Abstract
The present study provides a new concept for improving the properties of phenol-lignin-glyoxal (PLG) resins by lignin nanoparticles, a bio-nanomaterial. In the research work presented, lignin nanoparticles (10, 20, 30 and 40 wt%) were used instead of lignin for the phenol-lignin-glyoxal resin synthesis. The physicochemical and thermal properties of the prepared resins were then determined as well as the water absorption and mechanical properties (flexural modulus, flexural strength and internal bonding) of the particleboard panels bonded with them according to related standards methods. The addition of lignin nanoparticles appeared to change the physicochemical properties of the resins as the gelation time of the PLG resin was shorter and its viscosity increased. FTIR analysis indicated no differences in the chemical structure between the PLG resins with lignin and nanolignin. DSC analysis shows that the addition of lignin nanoparticles allows to decrease the curing temperature of the PLG resin from 170 °C to 159 °C. Based on panel analysis results, higher mechanical strength values and lower water absorption were obtained by progressively increasing the lignin nanoparticles proportion. The work presented here provides a new concept for the preparation of phenolic resins.
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References
ASTM standard D4426–01 (2006) Standard test method for determination of percent nonvolatile content of liquid phenolic resins used for wood laminating. ASTM, West Conshohocken, PA
ASTM D1200-10 (2014) Standard test method for viscosity by ford viscosity cup. ASTM, West Conshohocken, PA
Chen Y, Gong X, Yang G, Li Q, Zhou N (2019) Preparation and characterization of a nanolignin phenol formaldehyde resin by replacing phenol partially with lignin nanoparticles. RSC Adv 9:29255–29262
Feldman D (2016) Lignin nanocomposites. J Mac Sci Part A Pure Appl Chem 53(6):382–387
Hong MK, Park BD (2017) Effect of Urea-Formaldehyde Resin Adhesive Viscosity on Plywood Adhesion. J Korean Wood Sci Technol 45(2):223–231
Kalami S, Chen N, Borazjani H (2018) Comparative analysis of different lignins as phenol replacement in phenolic adhesive formulations. Ind Crops Prod 125:520–528
Khan MA, Ashraf SM, Malhotra VP, Lei H, Du G, Pizzi A, Celzard A, Fang Q, Pizzi A, Allal A, Charrier F, Charrier B (2004) (2009) Cornstarch and tannin in phenol–formaldehyde resins for plywood production. Ind Crop Prod 30(2009) 188–193
Nair S, Sharma S, Pu Y (2014) High Shear homogenization of lignin to Nanolignin and Thermal Stability of nanolignin-polyvinyl alcohol blends. Chem Sus Chem 7(12):3513–3520
Pizzi A, Mittal L (2011) Wood adhesives. CRC Press, New York, p 462
Younesi-Kordkheili H, Pizzi A (2021) Improving properties of phenol- lignin- glyoxal resin as a wood adhesive by an epoxy resin. Eur J Wood Prod 79(1):1–7
Younesi-Kordkheili H, Pizzi A (2020) Some of Physical and Mechanical Properties of Particleboard Panels bonded with phenol- lignin- glyoxal Resin. J Adhes 96(16):1385–1395
Younesi-Kordkheili H (2019) Ionic liquid modified lignin-phenol-glyoxal resin: a green alternative resin for production of particleboards. J Adhes 95(12):1075–1088
Younesi-Kordkheili H, Pizzi A (2018) Properties of plywood panels bonded with ionic liquid-modified lignin–phenol–formaldehyde resin. J Adhes 94(2):143–154
Younesi-Kordkheili H (2017) Improving Physical and Mechanical Properties of New Lignin- Urea- Glyoxal Resin by Nanoclay. Eur J Wood Prod 75(6):885–891
Younesi-Kordkheili H, Pizzi A, Niyatzade G (2016) Reduction of formaldehyde emission from particleboard by phenolated kraft lignin. J Adhes 92(6):485–497
Zhang Z, Terrasson V, Guenin E (2021) Lignin Nanoparticles and their nanocomposites. Nanomat 11(5):1–30
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Younesi-Kordkheili, H., Pizzi, A. Improving the properties of phenol-lignin-glyoxal as a wood adhesive by lignin nanoparticles. Eur. J. Wood Prod. 81, 507–512 (2023). https://doi.org/10.1007/s00107-022-01904-5
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DOI: https://doi.org/10.1007/s00107-022-01904-5