Abstract
The applications of nanomaterials have been enormous, which not only encompasses a single discipline but it stretches across the whole spectrum of science right from agricultural science to space technology. New approaches to synthesize nanomaterials in order to design new devices and processes are being developed and the techniques of fabrication of nanomaterials involve analyzing and controlling the matter at atomic scales. This fascinating research field has started a new era of integration of basic research and advanced technology at the atomic scale which has a potential to bring the technological innovations at highest level. The rudimentary capabilities of nanomaterials today are envisioned to evolve in our overlapping generations of nanotechnology products: passive nanostructures, active nanostructures, systems of nanosystems, and molecular nanosystems. This chapter presents the basic introduction to nanomaterials and their popular applications.
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References
A.S. Edelstein, R.C. Cammarata, Nanomaterials: Synthesis, Properties and Applications (Institute of Physics Publishing, Bristol, 1998)
K.E. Geckeler, E. Rosenberg (eds.), Functional Nanomaterials (American Scientific Publishers, Valencia, 2006), p. 488
B. Bhushan, Handbook of Nanotechnology (Springer, Berlin, 2004)
M. Wilson, K. Kannangara, G. Smith, M. Simmons, B. Raguse, Nanotechnology: Basic Science and Emerging Technologies (CRC Press, Boca Raton, 2002)
R. Valiev, Materials science: nanomaterial advantage. Nature 419(6910), 887–889 (2002)
W.G. Kreyling, M. Semmler-Behnke, Q. Chaudhry, A complementary definition of nanomaterial. Nano Today 5(3), 165–168 (2010)
N.C. Seeman, DNA in a material world. Nature 421, 427 (2003)
G. Taubes, Double helix does chemistry at a distance—but how? Science 275, 1420 (1997)
A. Okamoto, K. Tanaka, I. Saito, Rational design of a DNA wire possessing an extremely high hole transport ability. J. Am. Chem. Soc. 125, 5066 (2003)
J.R. Peralta-Videa, L. Zhao, M.L. Lopez-Moreno, G. de la Rosa, J. Hong, J.L. Gardea-Torresdey, Nanomaterials and the environment: a review for the biennium 2008–2010. J. Hazard. Mater. 186(1), 1–15 (2011)
B.A. Magnuson, T.S. Jonaitis, J.W. Card, A brief review of the occurrence use, and safety of food related nanomaterials. J. Food Sci. 76(6), R126–R133 (2011)
R.P. Adams, Nanotechnology: understanding small system (CRC Press, Taylor and Francis Group, Boca Raton, 2007)
M.S. Rajan, Nano: The Next Revolution (National Book Trust, New Delhi, 2005)
M.J. O’Connell, Carbon Nanotubes: Properties and Applications (CRS Taylor and Francis, Boca Raton, 2006)
M.A. Ratner, D. Ratner, Nanotechnology: A Gentle Introduction to the Next Big Idea, Technology and Engineering (Prentice Hall, Upper Saddle River, 2003)
Samori, Bruno. Plenty of Room for Biology at the Bottom. An Introduction to Bionanotechnology. By Ehud Gazit. 236–237 (2008)
J.L. de la Fuente, G. Mosquera, R. ParÃs, High performance HTPB-based energetic nanomaterial with CuO nanoparticles. J. Nanosci. Nanotechnol. 9(12), 1–7 (2009). 685
B.K. Teo, X.H. Sun, Classification and representations of low-dimensional nanomaterials: terms and symbols. J. Cluster Sci. 18(2), 346–357 (2007)
A.N. Guz, Y.Y. Rushchitskii, Nanomaterials: on the mechanics of nanomaterials. Int. Appl. Mech. 39(11), 1271–1293 (2003)
T. Tervonen, I. Linkov, J.R. Figueira, J. Steevens, M. Chappell, M. Merad, Risk-based classification system of nanomaterials. J. Nanopart. Res. 11(4), 757–766 (2009)
V.V. Pokropivny, V.V. Skorokhod, Classification of nanostructures by dimensionality and concept of surface forms engineering in nanomaterial science. Mater. Sci. Eng. C 27(5), 990–993 (2007)
L.M. Liz-Marzan, P. Mulvaney, The assembly of coated nanocrystals. J. Phys. Chem. B 107, 7312 (2003)
X.H. Sun, N.B. Wong, C.P. Li, S.T. Lee, T.K. Sham, Chainlike silicon nanowires: morphology, electronic structure and luminescence studies. J. Appl. Phys. 96, 3447 (2004)
X.H. Sun, C.P. Li, N.B. Wong, C.S. Lee, S.T. Lee, B.K. Teo, Templating effect of hydrogen-passivated silicon nanowires in the production of hydrocarbon nanotubes and nanoonions via sonochemical reactions with common organic solvents under ambient conditions. J. Am. Chem. Soc. 124, 14856 (2002)
A.I. Hochbaum, R. Fan, R.R. He, P.D. Yang, Controlled growth of Si nanowire arrays for device integration. Nano Lett. 5, 457 (2005)
Z. Zhong, F.X. Chen, A.S. Subramanian, J.Y. Lin, J. Highfield, A. Gedanken, Assembly of Au colloids into linear and spherical aggregates and effect of ultrasound irradiation on structure. J. Mater. Chem. 6, 489 (2006)
V. Svrcek, C. Pham-Huu, M.J. Ledoux, F. Le Norman, O. Ersen, S. Joulie, Filling of single silicon nanocrystals within multi-walled carbon nanotubes. Appl. Phys. Lett. 88, 033112 (2006)
W.Z. Li, S.S. Xie, L.X. Qian, B.H. Chang, B.S. Zou, W.Y. Zhou, R.A. Zhao, G. Wang, Large-scale synthesis of aligned carbon nanotubes. Science 274, 1701 (1996)
B.K. Teo, H.X. Sun, Silicon-based low-dimensional nanomaterials and nanodevices. Chem. Rev. 107, 1454 (2007)
A.N. Khlobystov, K. Porfyrakis, M. Kanai, D.A. Britz, A. Ardavan, H. Shinohara, T.J.S. Dennis, G.A.D. Briggs, Molecular motion of endohedral fullerenes in single-walled carbon nanotubes. Angew. Chem. Int. Ed. 43, 1386 (2004)
H.W. Kroto, J.R. Heath, S.C. O’Brien, R.F. Curl, R.E. Smalley, Reactivity of large carbon clusters: spheroidal carbon shells and their possible relevance to the formation and morphology of soot. Nature 318, 162 (1985)
W. Kratschmer, L.D. Lamb, K. Fostiropoulos, D.R. Huffman, C60: a new form of carbon. Nature 347, 354 (1990)
R.C. Haddon, A.F. Hebard, M.J. Rosseinsky, D.W. Murphy, S.J. Duclos, K.B. Lyons, B. Miller, J.M. Rosamilia, R.M. Fleming, A.R. Kortan, S.H. Glarum, A.V. Makhija, A.J. Muller, R.H. Eick, S.M. Zahurak, R. Tycko, G. Dabbagh, F.A. Thiel, Conducting films of C60 and C70 by alkali-metal doping. Nature 350, 320 (1991)
M. Shahid Khan, Figures Simulated (Department of Physics, Jamia Millia Islamia, New Delhi, India) (2015)
S. Iijima, Helical microtubules of graphitic carbon. Nature 354, 56 (1991)
S. Iijima, T. Ichihashi, Single-shell carbon nanotubes of 1-nm diameter. Nature 363, 603 (1993)
D.S. Bethune, C.H. Kiang, M.S. de Vries, G. Gorman, R. Savoy, J. Vazquez, R. Beyers, Cobalt-catalysed growth of carbon nanotubes with single-atomic-layer walls. Nature 363, 605 (1993)
S. Frank, P. Poncharal, Z.L. Wang, W.A. deHeer, Carbon nanotube quantum resistors. Science 280, 1744 (1998)
M.K. Rai, S. Sarkar, Carbon nanotube as VLSI interconnect, in Electronic Properties of Carbon Nanotubes, ed. by J.M. Marulanda (Intech, Rijeka, Croatia, 2011)
A. Kumar, S. Parveen, S. Husain, J. Ali, M. Zulfequar, Harsh, M. Husain, Effect of oxygen plasma on field emission characteristics of single-wall carbon nanotubes grown by plasma enhanced chemical vapour deposition system. J. Appl. Phys. 115, 084308 (2014)
A. Kumar, S. Husain, J. Ali, M. Husain, Harsh, M. Husain, Field emission study of carbon nanotubes forest and array grown on Si using Fe as catalyst deposited by electro-chemical method. J. Nanosci. Nanotech. 12(3), 2829 (2012)
Z.H. Khan, M. Husain, Carbon nanotube and its possible applications. Indian J. Mat. Sci. Eng. 12, 529–551 (CSIR, New Delhi)
Z.H. Khan, S. Khan, M. Husain, Variable range hopping in carbon nanotubes. Curr. Nanosci. 6, 1–16 (2010)
Z.H. Khan, N. Salah, S.S. Habib, A. Azam, M.S. Al-Shahawi, Multi-walled carbon nanotubes film sensor for carbon mono-oxide gas. Curr. Nanosci. 8, 274 (2012)
Z.H. Khan, N. Salah, S.S. Habib, M.S. Ansari, M.S. Al-Shahawi, Cobalt catalyzed multi-walled carbon nanotubes film sensor for carbon mono-oxide gas. Dig. J. Nanomater. Biostruct. 6(4), 1947 (2011)
A.F. Hollemann, E. Wiberg, Lehrbuch der Anorganischen Chemei (Walter de Gruyter, Berlin, 1985), p. 701
Y. Lifshitz, DLC-present status. Diamond Relat. Mater. 3–5, 388 (1996)
D.R. Mckenzie, Tetrahedral bonding in amorphous carbon. Rep. Prog. Phys. 59, 1611 (1996)
H. Tsai, D.B. Bogi, Characterisation of diamond-like carbon films and their application as overcoats on thin-film media for magnetic recording. J. Vac. Sci. Technol. A 5(6), 3287 (1987)
J.P. Hirvonen, J. Koskinen, R. Lappalainen, A. Anttila, Preparation and properties of high density hydrogen free hard carbon films with direction beam or arc discharge deposition mater. Sci. Forum 52–53, 197 (1990)
Y. Liftshitz, S.R. Kasi, J.W. Rabalais, Carbon (sp3) film growth from mass selected ion beams: parametric investigations and subplantation model. Mater. Sci. Forum 52–53, 237 (1990)
Y. Lifshitz, G.D. Lempert, E. Grossman, I. Avigal, C. UzanSaguy, R. Kalish, J. Kulik, D. Marton, J.W. Rabalais, The influence of substrate temperature during ion beam deposition on the diamond-like or graphitic nature of carbon films. Diam. Relat. Mater. 4, 287 (1995)
C.A. Davis, A simple model for the formation of compressive stress in thin films by ion bombardment. Thin Solid Films 226, 30 (1993)
J. Robertson, Deposition mechanisms for promoting sp3 bonding in diamond-like carbon. Diam. Relat. Mater. 2, 984 (1993)
Y. Lifshitz, S.R. Kasi, J.W. Rabalais, Subplantation model for film growth from hyperthermal species: application to diamond. Phys. Rev. Lett. 62, 1290 (1990)
B. Bhushan, Chemical, mechanical and tribological characterization of ultra-thin and hard amorphous carbon coatings as thin as 3.5Â nm: recent developments. Diam. Relat. Mater. 8, 1985 (1999)
A.K. Sikder, T. Sharda, D.S. Misra, P. Selvam, Chemical vapour deposition of diamond on stainless steel: the effect of Ni-diamond composite coated buffer layer. Diam. Relat. Mater. 7, 1010 (1998)
M. Chhowalla, Y. Yin, G.A.J. Amaratunga, D.R. McKenzie, Th Fraurnheim, Highly tetrahedral amorphous carbon films with low stress. Appl. Phys. Lett. 69, 2344 (1996)
C.B. Collins, F. Davanloo, T.J. Lee, D.R. Jander, J.H. You, H. Park, J.C. Pivin, The bonding of protective films of amorphic diamond to titanium. J. Appl. Phys. 71, 3260 (1992)
A.K. Geim, Graphene: status and prospects. Science 324(5934), 1530 (2009)
M.I. Katsnelson, K.S. Novoselov, A.K. Geim, Chiral tunnelling and the Klein paradox in graphene. Nat. Phys. 2, 620 (2006)
J.C. Slonczewski, P.R. Weiss, Band structure of graphite. Phys. Rev. 109, 272 (1958)
G.W. Semenoff, Condensed-matter simulation of a three-dimensional anomaly. Phys. Rev. Lett. 53, 244 (1984)
C.N.R. Rao, U. Maitra, H.S.S. Ramakrishna Matte, Synthesis, characterization, and selected properties of graphene, in Graphene: Synthesis, Properties, and Phenomena, 1st edn, ed. by C.N.R. Rao, A.K. Sood (wiley, Chichester, 2013)
M.A. Rafiee, J. Rafiee, Z. Wang, H. Song, Z.Z. Yu, N. Koratkar, Enhanced mechanical properties of nanocomposites at low graphene content. ACA Nano 3(12), 3884–3890 (2009)
M. Fuller, The axial ratio and lattice constants of zinc oxide. Science 70, 196 (1929)
C. Bunn, The lattice-dimensions of zinc oxide. Proc. Phys. Soc. 47, 835 (1935)
U. Ozgur, Ya.I. Alivov, C. Liu, A. Teke, M.A. Reshchikov, S. Dogan, V. Avrutin, S.-J. Cho, H. Morkoc, A comprehensive review of ZnO materials and devices. J. Appl. Phys. 98, 41301 (2005)
J. Grabowska, K.K. Nanda, E. McGlynn, J.-P. Mosnier, M.O. Henry, A. Beaucamp, A. Meaney, Synthesis and photoluminescence of ZnO nanowires/nanorods. J. Mater. Sci. Mater. Electron. 16, 397 (2005)
J. Grabowska, K.K. Nanda, E. McGlynn, J.-P. Mosnier, M.O. Henry, Control of ZnO nanorod array density by Zn supersaturation variation and effects on field emission. Surf. Coat. Technol. 200, 1093 (2005)
C. Ronning, P.X. Gao, Y. Ding, Z.L. Wang, Manganese-doped ZnO nanobelts for spintronics. Appl. Phys. Lett. 84, 782 (2004)
W.Z. Wang, B.Q. Zeng, J. Yang, B. Poudel, J.Y. Huang, M.J. Naughton, Z.F. Ren, Aligned ultralong ZnO nanobelts and their enhanced field emission. Adv. Mater. 18, 3275 (2006)
Z.W. Pan, Z.R. Dai, Z.L. Wang, Nanobelts of semiconducting oxides. Science 291, 1947–1949 (2001)
J. Grabowska, A. Meaney, K.K. Nanda, J.-P. Mosnier, M.O. Henry, J.R. Duclere, E. McGlynn, Surface excitonic emission and quenching effects in ZnO nanowire/nanowall systems: limiting effects on device potential. Phys. Rev. B 71, 115439 (2005)
Y.J. Xing, Z.H. Xi, Z.Q. Xue, X.D. Zhang, J.H. Song, Optical properties of the ZnO nanotubes synthesized via vapor phase growth. Appl. Phys. Lett. 83, 1689 (2003)
Y. Qiu, S. Yang, ZnO Nanotetrapods: controlled vapor-phase synthesis and application for humidity sensing. Adv. Func. Mater. 17, 1345 (2007)
W.I. Park, D.H. Kim, S.-W. Jung, G.C. Yi, Fabrication and electrical characteristics of high-performance ZnO nanorod field-effect transistors. Appl. Phys. Lett. 80, 4232 (2002)
X. Fan, M.L. Zhang, I. Shafiq, W.J. Zhang, C.S. Lee, S.T. Lee, ZnS/ZnO heterojunction nanoribbons. Adv. Mater. 21, 2393 (2009)
M. Riaz, J. Song, O. Nur, Z.L. Wang, M. Willander, Study of the piezoelectric power generation of ZnO nanowire arrays grown by different methods. Adv. Funct. Mater. XX, 1–6 (2010). doi:10.1002/adfm.201001203
J.J. Wu, S.C. Liu, Catalyst-free growth and characterization of ZnO nanorods. Adv. Mater. 14, 215 (2002)
X. Wang, J. Song, J. Liu, Z.L. Wang, Direct-current nanogenerator driven by ultrasonic waves. Science 316, 102 (2007)
Z.L. Wang, J. Song, Piezoelectric nanogenerators based on zinc oxide nanowire array. Science 312, 242 (2006)
C.J. Lee, T.J. Lee, S.C. Lyu, Y. Zhang, H. Ruth, H.J. Lee, Field emission from well-aligned zinc oxide nanowires grown at low temperature. Appl. Phys. Lett. 81, 3648 (2002)
E. Comini, G. Faglia, G. Sberveglieri, Z.W. Pan, Z.L. Wang, Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts. Appl. Phys. Lett. 81, 1869 (2002)
M. Zhao, Z.L. Wang, S.X. Mao, Piezoelectric characterization on individual zinc oxide nanobelt under piezoresponse force microscope. Nano Lett. 4, 587 (2004)
W. Hughes, Z.L. Wang, Nanobelts as nanocantilevers. Appl. Phys. Lett. 82, 2886 (2003)
H.T. Wang, Hydrogen-selective sensing at room temperature with ZnO nanorods. Appl. Phys. Lett. 86, 243503 (2005)
W. Lee, Catalyst-free growth of ZnO nanowires by metal-organic chemical vapour deposition (MOCVD) and thermal evaporation. Acta Mater. 52, 3949 (2004)
S. Liang, H. Sheng, Y. Liu, Z. Huo, Y. Lu, H. Shen, ZnO Schottky ultraviolet photodetectors. J. Cryst. Growth 225, 110 (2001)
Y.P. Liu, Y. Guo, J.Q. Li, M. Trunk, A.Y. Kuznetsov, J.B. Xu, Z.X. Mei, X.L. Du, Temperature dependence of surface plasmon mediated near band-edge emission from Ag/ZnO nanorods. J. Opt. 13, 075003 (2011)
C.J. Lee, T.J. Lee, S.C. Lyu, Y. Zhang, H. Ruth, H.J. Lee, Field emission from well-aligned zinc oxide nanowires grown at low temperature. Appl. Phys. Lett. 81, 3648 (2002)
M.S. Arnold, P. Avouris, Z.W. Pan, Z.L. Wang, Field-effect transistors based on single semiconducting oxide nanobelts. J. Phys. Chem. 107, 659 (2003)
P. Hui, L. Jizhong, S. Han, F. Yuanping, P. Cheekok, L. Jianyi, Hydrogen storage of ZnO and Mg doped ZnO nanowires. Nanotechnology 17, 2963 (2006)
Q. Wan, C.L. Lin, X.B. Yu, T.H. Wang, Room-temperature hydrogen storage characteristics of ZnO nanowires. Appl. Phys. Lett. 84, 124 (2004)
M. Ahmad, J. Zhu, ZnO based advanced functional nanostructures: synthesis, properties and applications. J. Mater. Chem. 21, 599 (2010)
H. Yan, R. He, J. Johnson, M. Law, R.J. Saykally, P. Yang, Dendritic nanowire ultraviolet laser array. J. Am. Chem. Soc. 25, 4728 (2003)
J.C. Johnson, H. Yan, P. Yang, R.J. Saykalley, Optical cavity effects in ZnO nanowire lasers and waveguides. J. Phys. Chem. B 105, 8816 (2001)
M.H. Huang, S. Mao, H. Feick, H. Yan, Y. Wu, H. Kind, E. Weber, R. Russo, P. Yang, Room-temperature ultraviolet nanowire nanolasers. Science 292, 1897 (2001)
J. Bao, M.A. Zimmler, F. Capasso, X. Wang, Z.F. Ren, Broadband ZnO single-nanowire light-emitting diode. Nano Lett. 6(8), 1719–1722 (2006)
I. Bedja, P.V. Kamat, X. Hua, A.G. Lappin, S. Hotchandani, Photosensitization of nanocrystalline ZnO films by Bis(2,2′-bipyridine)(2,2′-bipyridine-4,4′-dicarboxylic acid)ruthenium(II). Langmuir 13, 2398 (1997)
K. Keis, C. Bauer, G. Boschloo, J. Photochem et al., Nanostructured ZnO electrodes for dye-sensitized solar cell applications. Photobiol. A 148, 57 (2002)
K. Keis, E. Magnusson, H. Lindström, S.-E. Lindquist, A. Hagfeldt, A 5% efficient photoelectrochemical solar cell based on nano structured ZnO electrodes. Sol. Energy Mater. Sol. Cells 73, 51 (2002)
K. Keis, Photoelectrochemical properties of nano-to microstructured ZnO electrodes. J. Electrochem. Soc. 148, 149 (2001)
R. Katoh, A. Furube, Y. Tamaki, T. Yoshihara, M. Murai, K. Hara, S. Murata, H. Arakawa, M. Tachiya, Microscopic imaging of the efficiency of electron injection from excited sensitizer dye into nanocrystalline ZnO film. J. Photochem. Photobiol. A 166, 69 (2004)
R. Katoh, A. Furube, T. Yoshihara, K. Hara, G. Fujihashi, S. Takano, S. Murata, H. Arakawa, M. Tachiya, Efficiencies of electron injection from excited N3 dye into nanocrystalline semiconductor (ZrO2, TiO2, ZnO, Nb2O5, SnO2, In2O3) films. J. Phys. Chem. B 108, 4818 (2004)
A. Furube, R. Katoh, K. Hara, S. Murata, H. Arakawa, M. Tachiya, Ultrafast stepwise electron injection from photoexcited Ru-complex into nanocrystalline ZnO film via intermediates at the surface. J. Phys. Chem. B 107, 4162 (2003)
H. Horiuchi, R. Katoh, K. Hara, M. Yanagida, S. Murata, H. Arakawa, M. Tachiya, Electron injection efficiency from excited N3 into nanocrystalline ZnO films: effect of (N3–Zn2+) aggregate formation. J. Phys. Chem. B 107, 2570 (2003)
B. O’Regan, M.A. Grätzel, Low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 353, 737 (1991)
W. Lee, M.-C. Jeong, J.-M. Myoung, Fabrication and application potential of ZnO nanowires grown on GaAs (002) substrates by metal–organic chemical vapour deposition. Nanotechnology 15, 254 (2004)
Y. Huang, X. Bai, Y. Zhang, In situ mechanical properties of individual ZnO nanowires and the mass measurement of nanoparticles. J. Phys. Condens. Mat. 18, 179–184 (2006)
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Khan, Z.H., Kumar, A., Husain, S., Husain, M. (2016). Introduction to Nanomaterials. In: Husain, M., Khan, Z. (eds) Advances in Nanomaterials. Advanced Structured Materials, vol 79. Springer, New Delhi. https://doi.org/10.1007/978-81-322-2668-0_1
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