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Characterization Techniques Used to Study Various Macro and Nanocomposites of PTT

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Poly Trimethylene Terephthalate

Part of the book series: Materials Horizons: From Nature to Nanomaterials ((MHFNN))

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Abstract

The present chapter is a brief discussion on the characterization techniques most generally employed for the analysis of the renowned engineering polymer, polytrimethylene terephthalate (PTT). Characterization is necessary in order to explain the properties. When it becomes a composite, by the addition of a second phase such as a filler, there is an obvious change in its properties, and it should be thoroughly studied and explained. The different techniques involve thermal, mechanical, morphological, rheological, and crystallization studies. In addition to these methods, permeability and absorption studies are also included.

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References

  1. Xu Y, Jia H-B, Piao J-N, Ye S-R, Huang J (2008) Crystallization behavior of poly(trimethylene terephthalate)/multi-walled carbon nanotube composites. J Mater Sci 43(1):417–421

    Article  CAS  Google Scholar 

  2. Gupta A, Choudhary V (2013) Rheologic and mechanical properties of multiwalled carbon nanotubes-reinforced poly(trimethylene terephthalate) composites. J Mater Sci 48(9):3347–3356

    Article  CAS  Google Scholar 

  3. Martín-Fabiani I, García-Gutiérrez M-C, Rueda DR, Linares A, Hernández JJ, Ezquerra TA et al (2013 Jun) Crystallization under one-dimensional confinement in alumina nanopores of poly(trimethylene terephthalate) and its composites with single wall carbon nanotubes. ACS Appl Mater Interfaces 5(11):5324–5329

    Article  Google Scholar 

  4. Gupta A, Choudhary V (2013) Thermal and mechanical properties of poly(trimethyelene terephthalate)/acid-treated multiwalled carbon nanotube composites. J Mater Sci 48(20):7063–7070

    Article  CAS  Google Scholar 

  5. Li MF, Xiao R, Sun G (2011) Morphology development and size control of poly(trimethylene terephthalate) nanofibers prepared from poly(trimethylene terephthalate)/cellulose acetate butyrate in situ fibrillar composites. J Mater Sci 46(13):4524–4531

    Article  CAS  Google Scholar 

  6. Gemmeke N, Feldmann M, Heim H-P (2019) Processing and characterization of engineering biocomposites based on polybutylenterephthalat (PBT) and polytrimethylentherephthalat (PTT) with regenerated cellulose fibers modified with maleic anhydride grafted polyethylene as a processing agent. Compos Part A Appl Sci Manuf 118:327–335

    Article  CAS  Google Scholar 

  7. Ma Q, Cebe P (2010) Phase structure of electrospun poly(trimethylene terephthalate) composite nanofibers containing carbon nanotubes. J Therm Anal Calorim 102(2):425–434

    Article  CAS  Google Scholar 

  8. Run M, Song H, Yao C, Wang Y (2007 Oct) Crystal morphology and nonisothermal crystallization kinetics of short carbon fiber/poly(trimethylene terephthalate) composites. J Appl Polym Sci 106(2):868–877

    Article  CAS  Google Scholar 

  9. Picard M, Thakur S, Misra M, Mielewski DF, Mohanty AK (2020) Biocarbon from peanut hulls and their green composites with biobased poly(trimethylene terephthalate) (PTT). Sci Rep 10(1):3310

    Article  CAS  Google Scholar 

  10. Kiziltas A, Kiziltas EE, Boran S, Gardner DJ (2016 February) Micro-and nanocellulose composites for automotive applications Micro- and nanocellulose composites for automotive applications. 2013

    Google Scholar 

  11. Ramachandran AA, Mathew LP, Thomas S (2019) Effect of MA-g-PP compatibilizer on morphology and electrical properties of MWCNT based blend nanocomposites: New strategy to enhance the dispersion of MWCNTs in immiscible poly (trimethylene terephthalate)/polypropylene blends. Eur Polym J 118:595–605

    Article  CAS  Google Scholar 

  12. Piccinini P, Senaldi C, Lopes JFA (2013) Fibre labelling polytrimethylene terephthalate―PTT―DuPont

    Google Scholar 

  13. Ferreira Braga N, Morales Zaggo H, Stieven Montagna L, Roberto Passador F. (2020) Effect of carbon nanotubes (CNT) functionalization and maleic anhydride-grafted poly(trimethylene terephthalate) (PTT-g-MA) on the preparation of antistatic packages of PTT/CNT Nanocomposites. Vol. 4, J Compos Sci

    Google Scholar 

  14. Wu C, Liao H. (2013) Characterization and antistatic behavior of SiO 2―functionalized multiwalled carbon nanotube / poly ( trimethylene terephthalate ) composites

    Google Scholar 

  15. Sarathchandran C, Czajka M, Chan CH, Shanks RA, Thomas S (2016) Interfacial interactions of thermally reduced graphene in poly ( trimethylene terephthalate )—epoxy resin based composites. Polymer (Guildf). 106:140–151

    Article  CAS  Google Scholar 

  16. Gupta AK, Mohanty S, Nayak SK. (2015 June) RSC Advances on mechanical, thermal and biodegradation

    Google Scholar 

  17. Wu C. (2009) Synthesis and characterization of poly ( trimethylene terephthalate ) nanocomposites incorporating multi-walled carbon nanotubes

    Google Scholar 

  18. Seyfi J, Jafari S, Ali H, Saha P, Goodarzi V (2010) Thermochimica Acta Investigating the role of transreactions on degradation behavior of phenoxy/poly ( trimethylene terephthalate )/clay nanocomposites using thermal analysis techniques. Thermochim Acta 511(1–2):59–66

    Article  CAS  Google Scholar 

  19. Kim KJ, Ramasundaram S, Lee JS. (2008) Synthesis and characterization of poly (trimethylene terephthalate )/polyhedral oligomeric silsesquixanes nanocomposites

    Google Scholar 

  20. Zaggo HM, Montagna LS, Passador FR (2020) Effect of carbon nanotubes (CNT) functionalization and maleic anhydride-grafted poly(trimethylene terephthalate) (PTT-g-MA) on the preparation of antistatic packages of PTT/CNT nanocomposites

    Google Scholar 

  21. Paszkiewicz S, Szymczyk A, Sui XM, Wagner HD, Linares A, Cirera A, et al. (2017) Electrical conductivity and transparency of polymer hybrid nanocomposites based on poly (trimetylene terephthalate) containing single walled carbon nanotubes and expanded graphite1:1–9

    Google Scholar 

  22. Huang C-L, Wang Y-J, Fan Y-C. (2016 May) Morphological features and crystallization behavior of the conductive composites of poly(trimethylene terephthalate)/graphene nanosheets. J Appl Polym Sci 133(19)

    Google Scholar 

  23. Vivekanandhan S, Misra M, Mohanty AK (2012) Thermal, mechanical , and morphological investigation of injection molded poly(trimethylene terephthalate )/carbon fiber composites

    Google Scholar 

  24. Jog JP (2006) Crystallisation in polymer nanocomposites. 22(7):797–806

    CAS  Google Scholar 

  25. Liu Z, Chen K, Yan D (2003) Crystallization, morphology, and dynamic mechanical properties of poly(trimethylene terephthalate)/clay nanocomposites. 39:2359–66

    Google Scholar 

  26. Poly(trimethylene terephthalate )/silica nanocomposites prepared by dual in situ polymerization: synthesis, morphology, crystallization behavior and mechanical Chenguang Yao a , b and Guisheng Yang a , c ∗. 2010;(November 2009):492–500

    Google Scholar 

  27. Smith L, Vasanthan N. Effect of clay on melt crystallization, crystallization kinetics and spherulitic morphology of poly(trimethylene terephthalate) nanocomposites. Thermochim Acta. 152–62

    Google Scholar 

  28. Xue M, Liu Y, Lv K, Han S, Gao S, Yu G (2020) Prominent crystallization promotion effect of montmorillonite on PTT/PC blends with PTT as the continuous phase. Vol. 12, Polymers

    Google Scholar 

  29. Khan AN, Hong P-D, Chuang W-T, Shih K-S (2010) Crystallization kinetics and structure of poly(trimethylene terepthalate)/monolayer nano-mica nanocomposites. Mater Chem Phys 119(1):93–99

    Article  CAS  Google Scholar 

  30. Ou C-F (2003 Nov) Crystallization behavior and thermal stability of poly(trimethylene terephthalate)/clay nanocomposites. J Polym Sci Part B Polym Phys 41(22):2902–2910

    Article  CAS  Google Scholar 

  31. Favaro MM, Rego BT, Branciforti MC, Bretas RES (2010 Jan) Study of the quiescent and shear-induced crystallization kinetics of intercalated PTT/MMT nanocomposites. J Polym Sci Part B Polym Phys 48(2):113–127

    Article  CAS  Google Scholar 

  32. Hu X, Lesser AJ (2004 Mar) Non-Isothermal Crystallization of Poly(trimethylene terephthalate) (PTT)/Clay Nanocomposites. Macromol Chem Phys 205(5):574–580

    Article  CAS  Google Scholar 

  33. Run M, Yao C, Wang Y, Gao J (2007 Nov) Isothermal crystallization kinetics and melting behaviors of nanocomposites of poly(trimethylene terephthalate) filled with nano-CaCO3. J Appl Polym Sci 106(3):1557–1567

    Article  CAS  Google Scholar 

  34. Wang Y, Liu W, Zhang H (2009) The morphology and non-isothermal crystallization characteristics of poly(trimethylene terephthalate)/BaSO4 nanocomposites prepared by in situ polycondensation. Polym Test 28(4):402–411

    Article  CAS  Google Scholar 

  35. Ramesh V, Mohanty S, Panda BP, Nayak SK (2013 Feb) Nucleation effect of surface treated TiO2 on Poly(trimethylene terephthalate) (PTT) nanocomposites. J Appl Polym Sci 127(3):1909–1920

    Article  CAS  Google Scholar 

  36. Paszkiewicz S, Pawelec I, Szymczyk A (2016 February) Mechanical and thermal properties of hybrid nanocomposites prepared by in situ polymerization

    Google Scholar 

  37. Singaravelu Vivekanandhan, Manjusri Misra AKM (2012) Thermal, mechanical, and morphological investigation of injection molded poly(trimethylene terephthalate)/carbon fiber composites. Polym Polym Compos. 16(2):101–13

    Google Scholar 

  38. Yao C, Xie T, Yang G. (2008) Melting behaviors, isothermal crystallization kinetics , and morphology of poly(trimethylene terephthalate )/stainless steel fiber composites

    Google Scholar 

  39. Liu W, Mohanty AK, Drzal LT, Misra M, Kurian JV, Miller RW et al (2005) Injection molded glass fiber reinforced poly(trimethylene terephthalate) composites: Fabrication and properties evaluation. Ind Eng Chem Res 44(4):857–862

    Article  CAS  Google Scholar 

  40. Paszkiewicz S, Szymczyk A, Livanov K, Wagner HD, Rosłaniec Z (2015) Enhanced thermal and mechanical properties of poly(Trimethylene terephthalate-block-poly(tetramethylene oxide) segmented copolymer based hybrid nanocomposites prepared by in situ polymerization via synergy effect between SWCNTs and graphene nanoplatelets. Express Polym Lett 9(6):509–524

    Article  CAS  Google Scholar 

  41. Gupta A, Choudhary V (2014) Effect of multi-walled carbon nanotubes on mechanical and rheological properties of poly(trimethylene terephthalate). J Mater Sci 49(10):3839–3846

    Article  CAS  Google Scholar 

  42. Paszkiewicz S, Szymczyk A, Janowska I, Jedrzejewski R, Linares A, Ezquerra TA et al (2017) Comparative study on the properties of poly(trimethylene terephthalate) -based nanocomposites containing multi-walled carbon (MWCNT) and tungsten disulfide (INT-WS2) nanotubes. Polym Adv Technol 28(6):645–657

    Article  CAS  Google Scholar 

  43. Li M, Jeong YG (2011) Preparation and characterization of high-performance poly(trimethylene terephthalate) nanocomposites reinforced with exfoliated graphite. Macromol Mater Eng 296(2):159–167

    Article  CAS  Google Scholar 

  44. Paszkiewicz S, Szymczyk A, Sui XM, Wagner HD, Linares A, Cirera A et al (2017) Electrical conductivity and transparency of polymer hybrid nanocomposites based on poly(trimethylene terephthalate) containing single walled carbon nanotubes and expanded graphite. J Appl Polym Sci 134(1):1–9

    Article  Google Scholar 

  45. Szymczyk A, Roslaniec Z, Zenker M, García-Gutiérrez MC, Hernández JJ, Rueda DR et al (2011) Preparation and characterization of nanocomposites based on COOH functionalized multi-walled carbon nanotubes and on poly(trimethylene terephthalate). Express Polym Lett 5(11):977–995

    Article  CAS  Google Scholar 

  46. electrical and barrier properties of graphene PTT.pdf.

    Google Scholar 

  47. Wang J, Wang C, Run M (2013) Study on morphology, rheology, and mechanical properties of poly(trimethylene terephthalate)/CaCO3 nanocomposites. Int J Polym Sci

    Google Scholar 

  48. Jacob S, Misra M, Mohanty AK (2012) Novel biocomposites from poly(trimethylene terephthalate) and recycled carbon fibres. J Mater Sci 47(16):6056–6065

    Article  CAS  Google Scholar 

  49. Liu Z, Chen K, Yan D (2004) Nanocomposites of poly(trimethylene terephthalate) with various organoclays: Morphology, mechanical and thermal properties. Polym Test 23(3):323–331

    Article  CAS  Google Scholar 

  50. Chen G-X, Shimizu H (2008 Feb) Multiwalled carbon nanotubes grafted with polyhedral oligomeric silsesquioxane and its dispersion in poly(l-lactide) matrix. Polymer (Guildf) 49(4):943–951

    Article  CAS  Google Scholar 

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Correspondence to Arunima Reghunadhan .

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Sari, P.S., Reghunadhan, A. (2023). Characterization Techniques Used to Study Various Macro and Nanocomposites of PTT. In: Ajitha, A.R., Thomas, S. (eds) Poly Trimethylene Terephthalate. Materials Horizons: From Nature to Nanomaterials. Springer, Singapore. https://doi.org/10.1007/978-981-19-7303-1_6

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