Abstract
A comparison investigation was made on thermal decomposition behaviors of poly (lactic acid) (PLA) hybrids with two different metal oxides of TiO2 and ZnO by means of thermogravimetric analysis. Experimental measurements were conducted with a scanning rate of 5–20 K/min in nitrogen. Abstracted from non-isothermal decomposition data, thermal degradation temperatures of PLA/metal oxide hybrids were obtained and compared so as to investigate the effects of two metal oxides. The activation energy Ea for PLA thermal decomposition was calculated by using the Kissinger method and the results implied that the metal oxide added had greatly changed the PLA thermal stability and the service lifespan was predicted based on the Ea values.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Koshy, R. R., Mary, S. K., Thomas, S., et al. (2015). Environment friendly green composites based on soy protein isolate—A review. Food Hydrocolloids, 50, 174–192.
Reakasame, S., & Boccaccini, A. R. (2018). Oxidized alginate-based hydrogels for tissue engineering applications: A review. Biomacromolecules, 19, 3–21.
Li, H. J., Hu, C., Yu, H. J., et al. (2018). Chitosan composite scaffolds for articular cartilage defect repair: A review. RSC Advances, 8, 3736–3749.
Sangeetha, V. H., Deka, H., Varghese, T. O., et al. (2018). State of the art and future prospectives of poly(lactic acid) based blends and composites. Polymer Composites, 39, 81–101.
Koh, J. J., Zhang, X. W., & He, C. B. (2018). Fully biodegradable poly(lactic acid)/Starch blends: A review of toughening strategies. International Journal of Biological Macromolecules, 109, 99–113.
Huang, Z., Ye, Q. Q., & Teng, L. J. (2015). A comparison study on thermal decomposition behavior of poly (L-lactide) with different kinetic methods. Journal of Thermal Analysis and Calorimetry, 119, 2015–2027.
Ye, Q. Q., Huang, Z., Hao, Y. H., et al. (2016). Kinetic study of thermal degradation of poly (L-lactide) filled with β-zeolite. Journal of Thermal Analysis and Calorimetry, 124, 1471–1484.
Hao, Y. H., Huang, Z., Wang, J. W., et al. (2016). Improved thermal stability of poly (L-lactide) with the incorporation of zeolite ZSM-5. Polymer Testing, 49, 46–56.
Das, P., & Tiwari, P. (2017). Thermal degradation kinetics of plastics and model selection. Thermochimica Acta, 654, 191–202.
Laachachi, A., Ferriol, M., Cochez, M., et al. (2008). The catalytic role of oxide in the thermooxidative degradation of poly(methyl methacrylate)–TiO2 nanocomposites. Polymer Degradation and Stability, 93, 1131–1137.
Japic, D., Marinsek, M., & Orel, Z. C. (2016). Effect of ZnO on the thermal degradation behavior of poly(methyl methacrylate) nanocomposites. Acta Chimica Slovenica, 63, 535–543.
Vyazovkin, S., Burnham, A. K., Criado, J. M., et al. (2011). ICTAC kinetics committee recommendations for performing kinetic computations on thermal analysis data. Thermochimca Acta, 520, 1–19.
Kissinger, H. E. (1967). Variation of peak temperature with heating rate in differential thermal analysis. Journal of Research of the National Bureau of Standards, 57, 217–221.
Georgieva, V., Zvezdova, D., & Vlaev, L. (2012). Non-isothermal kinetics of thermal degradation of chitosan. Chemistry Central Journal, 6, 81–91.
Acknowledgements
The authors would like to thank National Students’ Innovation and Entrepreneurship Training Program (No. 201710069009) for funding this project.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Wang, X., Huang, Z. (2019). A Comparison Study on Thermal Degradation of Two Different Poly (Lactic Acid)/Metal Oxide Hybrids. In: Zhao, P., Ouyang, Y., Xu, M., Yang, L., Ren, Y. (eds) Advances in Graphic Communication, Printing and Packaging. Lecture Notes in Electrical Engineering, vol 543. Springer, Singapore. https://doi.org/10.1007/978-981-13-3663-8_120
Download citation
DOI: https://doi.org/10.1007/978-981-13-3663-8_120
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-13-3662-1
Online ISBN: 978-981-13-3663-8
eBook Packages: EngineeringEngineering (R0)