Skip to main content
Log in

Decay and termite resistance of pine blocks impregnated with different additives and subjected to heat treatment

  • Original
  • Published:
European Journal of Wood and Wood Products Aims and scope Submit manuscript

Abstract

Environmental pressures in France and in most European countries during the last decade have considerably changed the practises for wood protection. In this context, legislation and regulations, among which the Biocidal Products Directive (BPD) and Biocidal Products Regulations (BPR), are more and more constraining leading to the development of more environmentally acceptable preservation formulations and to an increasing interest in non-biocidal alternatives like thermal or chemical modifications. Wood heat treatment has been one of the most investigated alternative methods during the last years. However, even if some of the wood properties, like its decay resistance or and dimensional stability, are improved, the overall durability of the material is not sufficient to envisage use class 3 and 4 applications, where the wood is in direct contact with soil and termites. Impregnation of borax associated to polyglycerolmethacrylate (PGMA) before thermal treatment could be an attractive alternative to improve the performance of thermally modified wood in ground contact and especially its resistance to termites taking advantage of thermal treatment to initiate polymerization of PGMA within the wood structure to limit boron mobility. Thermo-modification with or without combination of boron impregnation and PGMA improved the durability of all wood samples. Thermal treatment alone or after boron impregnation and leaching was unable to effectively protect wood blocks against termites after leaching, while bocks treated with boron and PGMA were shown to be fully resistant to termites. More surprisingly, association of thermal treatment and PGMA impregnation without boron impregnation also produced protection against termite attack. Such treatments may be valuable alternatives to extend the scope of utilization of thermally modified wood in outdoor conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Baysal E, Ozaki SK, Yalinkilic MK (2004) Dimensional stabilization of wood treated with furfuryl alcohol catalysed by borates. Wood Sci Technol 38:405–415

    CAS  Google Scholar 

  • Candelier K, Dumarçay S, Pétrissans A, Gérardin P, Pétrissans M (2013) Comparison of mechanical properties of heat treated beech wood cured under nitrogen or vacuum. Polym Degrad Stab 98(9):1762–1765

    Article  CAS  Google Scholar 

  • EN 113 (1986) Wood preservatives—determination of toxic values of wood preservatives against wood destroying basidiomycetes cultured on agar medium. European committee for standardization, NF EN 113

  • EN 117 (1990) Wood preservatives—determination of toxic values against Reticulitermes santonensis de Feytaud (laboratory method). European committee for standardization, NF EN 117

  • EN 335-2 (2007) Durability of wood and wood-based products—definition of use classes—part 2: application to solid wood. European committee for standardization, EN 335-2

  • Esteves BM, Pereira HM (2009) Wood modification by heat treatment—A review. Bioresources 4(1):370–404

    CAS  Google Scholar 

  • European Committee for Standardization (1994) Wood preservatives—methods for measuring losses of active ingredients and other preservative ingredients from treated timber—part 2: laboratory method for obtaining samples for analysis to measure losses by leaching into water or synthetic sea water. ENV 1250-2

  • Gezer ED, Michael JH, Morrell JJ (1999) Effects of glycol on leachability and efficacy of boron wood preservatives. Wood Fiber Sci 31:136–142

    CAS  Google Scholar 

  • Kartal SN (2006) Combined effect of boron compounds and heat treatments on wood properties: boron release and decay and termite resistance. Holzforschung 60(4):455–458

    Article  CAS  Google Scholar 

  • Kartal SN, Green F (2003) Leachability of boron from wood treated with natural and semi-synthetic polymers and calcium precipitating agent. Holz Roh Werkst 61:388–389

    Article  CAS  Google Scholar 

  • Kartal SN, Imamura Y (2004) Effects of N’-N-(1, 8-naphthalyl) hydroxylamine (NHA-Na) and hydroxyl naphthalimide (NHA-H) on boron leachability and biological degradation of wood. Holz Roh Werkst 62:378–385

    Article  CAS  Google Scholar 

  • Kartal SN, Yoshimura T, Imamura Y (2004) Decay and termite resistance of boron-treated and chemically modified wood by in situ co-polymerisation of allyl glycidyl ether (AGE) with methyl methacrylate (MMA). Int Biodeter Biodegr 53:111–117

    Article  CAS  Google Scholar 

  • Kartal SN, Hwang WJ, Imamura Y (2008) Combined effect of boron compounds and heat treatments on wood properties: chemical and strength properties of wood. J Mat Process Tech 198:234–240

    Article  CAS  Google Scholar 

  • Kikuchi S, Maeda S (2007) Effects of fire retardant chemicals and retention on heat release rate of wood. Mokuzai Gakkaishi 53(5):276–282

    Article  CAS  Google Scholar 

  • Korkut S, Mehmet A, Turker D (2008) The effects of heat treatment on some technological properties of Scots pine (Pinus sylvestris L.) wood. Bioresour Technol 99:1861–1868

    Article  PubMed  CAS  Google Scholar 

  • Mburu F, Dumarçay S, Huber F, Pétrissans M, Gérardin P (2007) Evaluation of thermally modified Grevillea robusta heartwood as an alternative to shortage of wood resource in Kenya: characterisation of physicochemical properties and improvement of bio-resistance. Bioresour Technol 98:3478–3486

    Article  PubMed  CAS  Google Scholar 

  • Mburu F, Dumarçay S, Bocquet JF, Pétrissans M, Gérardin P (2008) Effect of chemical modifications caused by heat treatment on mechanical properties of Grevillea robusta wood. Polym Degrad Stab 93:401–405

    Article  CAS  Google Scholar 

  • Militz H (2002) Thermal treatment of wood: European processes and their background, The international research group on wood preservation. IRG/WP 02-40241

  • Mohareb A, Thévenon MF, Wozniak E, Gérardin P (2010) Effects of monoglycerides on leachability and efficacy of boron wood preservatives against decay and termites. Int Biodeter Biodegr 64:135–138

    Article  CAS  Google Scholar 

  • Mohareb A, Thévenon MF, Wozniak E, Gérardin P (2011) Effects of polyvinyl alcohol on leachability and efficacy of boron wood preservatives against fungal decay and termites attack. Wood Sci Technol 45(2):369–382

    Article  Google Scholar 

  • Mourant D, Yang DQ, Lu X, Riedl B, Roy C (2009) Copper and boron fixation in wood by pyrolytic resins. Bioresour Technol 100:1442–1449

    Article  PubMed  CAS  Google Scholar 

  • Obanda DN, Shupe FT, Barnes HM (2008) Reducing leaching of boron based wood preservatives—a review of research. Bioresour Technol 99:7312–7322

    Article  PubMed  CAS  Google Scholar 

  • Obounou Akong F, Pasc A, Mutlu M, Cosgun S, Gérardin P, Gérardin-Charbonnier C (2013) Hydrogels obtained from an original catanionic system for efficient formulation of boron wood-preservatives. Int Biodeter Biodegr 77:123–126

    Article  Google Scholar 

  • Patzelt M, Stingl R, Teischinger A (2002) Thermische Modifikation von Holz und deren Einfluss auf ausgewählte Holzeigenschaften (Thermal modification of wood and ist influence on selected wood properties), In Lignovisionen volume 3, Modifiziertes Holz Eigenschaften und Märkte., ISSN 1681–2808, 101–49 (In German)

  • Raberg U, Daniel G, Terziev N (2012) Loss of strength in biologically degraded thermally modified wood. Bioressources 7(4):4658–4671

    Google Scholar 

  • Salman S, Pétrissans A, Thévenon MF, Dumarçay S, Perrin D, Pollier B, Gérardin P (2014) Development of new wood treatments combining boron impregnation and thermo modification—effect of additives on boron leachability. Eur J Wood Prod 72:355–365

    Article  CAS  Google Scholar 

  • Soulounganga P, Marion C, Huber F, Gérardin P (2003) Synthesis of polyglycerol methacrylate and its application to wood dimensional stabilization. J Appl Polym Sci 88:743–749

    Article  CAS  Google Scholar 

  • Soulounganga P, Loubinoux B, Wozniak E, Lemor A, Gérardin P (2004) Improvement of wood properties by impregnation with polyglycerol methacrylate. Holz Roh Werkst 62:281–285

    Article  CAS  Google Scholar 

  • Surini T, Charrier F, Malvestio J, Charrier B, Moubarik A, Castéra P, Grelier S (2012) Physical properties and termite durability of maritime pine Pinus pinaster Ait heat-treated under vacuum pressure. Wood Sci Technol 46:487–501

    Article  CAS  Google Scholar 

  • Temiz A, Alfredsen G, Eikenes M, Terziev N (2008) Decay resistance of wood treated with boric acid and tall oil derivates. Bioresour Technol 99:2102–2106

    Article  PubMed  CAS  Google Scholar 

  • Thévenon MF, Pizzi A (2003) Polyborate ions influence on the durability of wood treated with non-toxic protein borate preservatives. Holz Roh Werkst 61:457–464

    Article  Google Scholar 

  • Thévenon MF, Pizzi A, Haluk JP (1997) Non-toxic albumin and soja protein borates as ground-contact wood preservatives. Holz Roh Werkst 55:293–296

    Article  Google Scholar 

  • Thévenon MF, Pizzi A, Haluk JP (1998) Protein borates as non-toxic, long-term, wide-spectrum, ground- contact wood preservatives. Holzforschung 52:241–248

    Article  Google Scholar 

  • Tomak ED, Hughes M, Yildiz UC, Viitanen H (2011) The combined effects of boron and oil heat treatment on beech and Scots pine wood properties. Part 1: boron leaching, thermogravimetric analysis and chemical composition. J Mater Sci 46(3):598–607

    Article  CAS  Google Scholar 

  • Toussaint-Dauvergne E, Soulounganga P, Gérardin P, Loubinoux B (2000) Glycerol/glyoxal: a new boron fixation system for wood preservation and dimensional stabilization. Holzforschung 54:123–126

    Article  CAS  Google Scholar 

  • Vernois M (2001) Heat treatment of wood in France—state of art, Proceedings of special seminar review on heat treatment of wood, Antibes, France february 9. BFH the federal research centre for forestry and forest products, Hamburg, 39–46

  • Yildiz S, Gezerb D, Yildiz C (2006) Mechanical and chemical behavior of spruce wood modified by heat. Build Environ 41:1762–1766

    Article  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge the financial support of the CPER 2007-2013 “Structuration du Pôle de Compétitivité Fibres Grand’Est” (Competitiveness Fibers Cluster). LERMAB is supported by a grant overseen by the French National Research Agency (ANR) as part of the “Investissements d’Avenir” program (ANR-11-LABX-0002-01, Lab of Excellence ARBRE).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Philippe Gérardin.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Salman, S., Pétrissans, A., Thévenon, M.F. et al. Decay and termite resistance of pine blocks impregnated with different additives and subjected to heat treatment. Eur. J. Wood Prod. 74, 37–42 (2016). https://doi.org/10.1007/s00107-015-0972-3

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00107-015-0972-3

Keywords

Navigation