Abstract
The decreasing fossil fuel reserves, rise in oil prices, and increasing awareness of environmental impact of continued fossil fuel use have made the quest for alternative energy sources significant throughout the world. In this regard, conversion of various types of wastes to biofuels and biomaterials offers a new paradigm of research in the changing world faced with these diverse problems. Lignocellulosic biomasses are the most predominant among different types of waste resources and are characterized by diverse nature and abundant supply. However, it also has numerous competitive uses which shrink the biomass resource base for energy production. There are numerous biomass materials which are produced as by-products, residues, or wastes from other processes, operations, or industries. The energy content of these materials can be usefully exploited and have the advantage of removing these materials from the landfill. This chapter presents an overview of the pyrolytic conversion of low-value biomass/bio-wastes, agricultural residues, bioenergy by-product, industrial agro-wastes, aquatic wastes, MSW, plastic solid wastes to bio-oil and biochar and their wide-ranging applications. Further, this chapter also reviews the pyrolysis technology and its economic analysis.
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References
Abnisa F, Wan Daud WMA (2014) A review on co-pyrolysis of biomass: an optional technique to obtain high-grade pyrolysis oil. Energ Convers Manage 87:71–85
Agarwal AK (2007) Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines. Prog Energy Combust Sci 33:233–271
Al-Salem SM, Antelava A, Constantinou A, Manos G, Dutta A (2017) A review on thermal and catalytic pyrolysis of plastic solid waste (PSW). J Environ Manage 197:177–198
Altafini CR, Wander PR, Barreto RM (2003) Prediction of the working parameters of a wood waste gasifier through an equilibrium model. Energy Convers Manage 44:2763–2777
Balat M (2008) Mechanisms of thermochemical biomass conversion processes. Part 1: Reactions of pyrolysis. Energy Sources Part A 30(7):620–635
Balat M, Balat M, Kirtay E, Balat H (2009) Main routes for the thermo-conversion of biomass into fuels and chemicals. Part 1: Pyrolysis systems. Energy Convers Manage 50:3147–3157
Bélanger NI, Côté B, Fyles JW, Chourchesne F, Hendershot WH (2004) Forest regrowth as the controlling factor of soil nutrient availability 75 years after fire in a deciduous forest of southern Quebec’. Plant Soil 262:363–372
Bentsen NS, Felby C, Thorsen BJ (2014) Agricultural residue production and potentials for energy and materials services. Prog Energy Combust Sci 40:59–73
Bordoloi N, Narzari R, Chutia RS, Bhaskar T, Kataki R (2015) Pyrolysis of Mesua ferrea and Pongamia glabra seed cover: characterization of bio-oil and its sub-fractions. Bioresour Technol 178:83–89
Bordoloi N, Goswami R, Kumar M, Kataki R (2017) Biosorption of Co (II) from aqueous solution using algal biochar: kinetics and isotherm studies. Bioresour Technol. https://doi.org/10.1016/j.biortech.2017.05.139
Boukis I, Gyftopoulou ME, Papamichael I (2001) Biomass fast pyrolysis in an air blown circulating fluidized bed reactor. In: Bridgwater AV (ed) Progress in thermochemical biomass conversion. Blackwell Science Ltd, Oxford, UK, pp 1259–1267. https://doi.org/10.1002/9780470694954.ch104
Brandt A, Grasvik J, Hallett JP, Welton T (2013) Deconstruction of lignocellulosic biomass with ionic liquids. Green Chem 15(3):550–583
Bridgwater AV, Peacocke GVC (2000) Fast pyrolysis processes for biomass. Renew Sustain Energy Rev 4(1):1–73
Bridgwater AV, Czernik S, Piskorz J (2001) An overview of fast pyrolysis. In: Bridgwater AV (ed) Progress in thermochemical biomass conversion, vol 2. Blackwell Science, London, pp 977–997
Chen D, Yin L, Wang H, He P (2014) Pyrolysis technologies for municipal solid waste: a review. Waste Manage 34(12):2466–2486
Chiaramonti D, Bonini M, Fratini E, Tondi G, Gartner K, Bridgwater AV, Grimm HP, Soldaini I, Webster A, Baglioni P (2003) Development of emulsions from biomass pyrolysis liquid and diesel and their use in engines. Biomass Bioenergy 25:101–111
Chiaramonti D, Oasmaa A, Solantausta Y (2007) Power generation using fast pyrolysis liquids from biomass. Renew Sustain Energy Rev 11:1056–1086
Chopra S, Jain A (2007) A review of fixed bed gasification systems for biomass. Agric Eng Int 5:1–23
Choudhury ND, Chutia RS, Bhaskar T, Kataki R (2014) Pyrolysis of jute dust: effect of reaction parameters and analysis of products. J Mater Cycles Waste Manage 16(3):449–459
Cottam ML, Bridgwater AV (1994) Techno-economic modeling of biomass flash pyrolysis and upgrading systems. Biomass Bioenerg 7:267–273
Czajczynska D, Anguilano L, Ghazal H, Krzyzynska R, Reynolds AJ, Spencer N, Jouhara H (2017) Potential of pyrolysis processes in the waste management sector. Therm Sci Eng Prog. https://doi.org/10.1016/j.tsep.2017.06.003
Czernik S, Bridgwater AV (2004) Overview of applications of biomass fast pyrolysis oil. Energy Fuels 18:590–598
Demirbas A (1998) Teaching practical chemical kinetics of pyrolysis reaction. Energy Educ Sci Technol 2:23–28
Demirbas A (2000) Mechanisms of liquefaction and pyrolysis reactions of biomass. Energ Convers Manage 41:633–646
Demirbas A (2001) Biomass resource facilities and biomass conversion processing for fuels and chemicals. Energ Convers Manage 42:1357–1378
Demirbas A (2004) Combustion characteristics of different biomass fuels. Prog Energy Combus Sci 30:219–230
Demirbas A (2007) Effect of temperature on pyrolysis products from biomass. Energy Sources Part A 29(4):329–336
Demirbas A, Arin G (2002) An overview of biomass pyrolysis. Energy Sources 24(5):471–482
Dhyani V, Bhaskar T (2017) A comprehensive review on the pyrolysis of lignocellulosic biomass. Renew Energy. https://doi.org/10.1016/j.renene.2017.04.035
Downie A, Crosky A, Munroe P (2009) Physical properties of biochar. In: Lehmann J, Joseph S (eds) Biochar for environmental management: science and technology. Earthscan, London, Dynamotive Energy Systems
Elliott D (1994) Water, alkali and char in flash pyrolysis oils. Biomass Bioenergy 7:179–185
Evans RJ, Milne TA (1987) Molecular characterization of the pyrolysis of biomass. Energy Fuels 1:123–137
Fahmi R, Bridgwater AV, Donnison I, Yates N, Jones JM (2008) The effect of lignin and inorganic species in biomass on pyrolysis oil yields, quality and stability. Fuel 87:1230–1240
Fitz HC, DeBellevue EB, Costanza R, Boumans R, Maxwell T, Wainger L, Sklar FH (1996) Development of a general ecosystem model for a range of scales and ecosystems. Ecol Modell 88:263–295
Freel BA, Graham RG, Huffman DR (1996) Commercial aspects of rapid thermal processing (RTMTM). In: Bio-oil production and utilization. CPL Press, Newbery, UK, pp 86–95
Glaser B, Lehmann J, Zechet W (2002) Ameliorating physical and chemical properties of highly weathered soils in the tropics with charcoal—a review. Biol Fertil Soils 35:219–230
Goswami R, Shimb J, Deka S, Kumari D, Kataki R, Kumar M (2016) Characterization of cadmium removal from aqueous solution by biochar produced from Ipomoea fistulosa at different pyrolytic temperatures. Ecol Eng 97:444–451
Gregoire CE (1992) Techno-economic analysis of the production of biocrude from wood; NREL/TP-430–5435. National Renewable Energy Laboratory, Golden, CO, USA
Gregoire CE, Bain RL (1994) Technoeconomic analysis of the production of biocrude from wood. Biomass Bioenerg 7:275–283
Gust S (1997) Combustion experiences of flash pyrolysis fuel in intermediate size boilers. In: Bridgwater AV, Boocock DG (eds) Developments in thermochemical biomass conversion. Blackie Academic & Professional, London, UK, pp 481–488
Hall DO (1997) Biomass energy in industrialized countries—a view of the future. For Ecol Manage 91:17–45
Harmsen J, Powell JB (2011) Sustainable development in the process industries: cases and impact. Wiley, Hoboken
http://www.eai.in/ref/ae/wte/concepts.html. Accessed 13 June 2017
https://www.btg-btl.com/en/applications/biochemicals. Accessed 20 May 2017
Intergovernmental Panel on Climate Change (2017) Forty-fifth session of the IPCC, Guadalajara, Mexico, 28–31 Mar 2017
International Energy Agency. World Energy Outlook 2016. http://www.worldenergyoutlook.org/factsheets/. Accessed 8 July 2017
International Energy Outlook (IEO 2011) https://www.iea.org/publications/freepublications/publication/WEO2011_WEB.pdf/. Accessed 3 Mar 2017
International Energy Outlook (IEO 2016) https://www.iea.org/media/publications/weo/WEO2016Chapter1.pdf. Accessed 22 Feb 2017
International Energy Outlook (IEO 2017) https://www.eia.gov/outlooks/ieo/pdf/0484(2017).pdf/. Accessed 12 Mar 2017
Ishak WNRW, Hisham MWM, Yarmo MA, Hin TY (2012) A review on biooil production from biomass by using pyrolysis method. Renew Sustain Energy Rev 16:5910–5923
Islam MN, Ani FN (2000) Techno-economics of rice husk pyrolysis, conversion with catalytic treatment to produce liquid fuel. Bioresour Technol 73:67–75
Jahirul MI, Rasul MG, Chowdhury AA, Ashwath N (2012) Biofuels production through biomass pyrolysis—a technological review. Energies 5:4952–5001
Jones SB, Holladay JE, Valkenburg C, Stevens DJ, Walton CW, Kinchin C, Elliott DC, Czernik S (2009) Production of gasoline and diesel from biomass via fast pyrolysis, hydrotreating and hydrocracking: a design case. Report No. PNNL-18284; U.S. Department of Energy, Springfield, VA, USA
Joseph SD, Camps-Arbestain M, Lin Y, Munroe P, Chia CH, Hook J, Zwieten L, Kimber S, Cowie A, Singh BP, Lehmann L, Foidl N, Smernik RJ, Amonette JE (2010) An investigation into the reactions of biochar in soil. Aust J Soil Res 48:501–515
Kabir G, Mohd Din AT, Hameed BH (2017) Pyrolysis of oil palm mesocarp fiber and palm frond in a slow-heating fixed-bed reactor: a comparative study. Bioresour Technol 241:563–572
Kasper JM, Jasas GB, Trauth RL (1983) Use of pyrolysis-derived fuel in a gas turbine engine. ASME Paper No. 83-GT-96
Keech O, Carcaillet C, Nilsson M (2005) Adsorption of allelopathic compounds by wood–derived charcoal: the role of wood porosity. Plant Soil 272:291–300
Kumar A, Jones D, Hanna M (2009) Thermochemical biomass gasification: a review of the current status of the technology. Energies 2(3):556–581
Kwapinski W, Byrne CMP, Kryachko E, Wolfram P, Adley C, Leahy JJ, Novotny EH, Hayes MHB (2010) Biochar from biomass and waste. Waste Biomass Valoriz 1(2):177–189
Labeckas G, Slavinskas S (2006) Performance of direct-injection off-road diesel engine on rapeseed oil. Renew Energy 31:849–863
Lehmann J, Joseph S (2009) Biochar for environmental management: science and technology. Earthscan, London, Dynamotive Energy Systems
Lehmann J, Gaunt J, Rondon M (2006) Bio-char sequestration in terrestrial ecosystems—a review. Mitig Adapt Strat Glob Change 11:395–419
Leung DYC, Yin XL, Wu CZ (2004) A review on the development and commercialization of biomass gasification technologies in China. Renew Sustain Energy Rev 8:565–580
Liang B, Lehman J, Solomon D, Kinyangi J, Grossman J, O’Neill B, Skjemstas JO, Thies J, Luizao FJ, Petersen J, Neves EG (2006) Black carbon increases cation exchange capacity in soils. Soil Sci Soc Am J 70(5):1719–1730
Luo Z, Wang S, Liao Y, Zhou J, Gu Y, Cen K (2004) Research on biomass fast pyrolysis for liquid fuel. Biomass Bioenergy 26:455–462
Lv PM, Xiong ZH, Chang J, Wu CZ, Chen Y, Zhu JX (2004) An experimental study on biomass air–steam gasification in a fluidized bed. Bioresour Technol 95:95–101
Meier D, Oasmaa A, Peacocke GVC (1997) Properties of fast pyrolysis liquids: status of test methods. Characterization of fast pyrolysis liquids. In: Bridgwater AV, Boocock DGB (eds) Developments in thermochemical biomass conversion. Blackie Academic & Professional, London, pp 391–408
Menon V, Rao M (2012) Recent trends in valorization of lignocellulose to biofuel. In: Satyanarayana T, Johri BN (eds) Microorganisms in sustainable agriculture and biotechnology. Springer, Dordrecht, pp 381–409
Mohan D, Pittman CU Jr, Steele P (2006) Pyrolysis of wood/biomass for bio-oil: a critical review. Energy Fuel 20:848–889
Moses C (1994) Fuel-specification considerations for biomass liquids. In: Proceedings of biomass pyrolysis oil properties and combustion meeting, 26–28 Sept, Estes Park, CO., NREL-CP- 430-7215, pp 362–382
Mullaney H, Farag IH, LaClaire CL, Barrett CJ (2002) Technical, environmental and economic feasibility of bio-oil in New Hampshire’s North Country. Final Report, New Hampshire Industrial Research Center (NHIRC), Durham City, NH, USA
Muradov NZ, Veziroglu TN (2008) “Green” path from fossil-based to hydrogen economy: an overview of carbon-neutral technologies. Int J Hydrogen Energy 33:6804–6839
Muradov N, Fidalgo B, Gujar A (2012) Production and characterization of duckweed bio-char and its catalytic application for biogas reforming. Biomass Energy 42:123–131
Oasmaa A, Kytö M, Sipilä K (2001) Pyrolysis oil combustion tests in an industrial boiler. In: Progress in thermochemical biomass conversion. Blackwell Science, Oxford, UK, pp 1468–1481
Oasmaa A, Elliott DC, Korhonen J (2010) Acidity of biomass fast pyrolysis bio-oils. Energy Fuel 24:6548–6554
Oasmaa A, Korhonen J, Kuoppala E (2011) An approach for stability measurement of wood-based fast pyrolysis bio-oils. Energy Fuels 25(7):3307–3313
Onwudili JA, Insura N, Williams PT (2009) Composition of products from the pyrolysis of polyethylene and polystyrene in a closed batch reactor: effects of temperature and residence time. J Anal Appl Pyrol 86:293–303
Ormrod D, Webster A (2000) Progress in utilization of bio-oil in diesel engines. In: PyNe News Letter. Aston University, Birmingham, UK, p 15
Peacocke GVC, Madrali ES, Li C-Z, Guell AJ, Kandiyoti R, Bridgwater AV (1994a) Effect of reactor configuration on the yields and structures of pine-wood derived pyrolysis liquids: a comparison between ablative and wire-mesh pyrolysis. Biomass Bioenergy 7(1–6):155–167
Peacocke GVC, Russell PA, Bridgwater AV (1994b) Ablative plate pyrolysis of biomass for liquids. Biomass Bioenergy 7:147–154
Pettersen RC (1984) The chemical composition of wood. Chem Solid Wood 207:57–126
Polagye LB, Hodgson KT, Malte PC (2007) An economic analysis of bio-energy options using thinnings from overstocked forests. Biomass Bioenergy 31:105–125
Prasad S, Singh A, Joshi HC (2007) Ethanol as an alternative fuel from agricultural, industrial and urban residues. Resour Conserv Recycl 50:1–39
Putun AE, Apaydin E, Putun E (2002) Bio-oil production from pyrolysis and steam pyrolysis of soybean-cake: product yields and composition. Energy 27(7):703–713
Ramadhas AS, Jayaraj S, Muraleedharan C (2005) Characterization and effect of using rubber seed oil as fuel in the compression ignition engines. Renew Energy 30:795–803
Rao MS, Singha SP, Sodhaa MS, Dubey AK, Shyam M (2004) Stoichiometric, mass, energy and exergy balance analysis of countercurrent fixed-bed gasification of post-consumer residues. Biomass Bioenergy 27:155–171
REN21-Renewable Energy Policy Network for the 21st Century. Renewables 2014 Global Status Report, 2014
Ringer M, Putsche V, Scahill J (2006) Large-scale pyrolysis oil production and economic analysis. Technical report NREL/TP-510–37779, National Renewable Energy Laboratory, Cole Boulevard, CO, USA
Roy P, Dias G (2017) Prospects for pyrolysis technologies in the bioenergy sector: a review. Renew Sustain Energy Rev 77:59–69
Roy C, Blanchette D, Korving L, Yang J, DeCaumia B (1997) Development of a novel vacuum pyrolysis reactor with improved heat transfer potential. In: Bridgewater AV, Boocock DGB (eds) Developments in thermochemical biomass conversion. Blackie Academic and Professional, London, UK, pp 351–367
Saffarzadeh A, Shimaoka T, Motomura Y, Watanabe K (2006) Chemical and mineralogical evaluation of slag products derived from the pyrolysis/melting treatment of MSW. Waste Manage 26:1443–1452
Saikia R, Chutia RS, Kataki R, Pant KK (2015) Perennial grass (Arundo donax L.) as a feedstock for thermo-chemical conversion to energy and materials. Bioresour Technol 188:265–272
Scott DS, Majerski P, Piskorz J, Radlein D (1999) A second look at fast pyrolysis of biomass—the RTI process. J Anal Appl Pyrol 51:23–37
Scurlock JMO, Dayton DC, Hames B (2000) Bamboo: an overlooked biomass resource? Biomass Bioenerg 19:229–244
Sharma A, Pareek V, Zhang D (2015) Biomass pyrolysis—a review of modelling, process parameters and catalytic studies. Renew Sustain Energy Rev 50:1081–1096
Sharuddin SDA, Abnisa F, Daud WMAW, Aroua MK (2016) A review on pyrolysis of plastic wastes. Energy Convers Manage 115:308–326
Solantausta Y, Oasmaa A (2003) Fast pyrolysis of forestry residues and sawdust, production and fuel oil quality. In Proceedings of international nordic bioenergy conference, Javaskyla, Finland, pp 1–3
Soltes EJ, Lin JCK (1984) Hydro processing of biomass tars for liquid engine fuels. In: Tillman DA, Jahn EC (eds) Progress in biomass conversion. Academic Press, New York, pp 1–69
Sorum L, Gronli MG, Hustad JE (2001) Pyrolysis characteristics and kinetics of municipal solid wastes. Fuel 80:1217–1227
Thewys T, Kuppens T (2008) Economics of willow pyrolysis after phytoextraction. Int J Phytorem 10:561–583
Tripathi M, Sahu JN, Ganesan P (2016) Effect of process parameters on production of biochar from biomass waste through pyrolysis: a review. Renew Sustain Energy Rev 55:467–481
Thornley P, Wright E (2001) Evaluation of Bio-Energy Projects. In PyNe Final Report to the EC; European Commission: Brussels, Belgium
Voets T, Kuppens T (2011) Economics of electricity and heat production by gasification or flash pyrolysis of short rotation coppice in Flanders (Belgium). Biomass Bioenergy 35:1912–1924
Wagenaar BM, Venderbosch RH, Carrasco J, Strenziok R, Van der Aa BJ (2001) Rotating cone bio-oil production and applications. In: Bridgewater AV (ed) Progress in thermochemical biomass conversion. Blackwell Science, Oxford, UK, pp 1268–1280
Wang X, Kersten SRA, Prins W, Van Swaaij WPM (2005) Biomass pyrolysis in a fluidized bed reactor. Part 2: Experimental validation of model results. Ind Eng Chem Res 44:8786–8795
Wang S, Dai G, Yang H, Luo Z (2017) Lignocellulosic biomass pyrolysis mechanism: a state-of-the-art review. Prog Energy Combust Sci 62:33–86
Wright MM, Daugaard DE, Satrio JA, Brown RC (2010) Techno-economic analysis of biomass fast pyrolys to transportation fuels. Fuel 89:S2–S10
Yaman S (2004) Pyrolysis of biomass to produce fuels and chemical feedstocks. Energy Convers Manage 45:651–671
Yang H, Yan R, Chen H, Lee DH, Liang DT, Zheng C (2006) Pyrolysis of palm oil wastes for enhanced production of hydrogen rich gases. Fuel Proc Technol 87:935–942
Zabaniotou AA (1999) Pyrolysis of forestry biomass by-products in Greece. Energy Sources Part A Recovery Util Environ Eff 21:395–403
Zanzi R, Sjostrom K, Bjornbom E (1996) Rapid high-temperature pyrolysis of biomass in a free-fall reactor. Fuel 75:545–550
Zhao YL, Dolat A, Steinberger Y, Wang X, Osman A, Xie GH (2009) Biomass yield and changes in chemical composition of sweet sorghum cultivars grown for biofuel. Fields Crop Res 111:55–64
Acknowledgements
The authors would like to offer their sincere thanks and acknowledgement for the support from Tezpur University and University Grants Commission, New Delhi, India [Grant No. 42-723/2013 (SR)] received in the form of UGC-MRP. The authors RN, DS, and RS sincerely acknowledge the receipt of fellowships from UGC and CSIR, respectively.
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Kataki, R. et al. (2018). Waste Valorization to Fuel and Chemicals Through Pyrolysis: Technology, Feedstock, Products, and Economic Analysis. In: Singhania, R., Agarwal, R., Kumar, R., Sukumaran, R. (eds) Waste to Wealth. Energy, Environment, and Sustainability. Springer, Singapore. https://doi.org/10.1007/978-981-10-7431-8_21
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