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Thermal properties of oxide glasses

Part III. Thermal stability of Li2O·2SiO2·nMeO2 glasses (M=Ti, Zr)

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Abstract

Glasses with the composition Li2O·2SiO2·nTiO2 and Li2O·2SiO2·nZrO2, where n=0, 0.03, 0.062, 0.1, were prepared and the onset and peak temperatures have been determined by DTA. From these characteristic temperatures, the kinetic parameters describing the nucleation and crystal growth have been obtained by isoconversional methods. The kinetic parameters have been used for the calculation of nucleation and crystal growth times for individual glasses so determining the order of glass stability at reheating. The stability of glasses increases with the content of TiO2 or ZrO2 where the increase is higher for ZrO2. Within the concentration range under study, the increase of both times with the metal oxide concentration is quadratic. It has been discussed that the crystallization kinetics does not obey the Arrhenius law and, therefore, when using the evaluation methods based on this law, the results should not be extrapolated outside the temperature range of the measurements.

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Authors and Affiliations

  1. Institute of Physical Chemistry and Chemical Physics, Faculty of Chemical and Food Technology, Slovak University of Technology, 812 37, Bratislava, Slovakia

    P. Šimon

  2. Department of Chemistry and Technology of Inorganic Materials, Faculty of Industrial Technologies, Tren čín University of Alexander Dubček, 020 32, Púchov, Slovakia

    E. Jóna & V. Pavlík

Authors
  1. P. Šimon
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  2. E. Jóna
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  3. V. Pavlík
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Correspondence to P. Šimon.

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Šimon, P., Jóna, E. & Pavlík, V. Thermal properties of oxide glasses. J Therm Anal Calorim 94, 421–425 (2008). https://doi.org/10.1007/s10973-008-9148-2

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