of base metals in the rift-related McArthur group, Australia. Aust J Earth Sci 45:33–49. https://doi.org/10.1080/08120099808728365

    Article  Google Scholar 

  • Davidson GJ (1999) Feldspar metasomatism along a Proterozoic rift-basin margin—“Smoke” around a base-metal “fire” (HYC deposit, Australia) or a product of background diagenesis? GSA Bull 111:663–673. https://doi.org/10.1130/0016-7606(1999)111

    Article  Google Scholar 

  • Davidson GJ, Dashlooty SA (1993) The Glyde Sub-basin: a volcaniclastic-bearing pull-apart basin coeval with the McArthur River base-metal deposit, Northern Territory. Aust J Earth Sci 40:527–543. https://doi.org/10.1080/08120099308728102

    Article  Google Scholar 

  • Eldridge CS, Williams N, Walshe JL (1993) Sulfur isotope variability in sediment-hosted massive sulfide deposits as determined using the ion microprobe SHRIMP; II, A study of the H.Y.C. Deposit at McArthur River, Northern Territory. Australia Econ Geol 88:1–26. https://doi.org/10.2113/gsecongeo.88.1.1

    Article  Google Scholar 

  • Emsbo P (2009) Geologic criteria for the assessment of sedimentary exhalative (sedex) Zn-Pb-Ag deposits, U.S. Geological Survey Open-File Report 2009–1209:21

  • Garven G, Bull SW, Large RR (2001) Hydrothermal fluid flow models of stratiform ore genesis in the McArthur Basin, Northern Territory, Australia. Geofluids 1:289–311. https://doi.org/10.1046/j.1468-8123.2001.00021.x

    Article  Google Scholar 

  • Giles D, Betts P, Lister G (2002) Far-field continental backarc setting for the 1.80–1.67 Ga basins of northeastern Australia. Geology 30:823–826. https://doi.org/10.1130/0091-7613(2002)030

    Article  Google Scholar 

  • Hinman M (1996) Constraints, timing and processes of stratiform base metal mineralization at the HYC Ag-Pb-Zn deposit, McArthur River (abs.): New developments in metallogenic research: The McArthur. Mount Isa, Cloncurry Minerals Province: James Cook University of North Queensland Economic Geology Research Unit, Extended Abstracts, Contribution 55:56–59

    Google Scholar 

  • Huston D, Stevens B, Southgate P, Muhling P, Wyborn LAI (2006) Australian Zn-Pb-Ag ore-forming systems: a review and analysis. Econ Geol 101:1117–1157. https://doi.org/10.2113/gsecongeo.101.6.1117

    Article  Google Scholar 

  • Ireland T, Bull SW, Large RR (2004a) Mass flow sedimentology within the HYC Zn–Pb–Ag deposit, Northern Territory, Australia: evidence for syn-sedimentary ore genesis. Miner Depos 39:143–158. https://doi.org/10.1007/s00126-003-0382-z

    Article  Google Scholar 

  • Ireland T, Large RR, McGoldrick P, Blake M (2004b) Spatial distribution patterns of sulfur isotopes, nodular carbonate, and ore textures in the McArthur River (HYC) Zn-Pb-Ag deposit, Northern Territory, Australia. Econ Geol 99:1687–1709. https://doi.org/10.2113/gsecongeo.99.8.1687

    Article  Google Scholar 

  • Jackson MJ, Muir MD, Plumb KA (1987) Geology of the southern McArthur Basin, Northern Territory, Bureau of Mineral Resources Bulletin, 220, Bureau of Mineral Resources, Geology and Geophysics.

  • Johnston DT, Poulton SW, Dehler C, Porter S, Husson J, Canfield DE, Knoll AH (2010) An emerging picture of Neoproterozoic ocean chemistry: Insights from the Chuar Group, Grand Canyon, USA. Earth PlanetSci Lett 290:64–73. https://doi.org/10.1016/j.epsl.2009.11.059

    Article  Google Scholar 

  • Lambert IB, Scott KM (1973) Implications of geochemical investigations of sedimentary rocks within and around the McArthur zinc-lead-silver deposit, Northern Territory. J Geochem Explor 2:307–330. https://doi.org/10.1016/0375-6742(73)90016-2

    Article  Google Scholar 

  • Lambert IB (1976) The McArthur zinc-lead-silver deposit: features, metallogenesis and comparisons with some other stratiform ores, in Wolf, K. H., ed., Handbook of stratabound and stratiform ore deposits: Amsterdam, Elsevier, pp 535–585.

  • Large RR, Bull SW, Cooke DR, McGoldrick PJ (1998) A genetic model for the H.Y.C. Deposit, Australia; based on regional sedimentology, geochemistry, and sulfide-sediment relationships. Econ Geol 93:1345–1368. https://doi.org/10.2113/gsecongeo.93.8.1345

    Article  Google Scholar 

  • Large RR, Bull SW, McGoldrick PJ (2000) Lithogeochemical halos and geochemical vectors to stratiform sediment hosted Zn–Pb–Ag deposits: Part 2. HYC deposit, McArthur River. Northern Territory J Geochem Explor 68:105–126. https://doi.org/10.1016/S0375-6742(99)00084-9

    Article  Google Scholar 

  • Leach DL, Marsh E, Emsbo P, Rombach CS, Kelley KD, Anthony M (2004) Nature of hydrothermal fluids at the shale-hosted Red Dog Zn-Pb-Ag deposits, Brooks Range, Alaska. Econ Geol 99:1449–1480. https://doi.org/10.2113/gsecongeo.99.7.1449

    Article  Google Scholar 

  • Logan RG (1979) The geology and mineralogical zoning of the H.Y.C. Ag-Pb-Zn deposit, McArthur River, Northern Territory, Australia. Unpublished MSc thesis, Australian National University, Canberra.

  • Lyons TW, Luepke JJ, Schreiber ME, Zieg GA (2000) Sulfur geochemical constraints on mesoproterozoic restricted marine deposition: lower Belt Supergroup, northwestern United States. Geochim Cosmochim Acta 64:427–437. https://doi.org/10.1016/S0016-7037(99)00323-3

    Article  Google Scholar 

  • Lyons T, Gellatly A, McGoldrick P, Kah L (2006) Proterozoic sedimentary exhalative (SEDEX) deposits and links to evolving global ocean chemistry. Geol Soc Am Mem 198:169–1841198. https://doi.org/10.1130/2006.1198(10)

    Article  Google Scholar 

  • Magnall JM, Gleeson SA, Hayward N, Rocholl A (2020) Massive sulfide Zn deposits in the Proterozoic did not require euxinia. Geochem Perspect Lett 13:19–24. https://doi.org/10.7185/geochemlet.2008

    Article  Google Scholar 

  • Maier RC (2011) Pyrite trace element haloes to Northern Australian SEDEX deposits: unpublished PhD thesis, University of Tasmania:217

  • Manning AH, Emsbo P (2018) Testing the potential role of brine reflux in the formation of sedimentary exhalative (sedex) ore deposits. Ore Geol Rev 102:862–874. https://doi.org/10.1016/j.oregeorev.2018.10.003

    Article  Google Scholar 

  • Martin LA, Wissocq A, Benedetti MF, Latrille C (2018) Thallium (Tl) sorption onto illite and smectite: Implications for Tl mobility in the environment. Geochim Cosmochim Acta 230:1–16. https://doi.org/10.1016/j.gca.2018.03.016

    Article  Google Scholar 

  • McGoldrick P, Keays RR, Scott BB (1979) Thallium: a sensitive indicator of rock/seawater interaction and of sulfur saturation of silicate melts. Geochim Cosmochim Acta 43:1303–1311. https://doi.org/10.1016/0016-7037(79)90120-0

    Article  Google Scholar 

  • McGoldrick P, Winefield P, Bull S, Selley D, Scott R (2010) Sequences, synsedimentary structures, and sub-basins: the where and when of SEDEX zinc systems in the Southern McArthur Basin, Australia, in Goldfarb, R. J., Marsh, E. E., and Monecke, T., eds., The challenge of finding new mineral resources: global metallogeny, innovative exploration, and new discoveries, Society of Economic Geologists

  • McLennan SM, Taylor SR (1991) Sedimentary rocks and crustal evolution: tectonic setting and secular trends. J Geol 99:1–21. https://doi.org/10.1086/629470

    Article  Google Scholar 

  • MMG Exploration Pty Ltd., Sandfire Resources (2018) MMG Sandfire North Batten Joint Venture, Exploration database (unpubl.)

  • Page RW, Jackson MJ, Krassay AA (2000) Constraining sequence stratigraphy in north Australian basins: SHRIMP U-Pb zircon geochronology between Mt Isa and McArthur River. Aust J Earth Sci 47:431–459. https://doi.org/10.1046/j.1440-0952.2000.00797.x

    Article  Google Scholar 

  • Page RW, Sweet IP (1998) Geochronology of basin phases in the western Mt Isa Inlier, and correlation with the McArthur Basin Aust J Earth Sci 45:219–232 doi:https://doi.org/10.1080/08120099808728383

  • Pietsch BA, Rawlings DJ, Creaser P, Kruse PD, Ahmad M, Ferenczi PA, Findhammer TLR (1991) Bauhinia Downs 1:250 000 geological map series explanatory notes in energy, D. o. M. a., ed., 2, Northern Territory Geological Survey

  • Plumb KA, Derrick GM, Wilson IH (1980) Precambrian geology of the McArthur River–Mount Isa region, northern Australia: in Henderson RA and Stephenson PJ (editors) The geology and geophysics of Northeastern Australia. Geological Society of Australia Inc, Queensland Division, Brisbane:71–88

  • Plumb KA, Wellman P (1987) McArthur Basin, Northern Territory: mapping of deep troughs using gravity and magnetic anomalies. BMR J Aust Geol Geophys 10:243–251

    Google Scholar 

  • Polito P, Jackson M (2006) The role of sandstone diagenesis and aquifer evolution in the formation of uranium and zinc-lead deposits, Southern McArthur Basin, Northern Territory, Australia. Econ Geol 101:1189–1209. https://doi.org/10.2113/gsecongeo.101.6.1189

    Article  Google Scholar 

  • Porter TM (2017) McArthur River Zn-Pb-Ag deposit: Australasian Institute of Mining and Metallurgy. Monograph 32:479–482

    Google Scholar 

  • Rawlings DJ, Korsch RJ, Goleby BR, Gibson GM, Johnstone DW, Barlow M (2004) The 2002 Southern McArthur Basin Seismic Reflection Survey, in Australia, G., ed., Record 2004/17. Geoscience Australia Record, Geoscience Australia, p. 78.

  • Rawlings DJ (1999) Stratigraphic resolution of a multiphase intracratonic basin system: The McArthur Basin, northern Australia Aust J Earth Sci 46:703–723 doi:https://doi.org/10.1046/j.1440-0952.1999.00739.x

  • Rawlings DJ (2006) Robinson River 1:250 000 geological map series explanatory notes in energy, D. o. M. a., ed., 2, Northern Territory Geological Survey

  • Shaw DM (1952) The geochemistry of thallium. Geochim Cosmochim Acta 2:118–154. https://doi.org/10.1016/0016-7037(52)90003-3

    Article  Google Scholar 

  • Spinks SC et al. (2020) Carbonate replacement as the principal ore formation process in the Proterozoic McArthur River (HYC) sediment-hosted Zn-Pb deposit, Australia. Econ Geol doi:https://doi.org/10.5382/econgeo.4793

  • Spinks SC et al. (2018) Geochemical and sedimentological characterization of the Proterozoic Blue Billy Formation shale-hosted Zn-Pb mineralization; Edmund basin, Western Australia: Perth, Australia, Commonwealth Scientific and Industrial Research Organisation (CSIRO), Technical Report EP189868, 82 p.

  • Warren J (2000) Dolomite: occurrence, evolution and economically important associations. Earth Sci Rev 52:1–81. https://doi.org/10.1016/S0012-8252(00)00022-2

    Article  Google Scholar 

  • Whitaker FF, Smart PL (1990) Active circulation of saline ground waters in carbonate platforms: evidence from the Great Bahama Bank. Geology 18:200–203. https://doi.org/10.1130/0091-7613(1990)018

    Article  Google Scholar 

  • Williams N (1978) Studies of the base metal sulfide deposits at McArthur River, Northern Territory, Australia; I, The Cooley and Ridge deposits. Econ Geol 73:1005–1035. https://doi.org/10.2113/gsecongeo.73.6.1005

    Article  Google Scholar 

  • Williams N, Rye DM (1974) Alternative interpretation of sulphur isotope ratios in the McArthur lead-zinc-silver deposit. Nature 247:535–537. https://doi.org/10.1038/247535a0

    Article  Google Scholar 

  • Winefield PR (1999) Sedimentology and diagenesis of late palaeoproterozoic carbonates, Southern McArthur Basin, northern Australia. PhD Thesis, University of Tasmania

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Acknowledgements

Thanks are extended to MMG Limited and Sandfire Resources for permission to publish, and to all MMG exploration geologists for stimulating discussions in the field and over the core. Thanks are also extended to several staff at the University of Tasmania, including Doctor Sandrin Feig for assistance operating the SEM, Associate Professor Sebastien Meffre for completing the LA-ICPMS zircon age dates, to Professor Ross Large for reviewing an earlier version of this manuscript, and to Dr Robert Scott for supervising the Honours research. Finally, comprehensive reviews by Dr Sam Spinks and Dr David Champion, and further refinement by Dr Karen Kelley improved the quality of the manuscript significantly.

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Gianfriddo, C., Bull, S.W. & Andrews, T.M. The Rosie pyrite hydrothermal system in the McArthur Basin: tectono-sedimentary constraints on mineralization and alkali metasomatism in stratiform sediment-hosted sulfide deposits of northern Australia. Miner Deposita 57, 377–398 (2022). https://doi.org/10.1007/s00126-021-01069-w

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