Skip to main content

A Comparison Study on Thermal Degradation of Two Different Poly (Lactic Acid)/Metal Oxide Hybrids

  • Conference paper
  • First Online:
Advances in Graphic Communication, Printing and Packaging

Part of the book series: Lecture Notes in Electrical Engineering ((LNEE,volume 543))

  • 1304 Accesses

Abstract

A comparison investigation was made on thermal decomposition behaviors of poly (lactic acid) (PLA) hybrids with two different metal oxides of TiO2 and ZnO by means of thermogravimetric analysis. Experimental measurements were conducted with a scanning rate of 5–20 K/min in nitrogen. Abstracted from non-isothermal decomposition data, thermal degradation temperatures of PLA/metal oxide hybrids were obtained and compared so as to investigate the effects of two metal oxides. The activation energy Ea for PLA thermal decomposition was calculated by using the Kissinger method and the results implied that the metal oxide added had greatly changed the PLA thermal stability and the service lifespan was predicted based on the Ea values.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Koshy, R. R., Mary, S. K., Thomas, S., et al. (2015). Environment friendly green composites based on soy protein isolate—A review. Food Hydrocolloids, 50, 174–192.

    Article  Google Scholar 

  2. Reakasame, S., & Boccaccini, A. R. (2018). Oxidized alginate-based hydrogels for tissue engineering applications: A review. Biomacromolecules, 19, 3–21.

    Article  Google Scholar 

  3. Li, H. J., Hu, C., Yu, H. J., et al. (2018). Chitosan composite scaffolds for articular cartilage defect repair: A review. RSC Advances, 8, 3736–3749.

    Article  Google Scholar 

  4. Sangeetha, V. H., Deka, H., Varghese, T. O., et al. (2018). State of the art and future prospectives of poly(lactic acid) based blends and composites. Polymer Composites, 39, 81–101.

    Article  Google Scholar 

  5. Koh, J. J., Zhang, X. W., & He, C. B. (2018). Fully biodegradable poly(lactic acid)/Starch blends: A review of toughening strategies. International Journal of Biological Macromolecules, 109, 99–113.

    Article  Google Scholar 

  6. Huang, Z., Ye, Q. Q., & Teng, L. J. (2015). A comparison study on thermal decomposition behavior of poly (L-lactide) with different kinetic methods. Journal of Thermal Analysis and Calorimetry, 119, 2015–2027.

    Article  Google Scholar 

  7. Ye, Q. Q., Huang, Z., Hao, Y. H., et al. (2016). Kinetic study of thermal degradation of poly (L-lactide) filled with β-zeolite. Journal of Thermal Analysis and Calorimetry, 124, 1471–1484.

    Article  Google Scholar 

  8. Hao, Y. H., Huang, Z., Wang, J. W., et al. (2016). Improved thermal stability of poly (L-lactide) with the incorporation of zeolite ZSM-5. Polymer Testing, 49, 46–56.

    Article  Google Scholar 

  9. Das, P., & Tiwari, P. (2017). Thermal degradation kinetics of plastics and model selection. Thermochimica Acta, 654, 191–202.

    Article  Google Scholar 

  10. Laachachi, A., Ferriol, M., Cochez, M., et al. (2008). The catalytic role of oxide in the thermooxidative degradation of poly(methyl methacrylate)–TiO2 nanocomposites. Polymer Degradation and Stability, 93, 1131–1137.

    Article  Google Scholar 

  11. Japic, D., Marinsek, M., & Orel, Z. C. (2016). Effect of ZnO on the thermal degradation behavior of poly(methyl methacrylate) nanocomposites. Acta Chimica Slovenica, 63, 535–543.

    Article  Google Scholar 

  12. Vyazovkin, S., Burnham, A. K., Criado, J. M., et al. (2011). ICTAC kinetics committee recommendations for performing kinetic computations on thermal analysis data. Thermochimca Acta, 520, 1–19.

    Article  Google Scholar 

  13. Kissinger, H. E. (1967). Variation of peak temperature with heating rate in differential thermal analysis. Journal of Research of the National Bureau of Standards, 57, 217–221.

    Article  Google Scholar 

  14. Georgieva, V., Zvezdova, D., & Vlaev, L. (2012). Non-isothermal kinetics of thermal degradation of chitosan. Chemistry Central Journal, 6, 81–91.

    Article  Google Scholar 

Download references

Acknowledgements

The authors would like to thank National Students’ Innovation and Entrepreneurship Training Program (No. 201710069009) for funding this project.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zhen Huang .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Singapore Pte Ltd.

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Wang, X., Huang, Z. (2019). A Comparison Study on Thermal Degradation of Two Different Poly (Lactic Acid)/Metal Oxide Hybrids. In: Zhao, P., Ouyang, Y., Xu, M., Yang, L., Ren, Y. (eds) Advances in Graphic Communication, Printing and Packaging. Lecture Notes in Electrical Engineering, vol 543. Springer, Singapore. https://doi.org/10.1007/978-981-13-3663-8_120

Download citation

  • DOI: https://doi.org/10.1007/978-981-13-3663-8_120

  • Published:

  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-13-3662-1

  • Online ISBN: 978-981-13-3663-8

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics